5-(2-methoxyphenyl)-nona-1,8-dien-5-ol | 1407188-30-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5-(2-methoxyphenyl)-nona-1,8-dien-5-ol
• 英文别名: 5-(2-Methoxyphenyl)nona-1,8-dien-5-ol；5-(2-methoxyphenyl)nona-1,8-dien-5-ol
• CAS: 1407188-30-0
• 化学式: C₁₆H₂₂O₂
• 分子量: 246.349
• InChiKey: XMAMIGOAOWZGKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-(2-methoxyphenyl)-nona-1,8-dien-5-ol 在 苯乙酮 作用下， 以 环己烷 、 乙腈 为溶剂， 反应 14.0h， 生成 rac-(1S,2S,5S,7R,8S,11S)-2-hydroxy-2-(but-3-enyl)-11-methoxytetracyclo[5.3.1.0^1,5.0^8,11]undec-9-ene
  参考文献：
  名称：

  Investigating the Photochemical Properties of an Arenyl Dienol

  摘要：

  Upon irradiation with UV light, an arenyl dienol was transformed into linear and angular meta photocycloadducts and ortho derived photoadducts. Extended exposure to UV radiation resulted in the formation of other degradation products, which shed light on the chemical processes taking place. One of the linear meta photocycloadducts was thermally unstable and underwent further thermal and photochemical transformation, while the ortho-derived photocycloadducts ring-opened and eliminated methanol to afford a cyclooctadienone product.

  DOI：

  10.1021/ol302718p
• 作为产物：
  描述：

  4-溴-1-丁烯 、 2-甲氧基苯甲酸甲酯 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 6.25h， 以67%的产率得到5-(2-methoxyphenyl)-nona-1,8-dien-5-ol
  参考文献：
  名称：

  Investigating the Photochemical Properties of an Arenyl Dienol

  摘要：

  Upon irradiation with UV light, an arenyl dienol was transformed into linear and angular meta photocycloadducts and ortho derived photoadducts. Extended exposure to UV radiation resulted in the formation of other degradation products, which shed light on the chemical processes taking place. One of the linear meta photocycloadducts was thermally unstable and underwent further thermal and photochemical transformation, while the ortho-derived photocycloadducts ring-opened and eliminated methanol to afford a cyclooctadienone product.

  DOI：

  10.1021/ol302718p

文献信息

• Investigating the Photochemical Properties of an Arenyl Dienol
  作者：Clive S. Penkett、Jason A. Woolford

  DOI：10.1021/ol302718p

  日期：2012.11.16

  Upon irradiation with UV light, an arenyl dienol was transformed into linear and angular meta photocycloadducts and ortho derived photoadducts. Extended exposure to UV radiation resulted in the formation of other degradation products, which shed light on the chemical processes taking place. One of the linear meta photocycloadducts was thermally unstable and underwent further thermal and photochemical transformation, while the ortho-derived photocycloadducts ring-opened and eliminated methanol to afford a cyclooctadienone product.