6-nitroperylo[1,12-b,c,d]thiophene | 1261152-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 6-nitroperylo[1,12-b,c,d]thiophene
• 英文别名: 5-Nitro-12-thiahexacyclo[11.8.0.02,11.03,8.04,20.016,21]henicosa-1(13),2(11),3(8),4,6,9,14,16(21),17,19-decaene；5-nitro-12-thiahexacyclo[11.8.0.02,11.03,8.04,20.016,21]henicosa-1(13),2(11),3(8),4,6,9,14,16(21),17,19-decaene
• CAS: 1261152-92-4
• 化学式: C₂₀H₉NO₂S
• 分子量: 327.363
• InChiKey: UHMVEPXVPFCUGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6-nitroperylo[1,12-b,c,d]thiophene 在 sulfur 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 5.0h， 以61%的产率得到thieno<2,3,4,5-i,k,l>perylo<6,6a,6b,7-c,d,e>-1,2-dithiin
  参考文献：
  名称：

  Solution-Processed, High-Performance Nanoribbon Transistors Based on Dithioperylene

  摘要：

  Solution-processed, high-performance 1D single-crystalline nanoribbon transistors fabricated from dithioperylene are described. The integration of two sulfur atoms into the perylene skeleton induces a compressed highly ordered packing mode directed by S center dot center dot center dot S interactions. The mobilities of up to 2.13 cm(2) V-1 s(-1) for a dithioperylene individual nanoribbon make it particularly attractive for electronic applications.

  DOI：

  10.1021/ja107599r
• 作为产物：
  描述：

  二萘嵌苯并[1,12-bcd]噻吩 在 硝酸 作用下， 以 1,4-二氧六环 、 水 为溶剂， 以15%的产率得到6-nitroperylo[1,12-b,c,d]thiophene
  参考文献：
  名称：

  Solution-Processed, High-Performance Nanoribbon Transistors Based on Dithioperylene

  摘要：

  Solution-processed, high-performance 1D single-crystalline nanoribbon transistors fabricated from dithioperylene are described. The integration of two sulfur atoms into the perylene skeleton induces a compressed highly ordered packing mode directed by S center dot center dot center dot S interactions. The mobilities of up to 2.13 cm(2) V-1 s(-1) for a dithioperylene individual nanoribbon make it particularly attractive for electronic applications.

  DOI：

  10.1021/ja107599r

文献信息

• [EN] NOVEL ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME<br/>[FR] NOUVEAU COMPOSÉ ORGANIQUE ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：DOOSAN CORP

  公开号：WO2014098455A1

  公开（公告）日：2014-06-26

  본 발명은 페난트로카바졸에 헤테로 원자를 포함하는 환이 융합되어 기본 골격을 이루며, 이러한 기본 골격에 다양한 치환체가 결합되는 신규 구조의 화합물 및 이를 포함하는 유기 전계 발광 소자에 관한 것이다. 본 발명에서는 상기 화합물을 하나 이상의 유기층, 바람직하게는 발광층에 포함함으로써, 소자의 발광효율, 구동 전압, 수명 등이 향상될 수 있다.
• Solution-Processed, High-Performance Nanoribbon Transistors Based on Dithioperylene
  作者：Wei Jiang、Yan Zhou、Hua Geng、Shidong Jiang、Shouke Yan、Wenping Hu、Zhaohui Wang、Zhigang Shuai、Jian Pei

  DOI：10.1021/ja107599r

  日期：2011.1.12

  Solution-processed, high-performance 1D single-crystalline nanoribbon transistors fabricated from dithioperylene are described. The integration of two sulfur atoms into the perylene skeleton induces a compressed highly ordered packing mode directed by S center dot center dot center dot S interactions. The mobilities of up to 2.13 cm(2) V-1 s(-1) for a dithioperylene individual nanoribbon make it particularly attractive for electronic applications.