苯基铵氧卑膦酸 | 28052-93-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 苯基铵氧卑膦酸
• 英文名称: 3,3'-bis(2-aminopropansaeure)
• 英文别名: S,S'-methylenebis(cysteine)；djenkolic acid；Djenkolinsaeure；Djenkolsaeure；([(2-Amino-2-carboxyethyl)sulfanyl]methyl)cysteine；2-azaniumyl-3-[(2-azaniumyl-2-carboxylatoethyl)sulfanylmethylsulfanyl]propanoate
• CAS: 28052-93-9
• 化学式: C₇H₁₄N₂O₄S₂
• mdl: MFCD00287287
• 分子量: 254.331
• InChiKey: JMQMNWIBUCGUDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -5.6
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.714
• 拓扑面积：
  177
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  ferrous(II) sulfate heptahydrate 、 苯基铵氧卑膦酸 在 KOH 作用下， 以 水 为溶剂， 生成 iron(II) djenkolate monohydrate
  参考文献：
  名称：

  Iron(II) djenkolate: synthesis and properties

  摘要：

  Djenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction of potassium djenkolate with Fe(SO(4)). 7H(2)O under nitrogen atmosphere. X-Ray diffraction pattern has been indexed in orthorhombic system with lattice parameters: a=11.24 Angstrom, b=7.50 Angstrom and c=6.96 Angstrom. According to IR spectroscopy, coordination is performed through COO(-) and NH(2) groups. An octahedral geometry for Fe ion is suggested by UV-Vis and Mossbauer spectroscopies. Thermal decomposition leads to the formation of Fe(2)O(3) (hematite). The compound shows poor solubility in water and in common organic solvents. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)00884-7
• 作为产物：
  描述：

  3,3'-bis(2-chlorpropansaeure-methylester) 在 rhenium heptasulfide 盐酸 、 sodium hydroxide 、 sodium azide 、 氢气 、 sodium acetate 、 甲基三辛基氯化铵 作用下， 以 水 为溶剂， 反应 15.0h， 生成 苯基铵氧卑膦酸
  参考文献：
  名称：

  Effenberger, Franz; Beisswenger, Thomas; Dannenhauer, Fritz, Chemische Berichte, 1988, vol. 121, p. 2209 - 2224

  摘要：

  DOI：

文献信息

• MACKENZIE S. L., J. ASSOC. OFFIC. ANAL. CHEM., 70,(1987) N 1, 151-160
  作者：MACKENZIE S. L.

  DOI：——

  日期：——
• EFFENBERGER, FRANZ;BEISSWENGER, THOMAS;DANNENHAUER, FRITZ, CHEM. BER., 121,(1988) N 12, C. 2209-2223
  作者：EFFENBERGER, FRANZ、BEISSWENGER, THOMAS、DANNENHAUER, FRITZ

  DOI：——

  日期：——
• Effenberger, Franz; Beisswenger, Thomas; Dannenhauer, Fritz, Chemische Berichte, 1988, vol. 121, p. 2209 - 2224
  作者：Effenberger, Franz、Beisswenger, Thomas、Dannenhauer, Fritz

  DOI：——

  日期：——
• Iron(II) djenkolate: synthesis and properties
  作者：Petr Melnikov、Pedro P Corbi、Carlos Diaz Aguila、Marisa A Zacharias、Maurı́cio Cavicchioli、Antonio C Massabni

  DOI：10.1016/s0925-8388(00)00884-7

  日期：2000.7

  Djenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction of potassium djenkolate with Fe(SO(4)). 7H(2)O under nitrogen atmosphere. X-Ray diffraction pattern has been indexed in orthorhombic system with lattice parameters: a=11.24 Angstrom, b=7.50 Angstrom and c=6.96 Angstrom. According to IR spectroscopy, coordination is performed through COO(-) and NH(2) groups. An octahedral geometry for Fe ion is suggested by UV-Vis and Mossbauer spectroscopies. Thermal decomposition leads to the formation of Fe(2)O(3) (hematite). The compound shows poor solubility in water and in common organic solvents. (C) 2000 Elsevier Science S.A. All rights reserved.