2,2-bis(4-hydroxy-3-propylphenyl)hexafluoropropane | 137400-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis(4-hydroxy-3-propylphenyl)hexafluoropropane
• 英文别名: 4,4'-(Hexafluoroisopropylidene)bis(2-propylphenol)；4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-propylphenyl)propan-2-yl]-2-propylphenol
• CAS: 137400-38-5
• 化学式: C₂₁H₂₂F₆O₂
• 分子量: 420.395
• InChiKey: LRGHXOUHGUEIAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,2-bis(4-hydroxy-3-propylphenyl)hexafluoropropane 在 potassium carbonate 、 N,N-二乙基苯胺 作用下， 以 丙酮 为溶剂， 反应 59.0h， 生成 4,4'-(perfluoropropane-2,2-diyl)bis(2-allyl-6-propylphenol)
  参考文献：
  名称：

  BISPHENOL HYPERSORBENTS FOR ENHANCED DETECTION OF, OR PROTECTION FROM, HAZARDOUS CHEMICALS

  摘要：

  本发明涉及强氢键酸性吸附剂。该吸附剂可以以一种形式提供，该形式限制或消除氢键酸性位点在相邻吸附剂分子之间的分子内键合，例如，通过在氢键酸性位点旁边提供立体阻碍基团。氢键位点可以是基于双酚体系结构的酚结构。本发明的吸附剂可以用于捕获或检测危险化学品或爆炸物的方法中。

  公开号：

  US20190134601A1
• 作为产物：
  描述：

  2,2-bis(3-allyl-4-hydroxyphenyl)hexafluoropropane 在 palladium on activated charcoal 氢气 作用下， 以 氯仿 为溶剂， 反应 3.5h， 以96%的产率得到2,2-bis(4-hydroxy-3-propylphenyl)hexafluoropropane
  参考文献：
  名称：

  Abraham, Michael H.; Hamerton, Ian; Rose, John B., Journal of the Chemical Society. Perkin transactions II, 1991, # 9, p. 1417 - 1423

  摘要：

  DOI：

文献信息

• Optical Element and Achromatic Lens
  申请人：Hatanaka Kunio

  公开号：US20090143560A1

  公开（公告）日：2009-06-04

  There are provided an optical element that comprises a polymer which has a structural unit derived from a specific dihydroxy compound typified by 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoro propane (bisphenol AF) and in which the relationship between a refractive index n D and an Abbe number ν D satisfies the following formula (I): n D +0.0076×ν D ≦1.78  (I) and that is used for correction of chromatic aberration, and an achromatic lens using the optical element.

  提供了一种光学元件，其包括一种聚合物，该聚合物具有从特定的二羟基化合物中导出的结构单元，该二羟基化合物以2,2-双(4-羟基苯基)-1,1,1,3,3,3-六氟丙烷（双酚AF）为代表，并且折射率nD和阿贝数νD之间的关系满足以下公式（I）：nD+0.0076×νD≦1.78（I），并且用于矫正色差，以及使用该光学元件的消色差透镜。
• OPTICAL DEVICE AND ACHROMATIC LENS
  申请人：Teijin Chemicals, Ltd.

  公开号：EP1947131A1

  公开（公告）日：2008-07-23

  There are provided an optical element that comprises a polymer which has a structural unit derived from a specific dihydroxy compound typified by 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoro propane (bisphenol AF) and in which the relationship between a refractive index nD and an Abbe number νD satisfies the following formula (I): nD+0.0076×νD≤1.78 and that is used for correction of chromatic aberration, and an achromatic lens using the optical element.

  提供了一种光学元件，它由一种聚合物组成，该聚合物的结构单元来源于一种特定的二羟基化合物，典型的是 2,2-双（4-羟基苯基）-1,1,1,3,3,3-六氟丙烷（双酚 AF），其中折射率 nD 和阿贝数 νD 之间的关系满足下式（I）：nD+0.0076×νD≤1.78。 用于校正色差，以及使用该光学元件的消色差透镜。
• Bisphenol hypersorbents for enhanced detection of, or protection from, hazardous chemicals
  申请人：The Government of the United States of America, as represented by the Secretary of the Navy

  公开号：US11325100B2

  公开（公告）日：2022-05-10

  The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.

  本发明涉及强氢键酸性吸附剂。这种吸附剂的形式可以限制或消除相邻吸附剂分子之间的氢键酸性位点的分子内键合，例如，在氢键酸性位点附近提供立体基团。氢键位点可以是基于双酚结构的酚醛结构。本发明的吸附剂可用于捕获或检测危险化学品或爆炸物的方法中。
• FUSER MEMBER HAVING COMPOSITE OUTER LAYER
  申请人：Xerox Corporation

  公开号：EP2248849B1

  公开（公告）日：2017-07-26
• Bisphenol Hypersorbents for Enhanced Detection of, or Protection From, Hazardous Chemicals
  申请人：The Government of the United States of America, as represented by the Secretary of the Navy

  公开号：US20220258125A1

  公开（公告）日：2022-08-18

  The invention relates to strong hydrogen-bond acidic sorbents. The sorbents may be provided in a form that limits or eliminates intramolecular bonding of the hydrogen-bond acidic site between neighboring sorbent molecules, for example, by providing steric groups adjacent to the hydrogen-bond acidic site. The hydrogen bond site may be a phenolic structure based on a bisphenol architecture. The sorbents of the invention may be used in methods for trapping or detecting hazardous chemicals or explosives.