2-(perfluoro-(1,1-bis-isopropyl)-2-propenyl)oxyethyl methacrylate | 100647-15-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(perfluoro-(1,1-bis-isopropyl)-2-propenyl)oxyethyl methacrylate
• 英文别名: 2-[1,1,1,4,5,5,5-Heptafluoro-3-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-4-(trifluoromethyl)pent-2-en-2-yl]oxyethyl 2-methylprop-2-enoate；2-[1,1,1,4,5,5,5-heptafluoro-3-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-4-(trifluoromethyl)pent-2-en-2-yl]oxyethyl 2-methylprop-2-enoate
• CAS: 100647-15-2
• 化学式: C₁₅H₉F₁₇O₃
• 分子量: 560.208
• InChiKey: RIULGZMAYQEEEQ-UHFFFAOYSA-N

物化性质

• 沸点：
  305.3±42.0 °C(Predicted)
• 密度：
  1.526±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 1,1,1,4,4,5,5,5-八氟-3-(1,1,1,2,3,3,3-七氟丙烷-2-基)-2-(三氟甲基)戊-2-烯 在 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.08h， 生成 2-(perfluoro-(1,1-bis-isopropyl)-2-propenyl)oxyethyl methacrylate
  参考文献：
  名称：

  Preparation and characterization of a novel fluorinated acrylate resin

  摘要：

  The novel fluorinated acrylate resin was successfully prepared by solution polymerization of 2(perfluoro-(1,1-bis-isopropyl)-2-propenyl)oxyethyl methacrylate (POMA) with butyl acrylate (BA), methyl methacrylate (MMA) and methacrylic acid (MAA) initiated by AIBN in the co-solvents of ethyl acetate, butyl alcohol and toluene. POMA was synthesized from the intermediate perfluoro nonene and 2-hydroxyethyl methacrylate as the staring reactants. Films of the novel fluorinated acrylate resin were prepared by coating the resin directly on the clean glass sheet and allowed to dry at room temperature. The characteristics of the film such as hydrophobicity, glass transition temperature and thermal stability were characterized with the contact angle, differential scanning calorimetry and thermo-gravimetric analysis respectively. The structure of the novel fluorinated acrylate resin was investigated by Fourier transform infrared (FTIR) spectrometry. The influences of the fluorine content on the performance of the acrylate resin were studied. Results show that the hydrophobicity, chemical resistance, glass transition temperature and thermal stability of the acrylate resin are improved when the fluorinated monomer is introduced to copolymerize with other monomers. However, the hydrophobicity of the fluorinated acrylate resin is improved slightly via annealing. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2010.03.009

文献信息

• (메트)아크릴레이트계 공중합체, 항균제, 항균성 부여 수지 조성물 및 대전 방지성 부여 수지 조성물
  申请人：NEOS CO., LTD. 네오스 컴파니 리미티드(519980600540)

  公开号：KR20150028820A

  公开（公告）日：2015-03-16

  본 발명은 하기 단량체 (1), 단량체 (2) 를 공중합 성분으로서 포함하는 (메트)아크릴레이트계 공중합체를 제공한다 : 단량체 (1) : 트리메틸암모늄 함유 (메트)아크릴계 모노머 [화학식 1] [식 중, R, R, Y, X, W 는 명세서에 정의되는 바와 같다.] 단량체 (2) : 불소 함유 (메트)아크릴레이트 [화학식 2] [식 중, Rf, R, R, Z 는 명세서에 정의되는 바와 같다.]

  本发明提供了包含以下单体（1）、单体（2）作为共聚物组分的（甲基）丙烯酸酯共聚物： 单体（1）：含有三甲基铵基团的（甲基）丙烯酸单体[化学式1] [其中，R、R、Y、X、W如说明书中所定义。] 单体（2）：含氟的（甲基）丙烯酸酯[化学式2] [其中，Rf、R、R、Z如说明书中所定义。]
• Fluorine-containing copolymer, composition for forming film, and optical film
  申请人：FUJIFILM Corporation

  公开号：US11078314B2

  公开（公告）日：2021-08-03

  A copolymer includes a repeating unit of Formula (I) and a repeating unit of Formula (II), a composition includes the copolymer, and an optical film has a layer formed of the composition, in the Formulae (I) and (II), R1 and R2 represent a hydrogen atom or an alkyl group, L3 and L1 represent a divalent linking group, L2 represents a single bond or a divalent linking group, and L4 represents a single bond or a divalent linking group, L4 does not represent a linking group including —O(C═O)—NH—, X represents a perfluoropolyether group, an alkyl group having a branched structure in which hydrogen is all substituted into fluorine, an alkenyl group, or an alkynyl group, and Y represents a crosslinking group.

  一种共聚物包括式（I）的重复单元和式（II）的重复单元，一种组合物包括该共聚物，一种光学薄膜具有由该组合物形成的层、 在式 (I) 和 (II) 中，R1 和 R2 代表氢原子或烷基，L3 和 L1 代表二价连接基团，L2 代表单键或二价连接基团，L4 代表单键或二价连接基团、L4不代表包括-O(C═O)-NH-在内的连接基团，X代表全氟聚醚基团、具有支链结构的烷基（其中氢被全部取代为氟）、烯基或炔基，Y代表交联基团。