N-Phenylsulfonyl-N'-p-tolylsulfonyl-hydrazin | 37049-79-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Phenylsulfonyl-N'-p-tolylsulfonyl-hydrazin
• 英文别名: 4-Methyl-2-(phenylsulfonyl)benzenesulfonic acid hydrazide；N'-(benzenesulfonyl)-4-methylbenzenesulfonohydrazide
• CAS: 37049-79-9
• 化学式: C₁₃H₁₄N₂O₄S₂
• 分子量: 326.397
• InChiKey: XUZFNRWJIVNRGV-UHFFFAOYSA-N

物化性质

• 熔点：
  224-225 °C(Solv: ethanol (64-17-5); water (7732-18-5))
• 沸点：
  501.2±43.0 °C(Predicted)
• 密度：
  1.390±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-Phenylsulfonyl-N'-p-tolylsulfonyl-hydrazin 在 硝酸 作用下， 反应 4.0h， 以67%的产率得到phenyl-p-tolyldisulfone
  参考文献：
  名称：

  Eine einfache und allgemeine Methode zur Herstellung von α-Disulfonen (R¹SO₂SO₂R²)

  摘要：

  一种简便通用的α-二砜制备方法 α-二砜（R1SO2SO2R2）的二烷基、二芳基及烷基芳基二砜可以通过硝酸氧化N,N′-二磺酰肼来轻松制备。该方法适用于硫原子上多种取代基（R1，R2）。

  DOI：

  10.1055/s-1993-25891
• 作为产物：
  描述：

  4-甲基苯磺酸-4-硝基苯酯 、 苯磺酰肼 在 potassium chloride 作用下， 以 乙醇 、 水 为溶剂， 生成 N-Phenylsulfonyl-N'-p-tolylsulfonyl-hydrazin
  参考文献：
  名称：

  Savelova; Karpichev; Simanenko, Russian Journal of Organic Chemistry, 1996, vol. 32, # 4, p. 530 - 539

  摘要：

  DOI：

文献信息

• Highly functionalized pyrazolines from symmetric and asymmetric 1,2-disulfonylhydrazines: a combination of experimental and DFT perspectives
  作者：Nasimeh Safari、Gholamhassan Imanzadeh、Roghayyeh Asgharzadeh、Seyyedeh Tahereh Hosseyni、Amir Nasser Shamkhali、Zahra Soltanzadeh

  DOI：10.1007/s10593-021-02962-y

  日期：2021.6

  In this work, new pyrazole derivatives were prepared by one-pot three-component reaction emloying symmetric and asymmetric 1,2-disulfonyl-hydrazines, cyclohexyl isocyanide, and dialkyl acetylenedicarboxylates. Reactions with asymmetric 1,2-disulfonylhydrazines led to two regioisomers, which were distinguished by density functional theory calculations and the major isomer attributed to the energically more stable one.

  本研究采用对称和不对称的 1,2-二磺酰肼、环己基异氰酸酯和乙炔二羧酸二烷基酯，通过一锅三组份反应制备了新的吡唑衍生物。与不对称 1,2-二磺酰基肼的反应产生了两种区域异构体，密度泛函理论计算对这两种异构体进行了区分，并认为主要异构体是能量更稳定的异构体。
• ELECTROLUMINESCENT DEVICE INCLUDING AN ANTHRACENE DERIVATIVE
  申请人：Eastman Kodak Company

  公开号：EP2013314A1

  公开（公告）日：2009-01-14
• [EN] PHOTOGRAPHIC ELEMENT CONTAINING IMPROVED PYRAZOLOTRIAZOLE COUPLER<br/>[FR] ELEMENT PHOTOGRAPHIQUE CONTENANT UN AGENT DE COUPLAGE PYRAZOLOTRIAZOLE AMELIORE
  申请人：EASTMAN KODAK CO

  公开号：WO2005033796A1

  公开（公告）日：2005-04-14

  Disclosed is photographic element comprising a light-sensitive silver halide emulsion layer containing a 1H-pyrazolo[1,5-b][1,2,4]triazole containing in the 6-position a fully substituted methyl group, in the 7-position a hydrogen atom or halogen atom, and in the 2-position a phenyl group substituted in the meta position with a sulfonamide group free of amide, sulfonamide, ureido or ester groups and bearing at least 9 (cyclo)aliphatic carbon atoms. The element exhibits improved resistance to coupler crystallization.
• [EN] AGGREGATE ORGANIC LIGHT EMITTING DIODE DEVICES<br/>[FR] DISPOSITIFS A DIODES ELECTROLUMINESCENTES ORGANIQUES AGREGES
  申请人：EASTMAN KODAK CO

  公开号：WO2005040303A1

  公开（公告）日：2005-05-06

  An organic light emitting device includes a substrate, an anode and a cathode disposed over the substrate, and a luminescent layer disposed between the anode and the cathode wherein the luminescent layer includes a host and at least one dopant. The host of the luminescent layer is selected to include a solid organic material comprising a mixture of at least two components, one of which contains at least one perylene carbocyclic ring structure or at least one mono-aza-perylene or poly-aza-perylene ring structure and is capable of forming both monomer state and an aggregate state.
• [EN] ORGANIC ELEMENT FOR ELECTROLUMINESCENT DEVICES<br/>[FR] ÉLÉMENT ORGANIQUE POUR DISPOSITIFS ÉLECTROLUMINESCENTS
  申请人：EASTMAN KODAK CO

  公开号：WO2005047420A1

  公开（公告）日：2005-05-26

  Disclosed is an OLED device comprising a light-emitting layer (LEL) containing a host and a dopant located between a cathode and an anode wherein the emitter is an orange-red light emitting rubrene derivative represented by the following formula (I), wherein: a) there are identical oxy, aza or thio groups at the 2- and 8-positions; b) the phenyl rings in the 5- and 11-positions contain only para-substituents identical to the oxy, aza or thio groups in paragraph a); c) the phenyl rings in the 6- and 12-positions are substituted; and provided that when a single substituent on both phenyl rings in paragraph c) are present, said substituent is not a methoxy group located at the para-position.