N,N-二(2-羟基乙基)壬酰胺 | 3077-37-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: N,N-二(2-羟基乙基)壬酰胺
• 中文别名: N-(8-苯甲基-8-氮杂二环[3.2.1]辛-3-基)-2-乙基-4-甲氧基嘧啶-5-甲酰胺
• 英文名称: Diethanolpelargonsaeureamid
• 英文别名: N,N-bis-(2-hydroxy-ethyl)-nonanamide；Pelargonsaeure-[bis-(2-hydroxy-aethyl)-amid]；N,N-Bis-(2-hydroxy-aethyl)-nonanamid；N.N-Bis-(2-hydroxy-aethyl)-pelargonamid；N,N-bis(2-hydroxyethyl)nonan-1-amide；Nonanamide, N,N-bis(2-hydroxyethyl)-；N,N-bis(2-hydroxyethyl)nonanamide
• CAS: 3077-37-0
• 化学式: C₁₃H₂₇NO₃
• mdl: MFCD13293000
• 分子量: 245.362
• InChiKey: WODYOUWSWYOPBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.923
• 拓扑面积：
  60.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  壬酸乙酯 、 二乙醇胺 生成 N,N-二(2-羟基乙基)壬酰胺
  参考文献：
  名称：

  Three Series of N-Substituted Aliphatic Amides¹

  摘要：

  DOI：

  10.1021/ja01280a026

文献信息

• One‐Step Biocatalytic Synthesis of Sustainable Surfactants by Selective Amide Bond Formation**
  作者：Max Lubberink、William Finnigan、Christian Schnepel、Christopher R. Baldwin、Nicholas J. Turner、Sabine L. Flitsch

  DOI：10.1002/anie.202205054

  日期：2022.7.25

  route to commercially important surfactants is presented. A truncated construct of carboxylic acid reductase (CARmm-A) catalyzes amide bond formation between fatty acids and amino alcohols with no esterification observed. The wide substrate scope of the enzyme, co-factor recycling, reaction engineering and up-scaling show the feasibility of this method for synthesis.

  提出了一种获得商业上重要的表面活性剂的酶促途径。截短的羧酸还原酶构建体 (CAR mm -A) 催化脂肪酸和氨基醇之间形成酰胺键，未观察到酯化反应。该酶的广泛底物范围、辅因子回收、反应工程和放大显示了该合成方法的可行性。
• LUBRICATING OIL COMPOSITION, AND SLIDING MECHANISM USING LUBRICATING OIL COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2826844A1

  公开（公告）日：2015-01-21

  Disclosed is a lubricating oil composition for low-friction sliding materials, which is used in a sliding mechanism where a DLC film containing hydrogen in an amount of from 5 atom% to 50 atom% is formed on at least one sliding surface. The lubricating oil composition contains, in the lubricant base oil therein and based on the total amount of the composition, (A) an organic zinc dithiophosphate in an amount of from 0.005% by mass to 0.12% by mass in terms of the phosphorus concentration therein, (B) an amide-based friction-reducing agent in an amount of from 0.05% by mass to 5.0% by mass, and (C) an alkaline earth metal salicylate-based detergent and/or an alkaline earth metal sulfonate-based detergent in an amount of from 0.05% by mass to 0.5o by mass in terms of the alkaline earth metal concentration therein.

  本发明公开了一种用于低摩擦滑动材料的润滑油组合物，该组合物用于在至少一个滑动表面上形成含氢量为 5 原子％至 50 原子％的 DLC 膜的滑动机构中。 该润滑油组合物在其中的润滑油基础油中，根据组合物的总量，含有 (A) 有机二硫代磷酸锌，以其中的磷浓度计，含量为 0.005% （质量分数）至 0.12% （质量分数）；(B) 酰胺基减摩剂，含量为 0.05% (质量)至 5.0% (质量)，以及 (C) 碱土金属水杨酸酯类洗涤剂和/或碱土金属磺酸盐类洗涤剂，以其中碱土金属浓度计，用量为 0.05% (质量)至 0.5o (质量)。
• Three Series of N-Substituted Aliphatic Amides¹
  作者：G. F. D'Alelio、E. Emmet Reid

  DOI：10.1021/ja01280a026

  日期：1937.1
• POLYMERIZATION METHOD USING SURFACTANT-CONTAINING PARTICLE
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20140288251A1

  公开（公告）日：2014-09-25

  An object of the present invention is to provide a method which can simply suppress fouling in a reactor and, according to the present invention, there is provided a method of polymerizing addition polymerizable monomers using a catalyst formed by bringing (A) a transition metal compound represented by the following general formula [3] or μ-oxo type transition metal compound dimer thereof and (B) an activating agent into contact with one another, the method comprising polymerizing addition polymerizable monomers in a solvent to which a surfactant-containing particle obtained by mixing a particle composed of an inorganic compound or an organic polymer, and at least one surfactant selected from the group consisting of a compound represented by the following general formula [1] and a compound represented by general formula [2] has been added. R 1 —O—(—R 2 —O—) m -Q 1 [1] R 1′ C(═O)NR 5 2 [2] L 1 a M 2 X 1 b [3]
• US9200093B2
  申请人：——

  公开号：US9200093B2

  公开（公告）日：2015-12-01