(4-tert-Butyl-phenyl)-{4-[(4-tert-butyl-phenyl)-hydroxy-methyl]-phenyl}-methanol | 98531-28-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-tert-Butyl-phenyl)-{4-[(4-tert-butyl-phenyl)-hydroxy-methyl]-phenyl}-methanol
• 英文别名: (4-Tert-butylphenyl)-[4-[(4-tert-butylphenyl)-hydroxymethyl]phenyl]methanol
• CAS: 98531-28-3
• 化学式: C₂₈H₃₄O₂
• 分子量: 402.577
• InChiKey: RVHOBBXFIMVLJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4-tert-Butyl-phenyl)-{4-[(4-tert-butyl-phenyl)-hydroxy-methyl]-phenyl}-methanol 在 manganese(IV) oxide 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 [4-(4-叔丁基苯甲酰基)苯基]-(4-叔丁基苯基)甲酮
  参考文献：
  名称：

  W(CO)6-Mediated desulfuroligomerization of bis-dithioacetals. New synthesis of substituted oligo(phenylene–vinylenes)

  摘要：

  Treatment of bisdithioacetals of 1,4-diaroylbenzenes (4) with W(CO)(6) in refluxing chlorobenzene afforded the corresponding substituted oligophenylenevinylenes (OPVs) (5). Average molecular weights determined by GPC indicate that OPVs 5 have 5-13 repetitive substituted phenylenevinylene units with narrow polydispersities. Emission in the blue-green to green region was observed for these OPVs depending on the nature of the substituent. The electron-donating alkoxy substituent shifted the emission to the longer wavelength whereas the electron-withdrawing trifluoromethyl group caused a blue shift in the fluorescence spectra. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00839-1
• 作为产物：
  描述：

  4-叔丁基苯基溴化镁 、 对苯二甲醛 以 四氢呋喃 、 乙醚 为溶剂， 反应 12.0h， 生成 (4-tert-Butyl-phenyl)-{4-[(4-tert-butyl-phenyl)-hydroxy-methyl]-phenyl}-methanol
  参考文献：
  名称：

  W(CO)6-Mediated desulfuroligomerization of bis-dithioacetals. New synthesis of substituted oligo(phenylene–vinylenes)

  摘要：

  Treatment of bisdithioacetals of 1,4-diaroylbenzenes (4) with W(CO)(6) in refluxing chlorobenzene afforded the corresponding substituted oligophenylenevinylenes (OPVs) (5). Average molecular weights determined by GPC indicate that OPVs 5 have 5-13 repetitive substituted phenylenevinylene units with narrow polydispersities. Emission in the blue-green to green region was observed for these OPVs depending on the nature of the substituent. The electron-donating alkoxy substituent shifted the emission to the longer wavelength whereas the electron-withdrawing trifluoromethyl group caused a blue shift in the fluorescence spectra. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00839-1

文献信息

• Polyolefin compositions
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0136381A1

  公开（公告）日：1985-04-10

  A polymer composition comprises an olefinic polymer selected from homopolymers and copolymers of C2-10 aliphatic, ethylenically-unsaturated monomers, and from 100 to 10,000 ppm of a compound which is benzohydrol of a benzohydrol derivative and which has the formula where R, and Rz are the same or different C6-26 aromatic groups and R3 is hydrogen, C1-20 alkyl or C2-20 acyl.

  一种聚合物组合物包含一种烯烃聚合物，选自 C2-10 脂肪族、乙烯基不饱和单体的均聚物和共聚物，以及 100 至 10,000 ppm 的一种化合物，该化合物是苯甲醇的苯甲醇衍生物，其式为 其中 R 和 Rz 是相同或不同的 C6-26 芳族基团，R3 是氢、C1-20 烷基或 C2-20 丙烯酸基。
• US4431497A
  申请人：——

  公开号：US4431497A

  公开（公告）日：1984-02-14
• W(CO)6-Mediated desulfuroligomerization of bis-dithioacetals. New synthesis of substituted oligo(phenylene–vinylenes)
  作者：Chung-Wai Shiau、Clifton K.F Shen、Wei Pan、Chi-Hong Kuo、Shen Chung Kao、Tien-Yau Luh

  DOI：10.1016/s0022-328x(00)00839-1

  日期：2001.4

  Treatment of bisdithioacetals of 1,4-diaroylbenzenes (4) with W(CO)(6) in refluxing chlorobenzene afforded the corresponding substituted oligophenylenevinylenes (OPVs) (5). Average molecular weights determined by GPC indicate that OPVs 5 have 5-13 repetitive substituted phenylenevinylene units with narrow polydispersities. Emission in the blue-green to green region was observed for these OPVs depending on the nature of the substituent. The electron-donating alkoxy substituent shifted the emission to the longer wavelength whereas the electron-withdrawing trifluoromethyl group caused a blue shift in the fluorescence spectra. (C) 2001 Elsevier Science B.V. All rights reserved.