2-Tridecylimidazol | 56750-10-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-Tridecylimidazol
• 英文别名: 2-tridecyl-1H-imidazole；2-Tridecyl-1H-imidazol；2-Tridecylimidazole；2-tridecyl-1H-imidazole
• CAS: 56750-10-8
• 化学式: C₁₆H₃₀N₂
• 分子量: 250.428
• InChiKey: VCWPWZZLRFHCLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  28.7
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-(2-氨基乙基)肉豆蔻酰胺 在 镍 作用下， 生成 2-Tridecylimidazol
  参考文献：
  名称：

  取代的咪唑和2-咪唑啉。

  摘要：

  DOI：

  10.1021/jo01168a015

文献信息

• [EN] HETEREOCYCLIC AGENT AS CATALYTIC STABILIZING AGENT IN A HYDROFORMYLATION PROCESS<br/>[FR] AGENT HÉTÉROCYCLIQUE COMME AGENT DE STABILISATION CATALYTIQUE DANS UN PROCÉDÉ D'HYDROFORMYLATION
  申请人：DOW TECHNOLOGY INVESTMENTS LLC

  公开号：WO2014149915A1

  公开（公告）日：2014-09-25

  A heterocyclic nitrogen stabilizing agent is employed to reduce the rate of catalyst deactivation in a hydroformylation process.

  在氢甲酰化过程中，使用杂环氮稳定剂来降低催化剂失活的速率。
• Catalyst activators comprising expanded anions
  申请人：——

  公开号：US20010027161A1

  公开（公告）日：2001-10-04

  A compound useful as a catalyst activator corresponding to the formula: (A* +a ) b (Z*J* j ) −c d , wherein: A* is a cation of charge +a, Z* is an anion group of from 1 to 50 atoms not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.

  一种有用的催化剂活化剂化合物，其化学式为：(A*+a)b(Z*J*j)−cd，其中：A*是带有+a电荷的阳离子，Z*是一个含有1至50个原子（不包括氢原子）的阴离子基团，进一步包含两个或更多的Lewis碱基位点；J*是独立的，每次出现时都是与Z*的至少一个Lewis碱基位点配位的Lewis酸，而且可选地，两个或更多这样的J*基团可以连接在一起，形成具有多个Lewis酸性功能的基团，j是从2到12的数字，a、b、c和d是从1到3的整数，但是a×b等于c×d。
• COLORED METALLIC PIGMENT, PROCESS FOR PRODUCING THE SAME, AND COATING COMPOSITION AND COSMETIC PREPARATION COMPRISING SAID COLORED METALLIC PIGMENT
  申请人：TOYO ALUMINIUM KABUSHIKI KAISHA

  公开号：EP1990377A1

  公开（公告）日：2008-11-12

  This invention provides a colored metallic pigment, which can develop a variety of colors and varied interference colors while maintaining good lightfastness, weatherfastness and hiding power, a process for producing the same, a coating composition containing the colored metallic pigment and capable of providing a coating film having excellent finished appearance, and a cosmetic preparation containing the colored metallic pigment, having excellent hiding power, and capable of providing sharp hue. The colored metallic pigment comprises at least a metallic pigment, an amorphous silicon oxide film layer provided on the surface of the metallic pigment, a metal layer provided on the surface of the amorphous silicon oxide film layer, and metallic particles provided on the surface of the metal layer. The metallic particles are provided so as to directly cover a part of the surface of the metal layer. In the colored metallic pigment, the metal layer preferably comprises at least one metal selected from Sn, Pd, Pt and Au. The metallic particle preferably comprises at least one metal selected from Cu, Ni and Ag.

  本发明提供了一种彩色金属颜料，它能在保持良好的耐光性、耐候性和遮盖力的同时，显现出多种颜色和各种干扰色；还提供了一种生产彩色金属颜料的工艺；一种含有该彩色金属颜料并能提供具有良好成品外观的涂膜的涂料组合物；以及一种含有该彩色金属颜料、具有良好遮盖力并能提供鲜明色调的化妆品制剂。彩色金属颜料至少包括金属颜料、设置在金属颜料表面的非晶氧化硅薄膜层、设置在非晶氧化硅薄膜层表面的金属层以及设置在金属层表面的金属颗粒。金属颗粒的设置是为了直接覆盖金属层的部分表面。在有色金属颜料中，金属层最好包括至少一种选自 Sn、Pd、Pt 和 Au 的金属。金属颗粒最好包括至少一种选自铜、镍和银的金属。
• Surface treatment liquid, surface treatment method, and method for suppressing pattern collapse
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US10961422B2

  公开（公告）日：2021-03-30

  A surface treatment liquid capable of hydrophobizing a surface of a treatment target without including a silylation agent, a surface treatment method using the liquid, and a method for suppressing pattern collapse, including surface treatment by the surface treatment method. The liquid contains a nitrogen-containing heterocyclic compound as a water-repelling agent. A compound including one or more hydrocarbon groups which may be substituted with a halogen atom in which a total number of carbon atoms of the one or more hydrocarbon group is three or more, is used as the nitrogen-containing heterocyclic compound. The liquid may include only a nitrogen-containing heterocyclic compound having the above-described predetermined structure, as a water-repelling agent.

  一种无需硅烷化剂即可使处理对象表面疏水的表面处理液、一种使用该液体的表面处理方法，以及一种抑制图案塌陷的方法，包括通过该表面处理方法进行的表面处理。该液体含有作为憎水剂的含氮杂环化合物。含氮杂环化合物包括一个或多个可被卤素原子取代的烃基，其中一个或多个烃基的碳原子总数为三个或更多。作为憎水剂，液体中可以只包含具有上述预定结构的含氮杂环化合物。
• Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
  申请人：——

  公开号：US20020032120A1

  公开（公告）日：2002-03-14

  A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A* +a ) b (Z*J* j ) −c d , wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.

  一种可用作助催化剂或助催化剂组分的化合物，特别是可用作加成聚合催化剂的化合物，其结构式为 (A* +a ) b (Z*J* j ) -c d , 其中 A* 是含有 1 至 80 个原子，最好是 1 至 60 个原子（不包括氢原子）的阳离子，所述 A* 带有电荷+a、 Z* 是 1 至 50 个原子，最好是 1 至 30 个原子（不包括氢原子）的阴离子基团，进一步含有两个或更多的路易斯碱位点； 每个独立出现的 J* 是 1 至 80 个原子（最好是 1 至 60 个原子）（不计氢原子）的路易斯酸，与 Z* 的至少一个路易斯碱位点配位，可选择将两个或多个这样的 J* 基团连接在一起，形成具有多个路易斯酸官能团的分子、 j 是 2 到 12 之间的数字，且 a、b、c 和 d 是 1 至 3 的整数，但 a×b 等于 c×d，而且 A*、Z* 或 J* 中的一个或多个包含羟基或含有静止反应官能团的极性基团。