3,5-dimethoxy-4'-methyl-3''-hydroxymethyltriphenylamine | 351340-89-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,5-dimethoxy-4'-methyl-3''-hydroxymethyltriphenylamine
• 英文别名: [3-(N-(3,5-dimethoxyphenyl)-4-methylanilino)phenyl]methanol
• CAS: 351340-89-1
• 化学式: C₂₂H₂₃NO₃
• 分子量: 349.43
• InChiKey: YFFUATQXADSMLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  41.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,5-dimethoxy-4'-methyl-3''-hydroxymethyltriphenylamine 在 18-冠醚-6 、 四溴化碳 、 potassium carbonate 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 生成 {3-[(3,5-Bis-{3-[(3,5-dimethoxy-phenyl)-p-tolyl-amino]-benzyloxy}-phenyl)-p-tolyl-amino]-phenyl}-methanol
  参考文献：
  名称：

  Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units

  摘要：

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.

  DOI：

  10.1021/ol0160203
• 作为产物：
  描述：

  3,5-二甲氧基苯胺 在 1,1'-bis(diphenylphosphino)ferrocene 、 tris(dibenzylideneacetone)palladium sodium tetrahydroborate 、 叔丁基锂 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 81.25h， 生成 3,5-dimethoxy-4'-methyl-3''-hydroxymethyltriphenylamine
  参考文献：
  名称：

  Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units

  摘要：

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.

  DOI：

  10.1021/ol0160203

文献信息

• Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units
  作者：Krys Bronk、S. Thayumanavan

  DOI：10.1021/ol0160203

  日期：2001.6.1

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.