N,N-dipentyldodecanamide | 574009-29-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N,N-dipentyldodecanamide
• CAS: 574009-29-3
• 化学式: C₂₂H₄₅NO
• 分子量: 339.605
• InChiKey: FUFMZDZCWYVTOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  月桂酰氯 、 二戊胺 在 吡啶 、 三乙胺 作用下， 以68%的产率得到N,N-dipentyldodecanamide
  参考文献：
  名称：

  在FAB质谱中将二价金属阳离子与酰胺基配位形成加成离子：Zn2 +在酰胺键的酶促水解中的意义。

  摘要：

  酰胺和金属离子之间的配合物的结构通过FAB质谱和碰撞诱导离解（CID）进行了检查。Zn2 +由N-十四烷基乙酰胺（1）的酰胺羰基氧原子配位。相反，酮和烯醇形式的Ca2 +和Mg2 +均由1的酰胺基团配位。Zn2 +在水解酶活性位点上的催化作用可能部分是由于Zn2 +对可裂解酰胺基的羰基氧原子的有效攻击所致。

  DOI：

  10.1248/cpb.56.672

文献信息

• AGROCHEMICAL COMPOSITION AND METHOD FOR PREPARING AND USING THE SAME
  申请人：Yin Amanda

  公开号：US20120071530A1

  公开（公告）日：2012-03-22

  An agrochemical composition comprises an azole active ingredient and an N,N-dialkyl long chain alkylamide. The N,N-dialkyl long chain alkylamide is present in sufficient amount to prevent or inhibit the crystallization of the azole derivative during the application of the composition to a locus. Preferred N,N-Dialkyl long chain alkylamide(s) comprised in the composition is/are selected from the group consisting of compounds of the formula (I): in which (a) R 1 and R 2 are independently normal alkyl radicals having 2 carbon atoms, and R represents an alkyl group having from 10 to 30 carbon atoms; or (b) R 1 and R 2 are independently normal alkyl radicals having 3 carbon atoms, and R represents an alkyl group having from 9 to 30 carbon atoms; or 20 (c) R 1 and R 2 are independently normal alkyl radicals having from 4 to 20 carbon atoms and R represents an alkyl group having from 6 to 30 carbon atoms. The composition is particularly advantageous when formulated with a fungicide, in particular one or more of tebuconazole, cyproconazole, difenoconazole, diniconazole, triticonazole, hexaconazole, triflumiazole, metconazole, tricylazole, flusilazole, flutriafol, and myclobutanil.
• US8653121B2
  申请人：——

  公开号：US8653121B2

  公开（公告）日：2014-02-18
• Coordination of Divalent Metal Cation to Amide Group to Form Adduct Ion in FAB Mass Spectrometry: Implication of Zn2+ in Enzymatic Hydrolysis of Amide Bond
  作者：Hisayoshi Kobayashi、Naoko Morisaki、Hiroyuki Miyachi、Yuichi Hashimoto

  DOI：10.1248/cpb.56.672

  日期：——

  The structures of complexes between amides and metal ions were examined by FAB mass spectrometry and collision-induced dissociation (CID). Zn2+ was coordinated by the amide carbonyl oxygen atom of N-tetradecylacetamide (1). In contrast, Ca2+ and Mg2+ were coordinated by the amide group of 1 in both the keto and enol forms. The catalytic role of Zn2+ at the active site of the hydrolases might partly

  酰胺和金属离子之间的配合物的结构通过FAB质谱和碰撞诱导离解（CID）进行了检查。Zn2 +由N-十四烷基乙酰胺（1）的酰胺羰基氧原子配位。相反，酮和烯醇形式的Ca2 +和Mg2 +均由1的酰胺基团配位。Zn2 +在水解酶活性位点上的催化作用可能部分是由于Zn2 +对可裂解酰胺基的羰基氧原子的有效攻击所致。