tris(2,2′-bipyridyl)ruthenium(II) | 57881-69-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: tris(2,2′-bipyridyl)ruthenium(II)
• 英文别名: bis(2,2'-bipyridine)ruthenium(II)；{Ru(2,2'-bipyridine)2}(2+)；2-pyridin-2-ylpyridine;ruthenium(2+)
• CAS: 57881-69-3
• 化学式: C₂₀H₁₆N₄Ru
• 分子量: 413.444
• InChiKey: BPBRCLYSUCQTPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.28
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris(2,2′-bipyridyl)ruthenium(II) 、 N,N,N',N'-tetra(n-hexadecyl)-2,2'-bipyridine-4,4'dicarboxamide 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  In-Situ Second-Harmonic Generation and Luminescence Measurements for Structural Characterization of Ruthenium−Polypyridine Complex Monolayers with Two and Four Aliphatic Tails at the Air/Water Interface

  摘要：

  Langmuir monolayer assemblies of ruthenium-polypyridine complexes having two and four aliphatic tails were studied by in-situ optical second-harmonic generation (SHG) and luminescence measurements, together with surface pressure-molecular area (lambda-A) isotherms. As the monolayer was compressed, the four-tailed complex showed a distinct phase transition at a 30-40 mN/m region from phase I (1.3 nm(2) mean molecular area) to phase II (1.1 nm(2)). Excitation with 1064-nm light gave an SHG signal at 532 nm that appeared almost synchronously with the increase of surface pressure, but the p-polarized component of the SHG signal, induced by either p- (parallel to the plane of incidence) or s- (perpendicular to the plane of incidence) polarized fundamental light, showed a different profile upon compression of the monolayer. In the phase II region, the p-polarized component increased steeply, whereas the s-polarized component decreased to almost zero. A significant blue-shift and a longer lifetime of the luminescence signal were also observed in phase II. Thus, a tightly packed structure in which the main hyperpolarizability tensor is directed roughly perpendicular to the water surface is suggested for phase II. For the two-tailed complex, on the other hand, no appreciable phase transitions were observed, only a liquid-expanded phase (0.9 nm(2)). The results are ascribed to differences in the number of long aliphatic tails.

  DOI：

  10.1021/jp983028u
• 作为产物：
  描述：

  tris(2,2'-bipyridine)ruthenium(II) perchlorate 、 溶剂黄146 、 乙腈 以 乙腈 为溶剂， 生成 Ru(2,2'-bipyridine)2(CH3COO)2(1+) 、 Ru(2,2'-bipyridine)2(acetonitrile)(2+) 、 tris(2,2′-bipyridyl)ruthenium(II)
  参考文献：
  名称：

  Online Mass Analysis of Reaction Products by Electrospray Ionization. Photosubstitution of Ruthenium(II) Diimine Complexes

  摘要：

  The first observation of photosubstitution products in electrospray mass spectra is reported. The solvent-coordinated Ru(II) complex ions created by photodissociation of Ru(2,2'-bipyrazine)(3)Cl-2, Ru(2,2'-bipyridine)(3)X(2) (X = Cl- and ClO4-), and the related complexes in acetonitrile solution were directly detected by on-line electrospray mass spectrometry. The mass spectra were well explained in terms of coordinating ability of counterions and solvent. Collision-induced dissociation in the gas phase was an important process particularly for interpretation of photoproducts such as weakly-bound solvent-coordinated complexes. It was found that the electrospray technique, combined with a flowing photoreaction cell, can potentially be used to identify photoproducts or intermediates.

  DOI：

  10.1021/ic00119a007

文献信息

• Online Mass Analysis of Reaction Products by Electrospray Ionization. Photosubstitution of Ruthenium(II) Diimine Complexes
  作者：Ryuichi Arakawa、Jian Lu、Akio Yoshimura、Koichi Nozaki、Takeshi Ohno、Hidekazu Doe、Takekiyo Matsuo

  DOI：10.1021/ic00119a007

  日期：1995.7

  The first observation of photosubstitution products in electrospray mass spectra is reported. The solvent-coordinated Ru(II) complex ions created by photodissociation of Ru(2,2'-bipyrazine)(3)Cl-2, Ru(2,2'-bipyridine)(3)X(2) (X = Cl- and ClO4-), and the related complexes in acetonitrile solution were directly detected by on-line electrospray mass spectrometry. The mass spectra were well explained in terms of coordinating ability of counterions and solvent. Collision-induced dissociation in the gas phase was an important process particularly for interpretation of photoproducts such as weakly-bound solvent-coordinated complexes. It was found that the electrospray technique, combined with a flowing photoreaction cell, can potentially be used to identify photoproducts or intermediates.
• In-Situ Second-Harmonic Generation and Luminescence Measurements for Structural Characterization of Ruthenium−Polypyridine Complex Monolayers with Two and Four Aliphatic Tails at the Air/Water Interface
  作者：Takashi Nakano、Yasuhiro Yamada、Taku Matsuo、Sunao Yamada

  DOI：10.1021/jp983028u

  日期：1998.10.1

  Langmuir monolayer assemblies of ruthenium-polypyridine complexes having two and four aliphatic tails were studied by in-situ optical second-harmonic generation (SHG) and luminescence measurements, together with surface pressure-molecular area (lambda-A) isotherms. As the monolayer was compressed, the four-tailed complex showed a distinct phase transition at a 30-40 mN/m region from phase I (1.3 nm(2) mean molecular area) to phase II (1.1 nm(2)). Excitation with 1064-nm light gave an SHG signal at 532 nm that appeared almost synchronously with the increase of surface pressure, but the p-polarized component of the SHG signal, induced by either p- (parallel to the plane of incidence) or s- (perpendicular to the plane of incidence) polarized fundamental light, showed a different profile upon compression of the monolayer. In the phase II region, the p-polarized component increased steeply, whereas the s-polarized component decreased to almost zero. A significant blue-shift and a longer lifetime of the luminescence signal were also observed in phase II. Thus, a tightly packed structure in which the main hyperpolarizability tensor is directed roughly perpendicular to the water surface is suggested for phase II. For the two-tailed complex, on the other hand, no appreciable phase transitions were observed, only a liquid-expanded phase (0.9 nm(2)). The results are ascribed to differences in the number of long aliphatic tails.