4-Phenylselanylbenzene-1,3-diamine | 1236252-95-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Phenylselanylbenzene-1,3-diamine
• 英文别名: 4-phenylselanylbenzene-1,3-diamine
• CAS: 1236252-95-1
• 化学式: C₁₂H₁₂N₂Se
• 分子量: 263.201
• InChiKey: MXXLZKLOEMLAHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.51
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-Phenylselanylbenzene-1,3-diamine 在 叠氮基三甲基硅烷 、 亚硝酸异戊酯 作用下， 以 四氢呋喃 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Synthesis of azido arylselenides and azido aryldiselenides: a new class of selenium–nitrogen compounds

  摘要：

  We present here our results of the efficient synthesis of azido arylselenides and azido aryldiselenides under mild conditions. Starting from nitrogen-substituted benzenes, we incorporated selenium atom at aromatic ring and obtained amino arylselenides and diselenides in satisfactory yields. Treatment of these compounds with iso-pentyl nitrite (i-C5H11ONO) and azido trimethylsilane (Me3SiN3) in THF affords a variety of azido arylselenides and diselenides in good to excellent yields. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.04.076
• 作为产物：
  描述：

  (2,4-dinitrophenyl)(phenyl)selane 在 氯化铵 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 生成 4-Phenylselanylbenzene-1,3-diamine
  参考文献：
  名称：

  Synthesis of azido arylselenides and azido aryldiselenides: a new class of selenium–nitrogen compounds

  摘要：

  We present here our results of the efficient synthesis of azido arylselenides and azido aryldiselenides under mild conditions. Starting from nitrogen-substituted benzenes, we incorporated selenium atom at aromatic ring and obtained amino arylselenides and diselenides in satisfactory yields. Treatment of these compounds with iso-pentyl nitrite (i-C5H11ONO) and azido trimethylsilane (Me3SiN3) in THF affords a variety of azido arylselenides and diselenides in good to excellent yields. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.04.076

文献信息

• Synthesis of azido arylselenides and azido aryldiselenides: a new class of selenium–nitrogen compounds
  作者：Anna Maria Deobald、Leandro R. Simon de Camargo、Greice Tabarelli、Manfredo Hörner、Oscar E.D. Rodrigues、Diego Alves、Antônio L. Braga

  DOI：10.1016/j.tetlet.2010.04.076

  日期：2010.6

  We present here our results of the efficient synthesis of azido arylselenides and azido aryldiselenides under mild conditions. Starting from nitrogen-substituted benzenes, we incorporated selenium atom at aromatic ring and obtained amino arylselenides and diselenides in satisfactory yields. Treatment of these compounds with iso-pentyl nitrite (i-C5H11ONO) and azido trimethylsilane (Me3SiN3) in THF affords a variety of azido arylselenides and diselenides in good to excellent yields. (C) 2010 Elsevier Ltd. All rights reserved.