8-[3-(4,8,12-Triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-yl)phenyl]-4,8,12-triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene | 1133248-96-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 8-[3-(4,8,12-Triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-yl)phenyl]-4,8,12-triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
• CAS: 1133248-96-0
• 化学式: C₂₆H₁₆N₆
• 分子量: 412.453
• InChiKey: NTJCVHZROCKLEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,3-二溴苯 、 5H-吡咯并[3,2-c:4,5-c]二吡啶 在 copper(I) oxide 、 2-吡啶甲酸 potassium phosphate 作用下， 以 二甲基亚砜 为溶剂， 反应 8.0h， 以65%的产率得到8-[3-(4,8,12-Triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaen-8-yl)phenyl]-4,8,12-triazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
  参考文献：
  名称：

  PRODUCING METHOD OF NITROGEN CONTAINING CONDENSED HETEROCYCLIC COMPOUND

  摘要：

  提供一种制备含氮紧缩杂环化合物的方法，其中包括以下步骤：在铜或铜离子和配体的存在下，将公式（1a）或公式（1b）所代表的化合物与公式（2）所代表的化合物反应，以制得公式（3a）或公式（3b）所代表的含氮紧缩杂环化合物。

  公开号：

  US20110184176A1

文献信息

• IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE AND DISPLAY DEVICE
  申请人：Konica Minolta Advanced Layers, Inc.

  公开号：US20130200340A1

  公开（公告）日：2013-08-08

  An organic electroluminescent element in which at least one organic layer including a light emitting layer is sandwiched between an anode and a cathode, wherein the at least one organic layer includes an iridium complex compound represented by a following general formula (1).

  一种有机电致发光元件，其中至少包括一个有机层，包括一个发光层，夹在阳极和阴极之间，其中至少一个有机层包括以下一般式（1）所代表的铱配合物化合物。
• ORGANIC ELECTROLUMINESCENT DEVICE, DISPLAY AND ILLUMINATING DEVICE
  申请人：KONICA MINOLTA HOLDINGS, INC.

  公开号：EP1998387A1

  公开（公告）日：2008-12-03

  The first object of the present invention is to provide a blue phosphorescent light-emitting organic electroluminescent (EL) device driven at low voltage, and a display and illuminating device each using such an organic EL device. The second object of the present invention is to provide an organic EL device having long life, and an illuminating device and display each using such an organic EL device. Each organic EL device comprises an electrode and at least one organic layer on a substrate, and at least one of the organic layers is a light-emitting layer containing a host compound and a phosphorescent compound. In order to accomplish the first object, the host compound has an HOMO of from -7.20 to -5.42 eV and an LUMO of from -2.30 to -0.50 eV, and the phosphorescent compound is represented by the general formula (1). In order to accomplish the second object, the host compound is an electron-transporting host compound having an excited triplet energy T1 of not less than 2.7 eV, and the phosphorescent compound has an HOMO of from -5.15 to -3.50 eV and an LUMO of from -1.25 to +1.00 eV.

  本发明的第一个目的是提供一种在低电压下驱动的蓝色磷光发光有机电致发光（EL）器件，以及使用这种有机EL器件的显示器和照明设备。本发明的第二个目的是提供一种具有长寿命的有机电致发光器件，以及使用这种有机电致发光器件的照明装置和显示器。每个有机电致发光器件包括一个电极和基板上的至少一个有机层，其中至少一个有机层是包含主化合物和磷光化合物的发光层。为了实现第一个目标，主化合物的 HOMO 为 -7.20 至 -5.42 eV，LUMO 为 -2.30 至 -0.50 eV，磷光化合物由通式（1）表示。为了实现第二个目标，宿主化合物是一种电子传递宿主化合物，其激发三重态能量T1不小于2.7eV，磷光化合物的HOMO为-5.15至-3.50eV，LUMO为-1.25至+1.00eV。
• ORGANIC ELECTROLUMINESCENT ELEMENT, NOVEL COMPOUND, LIGHTING DEVICE AND DISPLAY DEVICE
  申请人：Konica Minolta Holdings, Inc.

  公开号：EP2453496A1

  公开（公告）日：2012-05-16

  Provided are an organic electroluminescent element having high luminous efficiency, low driving voltage, and long life; novel compound; lighting device; and display device.

  本文提供了一种具有高发光效率、低驱动电压和长寿命的有机电致发光元件、新型化合物、照明设备和显示设备。
• ORGANIC ELECTROLUMINESCENT MATERIAL, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE AND LIGHTING DEVICE
  申请人：Konica Minolta Holdings, Inc.

  公开号：EP2584019A1

  公开（公告）日：2013-04-24

  Disclosed are: an organic EL material which emits light having a short wavelength and has high luminous efficiency and long light emission life; an organic EL element which contains the organic EL material; and a lighting device and a display device, each of which comprises the organic EL element.

  公开了：一种有机 EL 材料，它能发出波长短、发光效率高、发光寿命长的光；一种有机 EL 元件，它包含该有机 EL 材料；以及一种照明设备和一种显示设备，它们都包含该有机 EL 元件。
• ISOMER-MIXTURE METAL COMPLEX COMPOSITION, ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATOR, AND DISPLAY DEVICE
  申请人：Konica Minolta, Inc.

  公开号：EP2980094A1

  公开（公告）日：2016-02-03

  The present invention addresses the problem of providing an isomer-mixture metal complex composition that includes a plurality of atropisomers which are closely akin to each other in physical property and energy level and of providing an organic EL element using the isomer-mixture metal complex composition as a material for the organic EL element, the EL element having improved stability over time of the organometallic complex film, including a luminescent layer reduced in resistivity change, and giving a luminescent spectrum reduced in change in half-value width. Also provided are an illuminator and a display device which are obtained using the organic EL element. This isomer-mixture metal complex composition is a metal complex composition which is a mixture of isomers each comprising a metal atom and a plurality of ligands, and is characterized by containing a plurality of atropisomers because at least one of the ligands has an aromatic ring as a substituent and the free rotation of the axis of the bonding between the aromatic ring and the ligand is inhibited by the formation of a complex of the metal atom with other ligand(s).

  本发明要解决的问题是提供一种异构体混合物金属络合物组合物，该组合物包括多种在物理性质和能级上彼此非常接近的异构体，并提供一种使用该异构体混合物金属络合物组合物作为有机EL元件材料的有机EL元件，该EL元件在有机金属络合物薄膜的长期稳定性方面有所改善，包括电阻率变化减小的发光层，以及半值宽度变化减小的发光光谱。此外，还提供了使用该有机 EL 元件获得的照明器和显示装置。这种异构体混合物金属络合物组合物是一种金属络合物组合物，它是一种异构体的混合物，每个异构体包括一个金属原子和多个配体，其特征是含有多个异构体，因为配体中至少有一个具有芳香环作为取代基，并且芳香环和配体之间键合轴的自由旋转受到金属原子与其他配体形成的络合物的抑制。