3,5-dimethoxy-4'-methyl-3''-bromomethyltriphenylamine | 351340-90-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,5-dimethoxy-4'-methyl-3''-bromomethyltriphenylamine
• 英文别名: N-[3-(bromomethyl)phenyl]-3,5-dimethoxy-N-(4-methylphenyl)aniline
• CAS: 351340-90-4
• 化学式: C₂₂H₂₂BrNO₂
• 分子量: 412.326
• InChiKey: GCRRVUFBIWLWHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,5-dimethoxy-4'-methyl-3''-bromomethyltriphenylamine 在 18-冠醚-6 、 四溴化碳 、 potassium carbonate 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 生成 N,N'-((((5-((3-(bromomethyl)phenyl)(p-tolyl)amino)-1,3-phenylene)bis(oxy))bis(methylene))bis(3,1-phenylene))bis(3,5-dimethoxy-N-(p-tolyl)aniline)
  参考文献：
  名称：

  Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units

  摘要：

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.

  DOI：

  10.1021/ol0160203
• 作为产物：
  描述：

  3,5-二甲氧基苯胺 在 1,1'-bis(diphenylphosphino)ferrocene 、 tris(dibenzylideneacetone)palladium sodium tetrahydroborate 、 四溴化碳 、 叔丁基锂 、 三苯基膦 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 反应 81.25h， 生成 3,5-dimethoxy-4'-methyl-3''-bromomethyltriphenylamine
  参考文献：
  名称：

  Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units

  摘要：

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.

  DOI：

  10.1021/ol0160203

文献信息

• Design and Synthesis of Nonconjugated Monodendrons with Triarylamine Repeating Units
  作者：Krys Bronk、S. Thayumanavan

  DOI：10.1021/ol0160203

  日期：2001.6.1

  [GRAPHICS]Design and synthesis of new monodendrons with triarylamine repeating units, which are potentially useful in charge transport applications, are described. The triarylamines are connected through a nonconjugated linkage to facilitate independent electronic tuning of the monomer units.