9,10-环氧十八烷酰胺 | 15498-10-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 9,10-环氧十八烷酰胺
• 英文名称: 9,10-Epoxyoctadecanamide
• 英文别名: 8-(3-octyloxiran-2-yl)octanamide
• CAS: 15498-10-9
• 化学式: C₁₈H₃₅NO₂
• 分子量: 297.481
• InChiKey: PIBPDMARGRAGIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  21
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  55.6
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2924299090

反应信息

• 作为反应物：
  描述：

  2,2,2-三氟乙醇 、 9,10-环氧十八烷酰胺 在 四乙基溴化铵 作用下， 以 乙腈 为溶剂， 以50%的产率得到2,2,2-trifluoroethyl N-[7-(3-octyloxiran-2-yl)heptyl]carbamate
  参考文献：
  名称：

  电化学诱导的霍夫曼重排

  摘要：

  开发了在包含多种醇的新溶剂系统下电化学诱导的霍夫曼重排。由于反应在温和的条件下（中性）进行，因此通过该方法可以容易地制备具有各种烷氧基部分的各种氨基甲酸酯。在电解过程中，酰胺和醇部分中的环氧官能团保持完整。

  DOI：

  10.1016/s0040-4039(97)10324-0

文献信息

• THE HOFMANN REARRANGEMENT INDUCED BY ELECTROORGANIC METHOD
  作者：Tatsuya Shono、Yoshihiro Matsumura、Shin-ichiro Yamane、Shigenori Kashimura

  DOI：10.1246/cl.1982.565

  日期：1982.4.5

  The Hofmann rearrangement has been induced by the electroorganic method using potassium bromide as a mediator, of which role in the reaction is really catalytic.

  霍夫曼重排是通过使用溴化钾作为介体的有机电法诱导的，其在反应中的作用确实是催化作用。
• Connexin 26 inhibitor and cancer metastasis inhibitors
  申请人：Kita Yasuyuki

  公开号：US20060058379A1

  公开（公告）日：2006-03-16

  A connexin 26 inhibitor and a cancer metastasis inhibitor have a cis-oxirane structure and a terminal amide structure as represented by the following general formula (1): where R is a hydrogen atom or a hydrocarbon group, X is one of a hydrogen atom, a methansulfonyl group, an ethansulfonyl group, an acetyl group, a trifluoroacetyl group, a hydroxyl group, an alkoxy group and an amino group; m is an integer of from 4 to 10; and n is an integer of from 4 to 7. This compound is a novel cancer metastasis inhibitor which specifically inhibits the function of connexin 26.

  一种connexin 26抑制剂和癌症转移抑制剂具有cis-oxirane结构和末端酰胺结构，如下所示的通式（1）：其中R是氢原子或羟基烃基团，X是氢原子、甲磺酰基、乙磺酰基、乙酰基、三氟乙酰基、羟基、烷氧基和氨基中的一种；m是4到10的整数；n是4到7的整数。该化合物是一种新型癌症转移抑制剂，可以特异性地抑制connexin 26的功能。
• EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0947562A1

  公开（公告）日：1999-10-06

  In order to realise the objectives stated above, the thermosetting resin composition for carbon fibre reinforced composite materials of the present invention chiefly comprises the following components. (A) Thermosetting resin (B) Compound containing one functional group which can react with thermosetting resin (A) or its curing agent, and a moiety selected from the following formulae (1) to (4) Furthermore, the present invention also relates to a prepreg formed by impregnating reinforcing fibre with the aforesaid resin composition and to carbon fibre reinforced composite materials comprising reinforcing fibre and a cured aforesaid thermosetting resin composition. In accordance with the present invention, there can be obtained a thermosetting resin composition where the adhesion to reinforcing fibre by the cured material and the elastic modulus of the cured material are excellent, and by using this resin composition there can be obtained carbon fibre reinforced composite materials which are excellent in their 0° compressive strength, 90° tensile strength and interlaminar shear strength, and which also have outstanding impact resistance.

  为了实现上述目标，本发明用于碳纤维增强复合材料的热固性树脂组合物主要包括以下成分。 (A) 热固性树脂 (B) 含有一个可与热固性树脂（A）或其固化剂发生反应的官能团和一个选自下式 （1）至（4）的分子的化合物 此外，本发明还涉及用上述树脂组合物浸渍增强纤维而形成的预浸料，以及由增强纤维和固化的上述热固性树脂组合物组成的碳纤维增强复合材料。 根据本发明，可以获得一种热固性树脂组合物，在这种组合物中，固化材料与增强纤维的粘附性和固化材料的弹性模量都非常好，使用这种树脂组合物可以获得 0°抗压强度、90°抗拉强度和层间剪切强度都非常好的碳纤维增强复合材料，这种材料还具有出色的抗冲击性。
• EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：——

  公开号：US20020007022A1

  公开（公告）日：2002-01-17

  In order to realize the objectives stated above, the thermosetting resin composition for carbon fiber reinforced composite materials of the present invention chiefly comprises the following components. (A) Thermosetting resin (B) Compound containing one functional group which can react with thermosetting resin (A) or its curing agent, and a moiety selected from the following formulae (1) to (4) 1 Furthermore, the present invention also relates to a prepreg formed by impregnating reinforcing fiber with the aforesaid resin composition and to carbon fiber reinforced composite materials comprising reinforcing fiber and a cured aforesaid thermosetting resin composition. In accordance with the present invention, there can be obtained a thermosetting resin composition where the adhesion to reinforcing fiber by the cured material and the elastic modulus of the cured material are excellent, and by using this resin composition there can be obtained carbon fiber reinforced composite materials which are excellent in their 0° compressive strength, 90° tensile strength and interlaminar shear strength, and which also have outstanding impact resistance.

  为了实现上述目标，本发明用于碳纤维增强复合材料的热固性树脂组合物主要包括以下组分。 (A) 热固性树脂 (B) 含有一个可与热固性树脂（A）或其固化剂反应的官能团的化合物，以及一个选 自下式（1）至（4）的分子 1 此外，本发明还涉及用上述树脂组合物浸渍增强纤维而形成的预浸料，以及由增强纤维和固化的上述热固性树脂组合物组成的碳纤维增强复合材料。 根据本发明，可以获得一种热固性树脂组合物，在这种组合物中，固化材料与增强纤维的粘附性和固化材料的弹性模量都很好，使用这种树脂组合物可以获得 0°抗压强度、90°抗拉强度和层间剪切强度都很好的碳纤维增强复合材料，这种复合材料还具有出色的抗冲击性。
• US5788753A
  申请人：——

  公开号：US5788753A

  公开（公告）日：1998-08-04

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