苯乙酸-反-2-己烯酯 | 68133-78-8

• 物质功能分类: 化学试剂 - 有机试剂 - 烯烃（环状与无环状）
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯乙酸-反-2-己烯酯
• 中文别名: 反式-2-己烯醇苯乙酸酯；苯乙酸反-2-己烯-1-基酯；反-2-己烯苯乙酸酯
• 英文名称: trans-2-hexen-1-yl phenylacetate
• 英文别名: trans-hex-2-enyl phenylacetate ；(2E)-hex-2-enyl phenylacetate；(E)-hex-2-enyl phenylacetate；2-Hexenyl phenylacetate；[(E)-hex-2-enyl] 2-phenylacetate
• CAS: 68133-78-8
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: BYGAPGDXGHDYGP-XBXARRHUSA-N

物化性质

• 密度：
  0.99
• LogP：
  4.391 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916399090

反应信息

• 作为反应物：
  描述：

  甲基二氯硅烷 、 苯乙酸-反-2-己烯酯 在 platinum-diethylenetriaminetetraacetate complex anchored on magnetite-silica core-shell nanoparticles 作用下， 以 neat (no solvent) 为溶剂， 反应 6.5h， 生成 、
  参考文献：
  名称：

  A magnetically recyclable superparamagnetic silica supported Pt nanocatalyst through a multi-carboxyl linker: synthesis, characterization, and applications in alkene hydrosilylation

  摘要：

  为了简化分离程序，提高可重复使用性并减少Pt的损失，首次制备了两种Pt催化剂，它们被锚定在超顺磁性二氧化硅上（Fe₃O₄@SiO₂-EDTA@Pt和Fe₃O₄@SiO₂-DTPA@Pt）。

  DOI：

  10.1039/c9ra00375d

文献信息

• Use of unsaturated esters as perfuming ingredients
  申请人：——

  公开号：US20020055455A1

  公开（公告）日：2002-05-09

  The compound of formula 1 in which the wavy line represents a bond having a configuration of the type (Z) or (E), or a mixture of the two configurations; R 1 represents a hydrogen atom, a C 1 to C 4 linear or branched alkyl radical, a methoxy or ethoxycarbonyl radical, or an aryl radical, and R 2 represents a methyl or ethyl group, possess interesting organoleptic properties and can be advantageously used for the preparation of perfuming compositions to which it gives, in particular, a very natural connotation of the pear type.

  公式1的化合物中，波浪线代表具有(Z)或(E)类型配置或两种配置的混合物的键；R1代表氢原子，C1到C4的线性或支链烷基基团，甲氧基或乙氧基羰基基团或芳基基团，而R2代表甲基或乙基基团。这些化合物具有有趣的感官特性，并可优势地用于制备香料组合物，尤其是对于梨型香调，能赋予其非常自然的涵义。
• Air freshening compositions, articles comprising same and methods
  申请人：The Procter & Gamble Company

  公开号：US20030024997A1

  公开（公告）日：2003-02-06

  An air freshening composition including porous carrier particles having a perfume composition entrapped therein, and a second component selected from an inert filer, hygroscopic agent, binder, coating material, moisture providing agent, and mixtures thereof. The composition may further comprise various optional components such as free perfumes, colorants, disintegrants, water swelling agents, porosity modifiers and mixtures thereof. A method for processing the compositions into a solid article includes the steps of entrapping a perfume in the porous carrier particles, heating and incorporating a carrier or binder material. The compositions may be further processed by optionally incorporating a powder inert filler and forming articles from the mixture. The articles may be formed from the compositions through prilling, extrusion, or compaction amongst other techniques. The air freshening articles and compositions will provide a sustained and controlled release of the perfume compositions over a long period of time without the use of a heat to activate the release. Articles of manufacture including the air freshening articles and various packaging are also disclosed.

  一种空气清新组合物，包括内含香水组合物的多孔载体颗粒，以及选自惰性过滤剂、吸湿剂、粘合剂、涂层材料、保湿剂及其混合物的第二种成分。组合物还可进一步包含各种可选成分，如游离香料、着色剂、崩解剂、水膨胀剂、孔隙度调节剂及其混合物。将组合物加工成固体物品的方法包括以下步骤：在多孔载体颗粒中夹带香水、加热和加入载体或粘合剂材料。组合物还可以通过加入粉末惰性填料进一步加工，并由混合物形成物品。除其他技术外，还可以通过挤压、挤出或压制等方法将混合物制成物品。这种空气清新剂制品和组合物可以在长时间内持续、可控地释放香水组合物，而无需使用热量来激活释放。此外，还公开了包括空气清新剂和各种包装在内的制造物品。
• Dryer-added fabric softening articles and methods
  申请人：The Procter & Gamble Company

  公开号：US20030013632A1

  公开（公告）日：2003-01-16

  A fabric conditioning article for use in a clothes dryer. The fabric conditioning article having a flexible sheet and a fabric conditioning composition deposited on the sheet. The fabric conditioning composition includes a fabric conditioning agent, perfumed particles and minor components. The perfume particles are a perfume composition incorporated into a porous mineral carrier such as clay and/or zeolite. Optionally, the perfume composition comprises low levels of unstable perfume components. Alternatively, the perfumed particles have a coating material encapsulating at least a portion of the particles. Optionally, the articles are packaged in a container having a moisture barrier to prevent premature release of the perfume therefrom.

  一种用于干衣机的织物护理用品。织物护理用品具有柔性薄片和沉积在薄片上的织物护理组合物。织物护理组合物包括织物护理剂、香水颗粒和次要成分。香水微粒是掺入多孔矿物载体（如粘土和/或沸石）中的香水组合物。可选地，香水组合物包括低含量的不稳定香水成分。或者，香水颗粒具有包覆至少部分颗粒的涂层材料。可选地，物品包装在具有防潮层的容器中，以防止香水从容器中过早释放。
• Consumable composition comprising perfumed particles and article containing the same
  申请人：The Procter & Gamble Company

  公开号：US20030036489A1

  公开（公告）日：2003-02-20

  Perfume delivery compositions and/or consumable compositions that include perfumed particles made of a porous inorganic mineral carrier and a perfume composition absorbed and/or adsorbed thereon. The perfume composition having low levels of certain classes of perfume ingredients that tend to be unstable when incorporated onto or into a porous mineral carrier. Articles of manufacture include the perfume delivery or consumable compositions, and a moisture impermeable container. Optionally, the moisture impermeable container is designed for single use or unit dosing of the compositions. Optionally, the moisture impermeable container is designed for bulk compositions and optionally includes a reclosable or resealable closure.

  香水递送组合物和/或消耗品组合物，包括由多孔无机矿物载体制成的香水颗粒和吸收和/或吸附在其上的香水组合物。香水组合物中某些类别的香水成分含量较低，这些香水成分在加入多孔矿物载体时往往不稳定。制造物品包括香水输送或消耗组合物，以及防潮容器。可选地，防潮容器是为组合物的一次性使用或单位剂量而设计的。可选地，防潮容器是为散装组合物设计的，并可选地包括一个可重新封闭或重新密封的封口。
• Pharmaceutical compositions comprising flavonoids and menthol
  申请人：Berg Frimann Kurt

  公开号：US20060148726A1

  公开（公告）日：2006-07-06

  The present invention relates to use of certain antiviral fragrances for reduction of viruses, in particular vira causing common cold. In one embodiment, the invention relates to pharmaceutical compositions comprising an antiviral fragrance, preferably menthol. Said compositions preferably also comprise one or more flavonoids. The invention also relates to treatment of common cold using said compositions.

  本发明涉及使用某些抗病毒香料来减少病毒，特别是引起普通感冒的病毒。在一个实施方案中，本发明涉及包含抗病毒香料（最好是薄荷醇）的药物组合物。所述组合物最好还包含一种或多种类黄酮。本发明还涉及使用所述组合物治疗普通感冒。