2-(4'-t-butylphenyl)-5-(2",5"-dimethylphenyl)-1,3,4-oxadiazole | 432551-49-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4'-t-butylphenyl)-5-(2",5"-dimethylphenyl)-1,3,4-oxadiazole
• 英文别名: 2-(4-Tert-butyl-phenyl)-5-(-2,5-dimethyl-phenyl)-[1,3,4]oxadiazole；2-(4-tert-butylphenyl)-5-(2,5-dimethylphenyl)-1,3,4-oxadiazole
• CAS: 432551-49-0
• 化学式: C₂₀H₂₂N₂O
• 分子量: 306.407
• InChiKey: YAKIGZXXUXXESN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(4'-t-butylphenyl)-5-(2",5"-dimethylphenyl)-1,3,4-oxadiazole 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 生成 2-(4'-t-butylphenyl)-5-(2'',5''-dibromomethylphenyl)-1,3,4-oxadiazole
  参考文献：
  名称：

  SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE

  摘要：

  Poly[2-{5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.

  DOI：

  10.1080/15421400390263884
• 作为产物：
  描述：

  对叔丁基苯甲酸甲酯 在 吡啶 、 氯化亚砜 、 一水合肼 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 36.0h， 生成 2-(4'-t-butylphenyl)-5-(2",5"-dimethylphenyl)-1,3,4-oxadiazole
  参考文献：
  名称：

  SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE

  摘要：

  Poly[2-{5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.

  DOI：

  10.1080/15421400390263884

文献信息

• Conjugated polymers with tunable charge injection ability
  申请人：Canon Kabushiki Kaisha

  公开号：US06399224B1

  公开（公告）日：2002-06-04

  Conjugated polymers and copolymers with strong luminescent properties and balanced charge transporting/injection properties are disclosed. Methods of manufacturing such polymers and copolymers and optoelectronic devices fabricated with such polymers and copolymers are disclosed. A conjugated luminescent polymer with tunable charge transport is prepared according to the following polymerization reaction: mM1+nM2→(M1)m(M2)n wherein M1 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-withdrawing character and M2 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-donating character, wherein m and n are stoichiometric quantities of the monomers M1 and M2, respectively, wherein m and n are varied to tune the charge transport property of the conjugated luminescent polymer. The monomers may include aryl, substituted aryl, and/or multiple carbon double bonds so that when polymerized, the resulting polymer has a conjugated backbone. Additional monomer reactants (M3, M4, M5, etc.) can be used in the polymerization reaction. The stoichiometric monomer amounts are varied to tune the charge transport or other electronic properties of the resulting conjugated luminescent polymer.

  本文披露了具有强发光特性和平衡的电荷传输/注入特性的共轭聚合物和共聚物。本文还披露了制造这些聚合物和共聚物以及使用这些聚合物和共聚物制造的光电器件的方法。根据以下聚合反应制备了一种具有可调节电荷传输的共轭发光聚合物：mM1+nM2→(M1)m(M2)n，其中M1是至少具有两个反应性官能团和至少一个具有电子吸引性的化学键结合电荷传输色团的单体，M2是至少具有两个反应性官能团和至少一个具有电子给体性的化学键结合电荷传输色团的单体，其中m和n分别是单体M1和M2的化学计量量，m和n变化以调节共轭发光聚合物的电荷传输性质。单体可以包括芳基，取代芳基和/或多个碳双键，以便在聚合时形成具有共轭骨架的聚合物。聚合反应中可以使用其他单体反应物（M3、M4、M5等）。化学计量单体量的变化可以调节所得共轭发光聚合物的电荷传输或其他电子特性。
• US6399224B1
  申请人：——

  公开号：US6399224B1

  公开（公告）日：2002-06-04
• US7442760B2
  申请人：——

  公开号：US7442760B2

  公开（公告）日：2008-10-28
• SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE
  作者：Yun-Hi Kim、Dong-Cheol Shin、Sung-Ouk Jung、Soon-Ki Kwon、Do-Hoon Hwang

  DOI：10.1080/15421400390263884

  日期：2003.1

  Poly[2-5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.