tetracetone tetraperoxide | 74515-93-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: tetracetone tetraperoxide
• 英文别名: TrATrP；3,3,6,6,9,9,12,12-octamethyl-1,2,4,5,7,8,10,11-octaoxacyclododecane
• CAS: 74515-93-8
• 化学式: C₁₂H₂₄O₈
• 分子量: 296.318
• InChiKey: KTTZPKBRXFHBDC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  异丁烯 在 ozone-containing oxygen 作用下， 以 乙醚 为溶剂， 反应 1.0h， 生成 tetracetone tetraperoxide
  参考文献：
  名称：

  Odinokov, V. N.; Botsman, L. P.; Ishmuratov, G. Yu., Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, p. 453 - 463

  摘要：

  DOI：

文献信息

• Tin Chloride Catalysed Oxidation of Acetone with Hydrogen Peroxide to Tetrameric Acetone Peroxide
  作者：Heng Jiang、Gang Chu、Hong Gong、Qingdong Qiao

  DOI：10.1039/a809955c

  日期：——

  SnCl4·5H2O and SnCl2·2H2O are efficient catalysts for the oxidation of acetone with 30% hydrogen peroxide at room temperature and produce tetrameric acetone peroxide which is identified by molecular weight determination, elemental analysis, FTIR, NMR and MS.

  SnCl4·5H2O和SnCl2·2H2O是30%过氧化氢在室温下氧化丙酮的有效催化剂，生成四聚过氧化丙酮，通过分子量测定、元素分析、FTIR、NMR和MS鉴定。
• THERMOPLASTIC GRAFT COPOLYMER RESIN, METHOD FOR PREPARING SAME, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3290464A1

  公开（公告）日：2018-03-07

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93 % by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.

  本发明涉及一种热塑性接枝共聚物树脂、制备该树脂的方法以及包括该树脂的热塑性树脂组合物。更具体地说，本发明涉及一种热塑性接枝共聚物树脂，包括种子、包覆种子的丙烯酸烷基酯橡胶芯和包覆橡胶芯的外壳、制备方法和包括其在内的热塑性树脂组合物，其中热塑性接枝共聚物树脂的凝胶含量为 93 %（重量）或以上，溶胀指数为 6 至 14。 根据本公开，提供了一种具有优异耐化学性、耐热性和耐冲击性的热塑性接枝共聚物树脂、其制备方法以及包括其在内的热塑性树脂组合物。
• Thermoplastic graft copolymer resin, method of preparing the same, and thermoplastic resin composition including the same
  申请人：LG CHEM, LTD.

  公开号：US10450453B2

  公开（公告）日：2019-10-22

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93% by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.

  本发明涉及一种热塑性接枝共聚物树脂、制备该树脂的方法以及包括该树脂的热塑性树脂组合物。更具体地说，本发明涉及一种热塑性接枝共聚物树脂，包括种子、包覆种子的丙烯酸烷基酯橡胶芯和包覆橡胶芯的外壳、制备方法和包括其在内的热塑性树脂组合物，其中热塑性接枝共聚物树脂的凝胶含量为 93% （重量）或以上，溶胀指数为 6 至 14。根据本公开，提供了一种具有优异耐化学性、耐热性和耐冲击性的热塑性接枝共聚物树脂、其制备方法以及包括其在内的热塑性树脂组合物。
• ODINOKOV V. N.; BOTSMAN L. P.; ISHMURATOV G. YU.; TOLSTIKOV G. A., ZH. ORGAN. XIMII, 1980, 16, HO 3, 524-537
  作者：ODINOKOV V. N.、 BOTSMAN L. P.、 ISHMURATOV G. YU.、 TOLSTIKOV G. A.

  DOI：——

  日期：——
• THERMOPLASTIC GRAFT COPOLYMER RESIN, METHOD OF PREPARING THE SAME, AND THERMOPLASTIC RESIN COMPOSITION INCLUDING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20180142094A1

  公开（公告）日：2018-05-24

  The present disclosure relates to a thermoplastic graft copolymer resin, a method of preparing the same, and a thermoplastic resin composition including the same. More particularly, the present invention relates to a thermoplastic graft copolymer resin including a seed, an alkyl acrylate rubber core enclosing the seed, and a shell enclosing the rubber core, a method of preparing the same, and a thermoplastic resin composition including the same, wherein the thermoplastic graft copolymer resin has a gel content of 93% by weight or more and a swelling index of 6 to 14. In accordance with the present disclosure, a thermoplastic graft copolymer resin exhibiting excellent chemical resistance, heat resistance, and impact resistance, a method of preparing the same, and a thermoplastic resin composition including the same are provided.