Methyl-coriolat | 40707-82-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl-coriolat
• CAS: 40707-82-2
• 化学式: C₂₂H₄₂O₃Si
• 分子量: 382.659
• InChiKey: CKJJXCPHFROKCV-HCLGHBQCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  26.0
• 可旋转键数：
  16.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  35.53
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 methyl coriolate 在 N,O-双(三甲基硅烷基)三氟乙酰胺 作用下， 反应 1.0h， 生成 Methyl-coriolat
  参考文献：
  名称：

  High-Performance Liquid Chromatographic Analysis of the Products of Linoleic Acid Oxidation Catalyzed by Pea (Pisum sativum) Seed Lipoxygenases

  摘要：

  An HPLC method is discussed for the analysis of the products formed by the pea (Pisum sativum) lipoxygenase catalyzed oxidation of linoleic acid. The results demonstrate the feasibility of analyzing all of the hydroperoxides, hydroxides, and keto fatty acids in a single chromatographic step and show that it will be possible to analyze the product profile from the lipoxygenase activity contained in a portion of a seed, which will permit the remainder of the seed to be grown on for subsequent generations. The chemical structures of the products have been identified by HPLC analysis and GC-MS.

  DOI：

  10.1021/jf00050a014

文献信息

• High-Performance Liquid Chromatographic Analysis of the Products of Linoleic Acid Oxidation Catalyzed by Pea (Pisum sativum) Seed Lipoxygenases
  作者：Zecai Wu、David S. Robinson、Claire Domoney、Rod Casey

  DOI：10.1021/jf00050a014

  日期：1995.2

  An HPLC method is discussed for the analysis of the products formed by the pea (Pisum sativum) lipoxygenase catalyzed oxidation of linoleic acid. The results demonstrate the feasibility of analyzing all of the hydroperoxides, hydroxides, and keto fatty acids in a single chromatographic step and show that it will be possible to analyze the product profile from the lipoxygenase activity contained in a portion of a seed, which will permit the remainder of the seed to be grown on for subsequent generations. The chemical structures of the products have been identified by HPLC analysis and GC-MS.