hexane-1,2-dithiol

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: hexane-1,2-dithiol
• 英文别名: Hexan-1,2-dithiol
• 化学式: C₆H₁₄S₂
• 分子量: 150.309
• InChiKey: FHNYITPJJXPJHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  盐酸 、 hexane-1,2-dithiol 、 丙酮 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Bader et al., Journal of the Chemical Society, 1949, p. 619,622

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 盐酸氨基脲 作用下， 生成 hexane-1,2-dithiol
  参考文献：
  名称：

  Bader et al., Journal of the Chemical Society, 1949, p. 619,622

  摘要：

  DOI：

文献信息

• Thiophosphine compounds and methods of making polymerizable compositions containing them and their use for making ophthalmic lenses
  申请人：Wanigatunga Sirisoma

  公开号：US20050107579A1

  公开（公告）日：2005-05-19

  Thiophosphine compounds (also named phosphine sulfide compounds) and their use for making polymerizable compositions which after polymerization give optically transparent articles, such as ophthalmic lenses, having improved mechanical and optical properties and in particular having an improved UV cut.

  硫代磷化合物（也称为磷硫化合物），及其用于制备可聚合的组合物，聚合后形成光学透明的制品，例如具有改善机械和光学性能，特别是具有改善紫外线切除的眼科镜片。
• THIOPHOSPHINE COMPOUNDS AND METHODS OF MAKING POLYMERIZABLE COMPOSITIONS CONTAINING THEM AND THEIR USE FOR MAKING OPHTHALMIC LENSES
  申请人：Wanigatunga Sirisoma

  公开号：US20070232834A1

  公开（公告）日：2007-10-04

  Thiophosphine compounds (also named phosphine sulfide compounds) and their use for making polymerizable compositions which after polymerization give optically transparent articles, such as ophthalmic lenses, having improved mechanical and optical properties and in particular having an improved UV cut.

  硫代膦化合物（也称为膦硫化合物）及其用于制备可聚合组合物的方法，聚合后得到具有改善机械和光学性能，特别是具有改善紫外线切割性能的光学透明物品，例如眼镜镜片。
• SULFUR COMPOUND AND USE THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1302471A1

  公开（公告）日：2003-04-16

  This invention provides sulfur-containing (meth)acrylic ester compounds each of which is represented by the following formula (1); wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group or may be fused together to form a ring, R3 represents a hydrogen atom or a methyl group, X1 represents an oxygen atom or a sulfur atom, m stands for an integer of from 0 to 3, and n stands for an integer of from 1 to 4, polymerizable compositions comprising the sulfur-containing (meth)acrylic acids, and cured products and optical parts obtained by polymerizing the polymerizable compositions. The sulfur-containing (meth)acrylic ester compounds according to the present invention are very useful, as monomers for photocurable, polymerizable compositions, in applications such as optical materials and dental materials. The optical parts obtained by curing the polymerizable compositions are excellent in optical properties, thermal properties and mechanical properties and are also good in productivity.

  本发明提供了含硫(甲基)丙烯酸酯化合物，其中每个化合物都由下式(1)表示； 其中 R1 和 R2 各自独立地代表氢原子或烷基，或可融合在一起形成环，R3 代表氢原子或甲基，X1 代表氧原子或硫原子，m 代表 0 至 3 的整数，n 代表 1 至 4 的整数，提供了包含含硫（甲基）丙烯酸的可聚合组合物，以及通过聚合该可聚合组合物获得的固化产品和光学部件。根据本发明的含硫（甲基）丙烯酸酯化合物作为光固化可聚合组合物的单体，在光学材料和牙科材料等应用中非常有用。通过固化可聚合组合物获得的光学部件在光学性能、热性能和机械性能方面都非常出色，而且生产效率也很高。
• Liquid crystal display device
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US10241359B2

  公开（公告）日：2019-03-26

  A liquid crystal display device, whereby transparency when no voltage is applied and scattering properties when a voltage is applied, are good, adhesion between a liquid crystal layer and a vertical liquid crystal alignment film is high, and its lifespan is long even in a severe environment. The liquid crystal display device has a liquid crystal layer formed by disposing a liquid crystal composition containing a liquid crystal and a polymerizable compound between a pair of substrates provided with electrodes, and irradiating and curing the composition with ultraviolet rays by an ultraviolet irradiation apparatus, and at least one substrate is provided with a liquid crystal alignment film to vertically align a liquid crystal, wherein the ultraviolet irradiation apparatus is an ultraviolet irradiation apparatus capable of controlling the irradiation light intensity and wavelength of the ultraviolet rays to be irradiated and the surface temperature of the pair of the substrates.

  一种液晶显示装置，其无电压时的透明度和有电压时的散射性能良好，液晶层和垂直液晶排列膜之间的附着力高，即使在恶劣的环境中也能保持较长的使用寿命。该液晶显示装置具有液晶层，其形成方法是将含有液晶和可聚合化合物的液晶组合物置于一对带有电极的基板之间，并用紫外线照射装置对组合物进行紫外线照射和固化、其中紫外线辐照装置是一种紫外线辐照装置，能够控制要辐照的紫外线的辐照光强度和波长以及这对基板的表面温度。
• Polymerizable compositions for manufacturing transparent polymeric substrates, resulting transparent polymeric substrates and their applications in the optical field
  申请人：Essilor International Compagnie Generale d'Optique

  公开号：US20020115819A1

  公开（公告）日：2002-08-22

  The compositions comprise: (a) at least 40 parts by weight, preferably at least 50 parts by weight, of at least one thio(meth)acrylate monomer, (b) at least one high Abbe number monomer, (c) at the most 20 parts by weight, preferably at the most 15 parts by weight and more preferably 10 parts by weight of an aromatic polyvinyl monomer, and (d) at least one polythiol, for 100 parts by weight of (a), (b), (c) and (d). Application for the manufacture of optical lenses.

  组合物包括 (a) 至少一种硫代(甲基)丙烯酸酯单体，按重量计至少 40 份，最好至少 50 份、 (b) 至少一种高阿贝数单体、 (c) 至多 20 份（按重量计），最好是至多 15 份（按重量计），更可取的是 10 份（按重量计）芳香族聚乙烯单体，以及 (d) 至少一种聚硫醇，以(a)、(b)、(c)和(d)的 100 重量份计。 适用于制造光学镜片。