3-[4-(1,1-dimethylethyl)phenyl]-4,5-diphenyl-4H-1,2,4-triazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-[4-(1,1-dimethylethyl)phenyl]-4,5-diphenyl-4H-1,2,4-triazole
• 英文别名: 3-(4-(tert-Butyl)phenyl)-4,5-diphenyl-4H-1,2,4-triazole；3-(4-tert-butylphenyl)-4,5-diphenyl-1,2,4-triazole
• 化学式: C₂₄H₂₃N₃
• 分子量: 353.467
• InChiKey: XJYWOYRBUISMBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-[4-(1,1-dimethylethyl)phenyl]-4,5-diphenyl-4H-1,2,4-triazole 、 1-(7-Tert-butylpyren-1-yl)cyclohexan-1-ol 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以65%的产率得到3-(4-Tert-butylphenyl)-4-[4-[1-(7-tert-butylpyren-1-yl)cyclohexyl]phenyl]-5-phenyl-1,2,4-triazole
  参考文献：
  名称：

  蓝荧光材料及显示面板

  摘要：

  本发明提供一种蓝荧光材料及其OLED显示面板，其蓝荧光材料为将叔丁基芘和载流子传输单元同时连接到环己烷的同一个碳上，形成的一种四面体结构；其中，叔丁基芘可以通过其三重态‑三重态融合，达到相对较高的外量子效率；同时，四面体的结构增加了激活粒子之间的中心距离，降低了浓度猝灭的风险，大大增加了膜态荧光量子效率；另外，高载流子迁移率的传输单元，可以改善载流子传输的平衡，增加复合几率，进一步提高OLED显示器件的外量子效率，缓解了现有OLED显示面板存在蓝光材料发光效率低的问题。

  公开号：

  CN110129034B

文献信息

• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10381569B2

  公开（公告）日：2019-08-13

  A composition formed of a mixture of two compounds having similar thermal evaporation properties that are pre-mixed into an evaporation source that can be used to co-evaporate the two compounds into an emission layer in OLEDs via vacuum thermal evaporation process is disclosed. The first and second compounds can have an evaporation temperature T1 and T2, respectively, of 150 to 350° C., and the absolute value of T1−T2 can be less than 20° C. The first compound can have a concentration C1 in the mixture and a concentration C2 in a film formed by evaporating the mixture in a vacuum deposition tool at a constant pressure between 1×10−6 Torr to 1×10−9 Torr, at a 2 Å/sec deposition rate on a surface positioned at a predefined distance away from the mixture being evaporated, where the absolute value of (C1−C2)/C1 is less than 5%.

  本发明公开了一种由两种具有相似热蒸发特性的化合物的混合物组成的组合物，这两种化合物预先混合到蒸发源中，可用于通过真空热蒸发工艺将这两种化合物共同蒸发到 OLED 的发射层中。第一种和第二种化合物的蒸发温度 T1 和 T2 可分别为 150 至 350 摄氏度、第一种化合物在混合物中的浓度为 C1，而在真空沉积工具中以 1×10-6 托至 1×10-9 托的恒定压力、2 Å/秒的沉积速率、在距离被蒸发混合物预定距离的表面上蒸发混合物而形成的薄膜中的浓度为 C2，其中 (C1-C2)/C1 的绝对值小于 5%。
• Organic Luminescent Compound With Delayed Fluorescence
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20140145149A1

  公开（公告）日：2014-05-29

  Novel organic compounds containing an imidazole core and electron donor and acceptor fragments are provided. By selection of the disclosed donor and acceptor groups, compounds exhibiting small singlet-triplet gaps are obtained. These compounds are useful in OLED devices as host materials or as delayed fluorescent emitters.
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20160149139A1

  公开（公告）日：2016-05-26

  A composition formed of a mixture of two compounds having similar thermal evaporation properties that are pre-mixed into an evaporation source that can be used to co-evaporate the two compounds into an emission layer in OLEDs via vacuum thermal evaporation process is disclosed. The first and second compounds can have an evaporation temperature T 1 and T 2 , respectively, of 150 to 350° C., and the absolute value of T 1 −T 2 can be less than 20° C. The first compound can have a concentration C 1 in the mixture and a concentration C 2 in a film formed by evaporating the mixture in a vacuum deposition tool at a constant pressure between 1×10 −6 Torr to 1×10 −9 Torr, at a 2 Å/sec deposition rate on a surface positioned at a predefined distance away from the mixture being evaporated, where the absolute value of (C 1 −C 2 )/C 1 is less than 5%.
• BLUE FLUORESCENT MATERIAL AND DISPLAY PANEL
  申请人：WUHAN CHINA STAR OPTOELECTRONICS SEMICONDUCTOR DISPLAY TECHNOLOGY CO., LTD.

  公开号：US20200373495A1

  公开（公告）日：2020-11-26

  The present application provides a blue fluorescent material and an OLED display panel, wherein the blue fluorescent material is a tetrahedral structure formed by simultaneously connecting a tert-butyl pyrene and a charge carrier transport unit to a same carbon of cyclohexane; wherein the tert-butyl pyrene increases an external quantum efficiency of the OLED display panel, and the tetrahedral structure increases distance between activated particles and reduces a concentration quenching. The charge carrier transport unit improves a balance of the carrier transfer and alleviates a problem that the current OLED display panel has a low luminous efficiency of the blue light material.
• US9512136B2
  申请人：——

  公开号：US9512136B2

  公开（公告）日：2016-12-06