3-Methyl-hexen-2-carbonsaeure, Z | 54068-86-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-Methyl-hexen-2-carbonsaeure, Z
• 英文别名: (Z)-3-methyl-hex-2-enoic acid；3-Methyl-2Z-hexenoic acid；(Z)-3-methylhex-2-enoic acid
• CAS: 54068-86-9
• 化学式: C₇H₁₂O₂
• 分子量: 128.171
• InChiKey: NTWSIWWJPQHFTO-WAYWQWQTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Methyl-hexen-2-carbonsaeure, Z 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 (Z)-3-methylhex-2-en-1-ol
  参考文献：
  名称：

  Organocuivreux乙烯基：III。碳酸化：制备立体酸α-乙烯酯等得来

  摘要：

  通过碳化将乙烯基铜化合物立体定向地和几乎定量地转化为相应的β，β-二取代的α-乙烯酸。讨论了溶剂和配体在此插入过程中的影响。各种官能团衍生自这些酸。

  DOI：

  10.1016/s0022-328x(00)81328-5
• 作为产物：
  描述：

  二氧化碳 、 在 亚磷酸三乙酯 作用下， 以 六甲基磷酰三胺 为溶剂， 生成 3-Methyl-hexen-2-carbonsaeure, Z
  参考文献：
  名称：

  Organocuivreux乙烯基：III。碳酸化：制备立体酸α-乙烯酯等得来

  摘要：

  通过碳化将乙烯基铜化合物立体定向地和几乎定量地转化为相应的β，β-二取代的α-乙烯酸。讨论了溶剂和配体在此插入过程中的影响。各种官能团衍生自这些酸。

  DOI：

  10.1016/s0022-328x(00)81328-5

文献信息

• SUBSTITUTED CYANO CYCLOALKYL PENTA-2,4-DIENES, CYANO CYCLOALKYL PENT-2-EN-4-YNES, CYANO HETEROCYCLYL PENTA-2,4-DIENES AND CYANO HETEROCYCLYL PENT-2-EN-4-YNES AS ACTIVE SUBSTANCES
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US20170210701A1

  公开（公告）日：2017-07-27

  The invention relates to cyano cycloalkyl penta-2,4-dienes, cyano cycloalkyl pent-2-en-4-ynes, cyano heterocyclyl penta-2,4-dienes and cyano heterocyclyl pent-2-en-4-ynes of general formula (I), or the salts thereof, where [X-Y], Q, R 1 , R 2 , A 1 , A 2 , V, W, m and n have the definitions specified in the description. The invention also relates to a production method for same and to the use of same for increasing stress tolerance in plants against abiotic stress, and/or for increasing the plant yield.

  该发明涉及一般式(I)的氰基环烷基戊二烯、氰基环烷基戊-2-炔、氰基杂环烷基戊二烯和氰基杂环烷基戊-2-炔，或其盐，其中[X-Y]、Q、R1、R2、A1、A2、V、W、m和n的定义如描述中所指定。该发明还涉及同类物质的生产方法以及将其用于增加植物对非生物胁迫的抗逆性和/或增加植物产量。
• SUBSTITUTED 5-(BICYCLO[4.1.0]HEPT-3-EN-2-YL)PENTA-2,4-DIENES AND 5-(BICYCLO[4.1.0]HEPT-3-EN-2-YL)PENT-2-ENE-4-INES AS ACTIVE AGENTS AGAINST ABIOTIC STRESSES IN PLANTS
  申请人：Frackenpohl Jens

  公开号：US20140051577A1

  公开（公告）日：2014-02-20

  The invention relates to substituted 5-(bicyclo[4.1.0]hept-3-en-2-yl)penta-2,4-dienes and 5-(bicyclo[4.1.0]hept-3-en-2-yl)pent-2-ene-4-ines of the formula (I) and salts thereof, where the radicals R1, R2, R3, R4, R5, [X—Y] and Q are each as defined in the description, to processes for preparation thereof and to the use thereof for enhancing stress tolerance in plants with respect to abiotic stress, and/or for increasing plant yield.

  该发明涉及代换的5-(bicyclo[4.1.0]庚-3-烯-2-基)戊-2,4-二烯和5-(bicyclo[4.1.0]庚-3-烯-2-基)戊-2-烯-4-炔的化合物及其盐，其中基团R1、R2、R3、R4、R5、[X—Y]和Q的定义如描述中所示，以及其制备方法和用途，用于增强植物对非生物胁迫的抗压能力，和/或增加植物产量。
• SUBSTITUTED 5-(CYCLOHEX-2-EN-1-YL)-PENTA-2,4-DIENES AND 5-(CYCLOHEX-2-EN-1-YL)-PENT-2-EN-4-INES AS ACTIVE AGENTS AGAINST ABIOTIC STRESS IN PLANTS
  申请人：Frackenpohl Jens

  公开号：US20140087949A1

  公开（公告）日：2014-03-27

  The invention relates to substituted 5-(cyclohex-2-en-1-yl)penta-2,4-dienes and 5-(cyclohex-2-en-1-yl)pent-2-en-4-ines of the formula (I) and their salts where the radicals R 1 , R 2 , R 3 , R 4 , [X—Y] and Q are each as defined in the description, to processes for preparation thereof and to the use thereof for enhancing stress tolerance in plants with respect to abiotic stress, and/or for increasing plant yield.

  该发明涉及代换的5-(环己-2-烯-1-基)戊-2,4-二烯和5-(环己-2-烯-1-基)戊-2-烯-4-炔的化合物(I)及其盐，其中基团R1、R2、R3、R4、[X—Y]和Q如描述中所定义，以及其制备方法和用途，用于增强植物对非生物胁迫的抗逆性，并/或增加植物产量。
• Solvent based coating composition
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0413352A2

  公开（公告）日：1991-02-20

  Disclosed is a solvent based coating composition comprising at least one kind of vinyl polymer and an organic solvent, wherein any one of said vinyl polymer has at least one kind selected from the group consisting of an active hydrogen-containing group and a substituted acylamide group, and said vinyl polymer contains the above described two kinds of group as a whole.

  本发明公开了一种溶剂型涂料组合物，该组合物包含至少一种乙烯基聚合物和一种有机溶剂，其中任一种所述乙烯基聚合物具有至少一种从活性含氢基团和取代的酰酰胺基团组成的组中选出的基团，且所述乙烯基聚合物整体包含上述两种基团。
• Aqueous dispersion coating composition
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0413351A2

  公开（公告）日：1991-02-20

  Disclosed is an aqueous dispersion coating composition comprising at least one kind of resins, wherein any one of said resins has at least one kind selected from the group consisting of an active hydrogen-containing group, a substituted acylamide group and a water dispersible or water-soluble group, and said resin composition contains the above described kinds of group as a whole.

  本发明公开了一种水性分散涂料组合物，该组合物包含至少一种树脂，其中任一种树脂具有至少一种选自活性含氢基团、取代的酰酰胺基团和水分散或水溶性基团组成的组的基团，且所述树脂组合物整体包含上述基团。