9,10-二(对甲氧基)苯基蒽(BPEN) | 110904-87-5

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 中文名称: 9,10-二(对甲氧基)苯基蒽(BPEN)
• 中文别名: 9,10-双(4-甲氧基苯基)-2-氯蒽；9,10-二(对甲氧苯基)-2-氯-蒽；2-氯-9,10-双(4-甲氧基苯基)蒽；9,10-二(对甲氧基)苯基蒽；BPEN
• 英文名称: 9,10-Bis(4-methoxyphenyl)-2-chloroanthracene
• 英文别名: 2-chloro-9,10-bis(4-methoxyphenyl)anthracene
• CAS: 110904-87-5
• 化学式: C₂₈H₂₁ClO₂
• mdl: MFCD00009935
• 分子量: 424.9
• InChiKey: ONASMBRWDSADQY-UHFFFAOYSA-N

物化性质

• 熔点：
  240-242 °C(lit.)
• 沸点：
  550.0±50.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.071
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 安全说明：
  S26,S36
• 危险性防范说明：
  P280,P305+P351+P338
• 危险性描述：
  H302

文献信息

• Blue/violet diphenylanthracene chemiluminescent fluorescers
  申请人：Cranor Earl

  公开号：US20100327240A1

  公开（公告）日：2010-12-30

  Compounds are disclosed for the production of chemiluminescent light, particularly for the production of blue/violet light within the range of about 390 nm to less than 438 nm, and most particularly to the use of compounds composed of symmetrically and asymmetrically substituted anthracenes which are effective for increasing the production of such blue/violet light when used as fluorescers in conjunction with chemiluminescent systems. These systems utilize derivatives of 9,10-diphenylanthracene containing one or more fluorines As shown in General Formulae 1-3. The variables shown in Formulae 1-3 are defined in the specification.

  揭示了用于生产化学发光灯的化合物，特别是用于在约390纳米至不到438纳米范围内产生蓝/紫光的化合物，尤其是使用由对称和非对称取代的蒽组成的化合物，这些化合物在与化学发光系统一起作为荧光剂时有效地增加了这种蓝/紫光的产生。这些系统利用含有一个或多个氟的9,10-二苯基蒽衍生物，如通用公式1-3所示。公式1-3中显示的变量在说明书中有定义。
• Anthracene compound and chemiluminescent composition comprising the same
  申请人：——

  公开号：US20030116759A1

  公开（公告）日：2003-06-26

  The present invention discloses an anthracene compound represented by the following formula 4 and chemiluminescent composition comprising the compound: 1 wherein R is an alkyl group having 1-8 carbon atoms, and X 1 and X 2 are independently hydrogen or halogen.

  本发明公开了一种由下式4表示的蒽化合物和包括该化合物的化学发光组合物：1其中R是具有1-8个碳原子的烷基基团，X1和X2分别是氢或卤素。
• A NEW USE OF CARBONATES
  申请人：Jin Chaoyang

  公开号：US20100176355A1

  公开（公告）日：2010-07-15

  This invention publishes new usages of kinds of carbonic ester compounds. The new usage described in this invention is related to the application of carbonic ester compounds in the preparation of solvents for chemiluminescent systems. This invention also provides luminescent compositions, luminescent liquids and oxidized liquids that contain carbonic ester compounds. Chemiluminescent compositions containing carbonic ester compounds can decrease reaction pressure effectively, facilitate reaction balance heading to luminescence reaction, generate larger luminescent output without adding catalyst, decrease the dosage of catalyst or not need adding catalyst, decrease influences of over-high output at the reaction start caused by catalyst on whole luminescent time, and ensure stable light output from luminescent compositions. Carbonic ester compounds, especially long carbon chain carbonic ester, have the characters of non-toxic and high flash point, and have suitable solubility on ordinary bis oxalate ester. Carbonic ester compounds are environment-friendly solvents, which can be widely accepted and recognized no matter in industrial synthesization or in applications.

  本发明公开了各种碳酸酯化合物的新用途。本发明所描述的新用途与碳酸酯化合物在制备化学发光系统溶剂方面的应用有关。本发明还提供了含有碳酸酯化合物的发光组合物、发光液体和氧化液体。含有碳酸酯化合物的化学发光组合物可以有效降低反应压力，促进反应平衡，导致发光反应，生成更大的发光输出，无需添加催化剂，减少催化剂用量或不需要添加催化剂，减少催化剂在整个发光时间内对反应开始时产生的过高输出的影响，并确保发光组合物的稳定光输出。碳酸酯化合物，特别是长碳链碳酸酯，具有无毒和高闪点的特性，并在普通的草酸酯上具有适当的溶解性。碳酸酯化合物是环保溶剂，无论在工业合成还是在应用中都可以被广泛接受和认可。
• High light output-short duration chemiluminescent compositions
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0231923A2

  公开（公告）日：1987-08-12

  Novel activator and oxalate compositions are disclosed which, when combined, result in a chemiluminescent light of high light output and short duration.

  本发明公开了新型活化剂和草酸盐组合物，两者结合后可产生高光输出和短持续时间的化学发光。
• Chemiluminescent composition
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0227086A2

  公开（公告）日：1987-07-01

  Compositions intended to be reacted with hydrogen per­oxide to produce chemiluminescent light are disclosed wherein the compositions contain an oxalate and a fluo­rescer comprising 9,10-bis(4-methoxyphenyl)-2-chloro­anthracene. A perylene dye may also be incorporated.

  本发明公开了可与过氧化氢反应产生化学发光的组合物，其中组合物含有草酸盐和由 9,10-双（4-甲氧基苯基）-2-氯蒽组成的荧光剂。此外，还可加入一种过烯染料。

表征谱图