1,6,7,12-tetrachloroperylenbisbenzimidazole | 170239-04-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,6,7,12-tetrachloroperylenbisbenzimidazole
• 英文别名: 18,21,36,40-Tetrachloro-7,14,25,32-tetrazaundecacyclo[21.13.2.22,5.03,19.04,16.06,14.08,13.020,37.025,33.026,31.034,38]tetraconta-1(36),2(40),3,5(39),6,8,10,12,16,18,20,22,26,28,30,32,34,37-octadecaene-15,24-dione
• CAS: 170239-04-0
• 化学式: C₃₆H₁₂Cl₄N₄O₂
• 分子量: 674.329
• InChiKey: YRGXRCLDENFAKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  46
• 可旋转键数：
  0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  邻苯二胺 、 1,6,7,12-四氯-3,4,9,10-苝四甲酸二酐 在 溶剂黄146 作用下， 反应 6.0h， 生成 1,6,7,12-tetrachloroperylenbisbenzimidazole 、 1,6,7,12-tetrachloroperylenbisbenzimidazole
  参考文献：
  名称：

  新型苝-3,4:9,10-双(二甲酰亚胺)和苝-3,4:9,10-双(苯并咪唑)衍生物的合成、电化学和光吸收性能

  摘要：

  一系列在海湾被二或四取代的苝-3,4:9,10-双（二甲酰亚胺）（PBI）和苝-3,4:9,10-双（苯并咪唑）（PTCBI）衍生物通过给电子或吸电子基团的区域已被合成为可溶性 n 型半导体。光吸收光谱和电化学分析表明，湾区的取代性质在调节这些 PBI 和 PTCBI 衍生物的电子特性中起着至关重要的作用。根据理论研究确定的能级检查这些光学和电化学数据，可以建立结构和电子特性之间的关系。

  DOI：

  10.1002/ejoc.201100513

文献信息

• Method for producing organic field-effect transistors
  申请人：BASF Aktiengesellschaft

  公开号：US07910736B2

  公开（公告）日：2011-03-22

  A method for producing an organic field-effect transistor, comprising the steps of: a) providing a substrate comprising a gate structure, a source electrode and a drain electrode located on the substrate, and b) applying an n-type organic semiconducting compound to the area of the substrate where the gate structure, the source electrode and the drain electrode are located, wherein the n-type organic semiconducting compound is selected from the group consisting of compounds of the formula I wherein R1, R2, R3and R4are independently hydrogen, chlorine or bromine, with the proviso that at least one of these radicals is not hydrogen, Y1 is O or NRa, wherein Ra is hydrogen or an organyl residue, Y2 is O or NRb, wherein Rb is hydrogen or an organyl residue, Z1, Z2, Z3 and Z4 are O, where, in the case that Y1 is NRa, one of the residues Z1 and Z2 may be a NRc group, where Ra and Rc together are a bridging group having 2 to 5 atoms between the terminal bonds, where, in the case that Y2 is NRb, one of the residues Z3 and Z4 may be a NRd group, where Rb and Rd together are a bridging group having 2 to 5 atoms between the terminal bonds.

  一种生产有机场效应晶体管的方法，包括以下步骤：a）提供包括栅结构、位于基底上的源电极和漏电极的基底，并b）将n-型有机半导体化合物应用于基底上栅结构、源电极和漏电极所在的区域，其中n-型有机半导体化合物选自以下化合物组：式I的化合物其中R1、R2、R3和R4独立地是氢、氯或溴，但至少其中一个基团不是氢，Y1是O或NRa，其中Ra是氢或有机残基，Y2是O或NRb，其中Rb是氢或有机残基，Z1、Z2、Z3和Z4是O，在Y1是NRa的情况下，残基Z1和Z2中的一个可以是NRc基团，其中Ra和Rc一起是具有2到5个原子的端部键之间的桥连接基团，在Y2是NRb的情况下，残基Z3和Z4中的一个可以是NRd基团，其中Rb和Rd一起是具有2到5个原子的端部键之间的桥连接基团。
• Compound, solar cell module, and solar power generation device
  申请人：Sharp Kabushiki Kaisha

  公开号：US09343686B2

  公开（公告）日：2016-05-17

  A compound is represented by the following general formula (IA0) or (IB0). A solar cell module for which the compound is used is used for a solar power generation device.

  化合物由以下通式（IA0）或（IB0）表示。使用该化合物的太阳能电池模块用于太阳能发电设备。
• METHOD FOR PRODUCING ORGANIC FIELD-EFFECT TRANSISTORS
  申请人：Konemann Martin

  公开号：US20070259475A1

  公开（公告）日：2007-11-08

  A method for producing an organic field-effect transistor, comprising the steps of: a) providing a substrate comprising a gate structure, a source electrode and a drain electrode located on the substrate, and b) applying an n-type organic semiconducting compound to the area of the substrate where the gate structure, the source electrode and the drain electrode are located, wherein the n-type organic semiconducting compound is selected from the group consisting of compounds of the formula I wherein R 1 , R 2 , R 3 and R 4 are independently hydrogen, chlorine or bromine, with the proviso that at least one of these radicals is not hydrogen, Y 1 is O or NR a , wherein R a is hydrogen or an organyl residue, Y 2 is O or NR b , wherein R b is hydrogen or an organyl residue, Z 1 , Z 2 , Z 3 and Z 4 are O, where, in the case that Y 1 is NR a , one of the residues Z 1 and Z 2 may be a NR c group, where R a and R c together are a bridging group having 2 to 5 atoms between the terminal bonds, where, in the case that Y 2 is NR b , one of the residues Z 3 and Z 4 may be a NR d group, where R b and R d together are a bridging group having 2 to 5 atoms between the terminal bonds.
• COMPOUND, SOLAR CELL MODULE, AND SOLAR POWER GENERATION DEVICE
  申请人：Sharp Kabushiki Kaisha

  公开号：US20150162547A1

  公开（公告）日：2015-06-11

  A compound is represented by the following general formula (IA0) or (IB0). A solar cell module for which the compound is used is used for a solar power generation device.
• US7910736B2
  申请人：——

  公开号：US7910736B2

  公开（公告）日：2011-03-22