2,3,7,8,12,13-Hexaethoxy-10,15-dihydro-5H-tribenzocyclononen | 1506-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,3,7,8,12,13-Hexaethoxy-10,15-dihydro-5H-tribenzocyclononen
• 英文别名: 2,3,7,8,12,13-hexaethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene；2,3,7,8,12,13-Hexaaethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen；2,3,7,8,12,13-Hexaethoxy-10,15-dihydro-5H-tribenzo[A,D,G]cyclononene；5,6,12,13,19,20-hexaethoxytetracyclo[15.4.0.03,8.010,15]henicosa-1(21),3,5,7,10,12,14,17,19-nonaene
• CAS: 1506-27-0
• 化学式: C₃₃H₄₂O₆
• mdl: MFCD05854717
• 分子量: 534.693
• InChiKey: IWJWAWDBOXNNCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  39
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 邻苯二乙醚 在 硫酸 、 溶剂黄146 作用下， 生成 2,3,7,8,12,13-Hexaethoxy-10,15-dihydro-5H-tribenzocyclononen
  参考文献：
  名称：

  Arcoleo; Garofano, Annali di Chimica, 1956, vol. 46, p. 934,936

  摘要：

  DOI：

文献信息

• OLEFIN POLYMERIZATION CATALYST COMPRISING CYCLOTRIVERATRYLENE AND DERIVATIVES THEREOF
  申请人：China Petroleum & Chemical Corporation

  公开号：EP3656754A1

  公开（公告）日：2020-05-27

  The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M1, M2, M3, M4, M5, M6, M1', M2', M3', M4', M5' and M6' are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, -R1 and -OR2, wherein R1 and R2 are each independently a C1-C10 hydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C1-C10 alkoxy and heteroatoms; and wherein, when among M1-M6 and M1'-M6', any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of R1 and -OR2, the two adjacent groups may optionally be linked to form a ring, with a proviso that M1, M2, M3, M4, M5, M6, M1', M2', M3', M4', M5' and M6' are not simultaneously hydrogen.

  本发明公开了一种用于烯烃聚合的齐格勒-纳塔催化剂体系，该催化剂体系包括至少一种由式(I)表示的化合物作为(i)内部电子供体，(ii)外部电子供体，或(iii)两者，其中M1、M2、M3、M4、M5、M6、M1'、M2'、M3'、M4'、M5'和M6'各自独立地选自氢、羟基、氨基、醛基、羧基、酰基、卤原子、-R1和-OR2组成的组、羟基、氨基、醛基、羧基、酰基、卤素原子、-R1 和 -OR2，其中 R1 和 R2 各自独立地为 C1-C10 碳氢基，该碳氢基未被取代或被选自羟基、氨基、醛基、羧基、酰基、卤素原子、C1-C10 烷氧基和杂原子组成的组的取代基取代；其中，当M1-M6和M1'-M6'中，同一苯环上的任意两个相邻基团各自独立地选自R1和-OR2组成的组时，这两个相邻基团可任选连接形成一个环，但M1、M2、M3、M4、M5、M6、M1'、M2'、M3'、M4'、M5'和M6'不能同时为氢。
• Olefin polymerization catalyst comprising cyclotriveratrylene and derivatives thereof
  申请人：CHINA PETROLEUM & CHEMICAL CORPORATION

  公开号：US11401356B2

  公开（公告）日：2022-08-02

  The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M1, M2, M3, M4, M5, M6, M1′, M2′, M3′, M4′, M5′ and M6′ are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, —R1 and —OR2, wherein R1 and R2 are each independently a C1-C10 hydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C1-C10 alkoxy and heteroatoms; and wherein, when among M1-M6 and M1′-M6′, any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of R1 and —OR2, the two adjacent groups may optionally be linked to form a ring, with a proviso that M1, M2, M3, M4, M5, M6, M1′, M2′, M3′, M4′, M5′ and M6′ are not simultaneously hydrogen.

  本发明公开了一种用于烯烃聚合的齐格勒-纳塔催化剂体系，它包括至少一种由式(I)代表的化合物作为(i)内部电子供体、(ii)外部电子供体，或(iii)两者，其中 M1、M2、M3、M4、M5、M6、M1′、M2′、M3′、M4′、M5′和 M6′各自独立地选自氢组成的组、羟基、氨基、醛基、羧基、酰基、卤素原子、-R1 和 -OR2，其中 R1 和 R2 各自独立地为 C1-C10 碳氢基，该碳氢基未被取代或被选自羟基、氨基、醛基、羧基、酰基、卤素原子、C1-C10 烷氧基和杂原子的取代基取代；其中，当在 M1-M6 和 M1′-M6′ 之间时，同一苯环上的任何两个相邻基团各自独立地选 自由 R1 和 -OR2 组成的组、这两个相邻基团可任选连接形成一个环，但 M1、M2、M3、M4、M5、M6、M1′、M2′、M3′、M4′、M5′和 M6′不能同时为氢。
• Arcoleo; Garofano, Annali di Chimica, 1956, vol. 46, p. 934,936
  作者：Arcoleo、Garofano

  DOI：——

  日期：——
• 316. The structure of cyclotriveratrylene (10,15-dihydro-2,3,7,8,12,13-hexamethoxy-5H-tribenzo[a,d,g]cyclononene) and related compounds
  作者：A. S. Lindsey

  DOI：10.1039/jr9650001685

  日期：——