1-(2-methoxyethoxy)-3-vinylbenzene | 1313010-14-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(2-methoxyethoxy)-3-vinylbenzene
• 英文别名: 1-Ethenyl-3-(2-methoxyethoxy)benzene
• CAS: 1313010-14-8
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: UAAAWNPLYDBUKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(2-methoxyethoxy)-3-vinylbenzene 在 盐酸 、 甲酸 、 sodium acetate 、 三乙酰氧基硼氢化钠 作用下， 以 二氯甲烷 、 水 、 乙酸乙酯 为溶剂， 反应 15.5h， 生成 N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]-1-{2-[3-(2-methoxyethoxy)phenyl]ethyl}piperidine-4-carboxamide hydrochloride
  参考文献：
  名称：

  Synthesis and Pharmacological Evaluation of 1-Alkyl-N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]piperidine-4-carboxamide Derivatives as Novel Antihypertensive Agents

  摘要：

  我们合成并评估了一系列1-烷基-N-[(1R)-1-(4-氟苯基)-2-甲基丙基]哌啶-4-羧酰胺衍生物对T型钙通道的抑制活性。结构-活性关系研究表明，苄位异丙基取代基在发挥强效抑制活性中起着重要作用，并且苄位的绝对构型与作为新型T型钙通道阻滞剂首次上市的米贝地尔相反。N-[(1R)-1-(4-氟苯基)-2-甲基丙基]-1-[2-(3-甲氧基苯基)乙基]哌啶-4-羧酰胺（17f）的口服给药能降低自发性高血压大鼠的血压，而不会引起反射性心动过速，这是传统L型钙通道阻滞剂常见的不良反应。

  DOI：

  10.1248/cpb.59.1376
• 作为产物：
  描述：

  间羟基苯甲醛 在 potassium tert-butylate 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 反应 28.0h， 生成 1-(2-methoxyethoxy)-3-vinylbenzene
  参考文献：
  名称：

  변성 단량체, 이를 포함하는 변성 중합체 및 이들의 제조방법

  摘要：

  本发明涉及对化学式1表示的聚合物进行改性的有用改性单体、改性单体的制备方法、包含改性单体衍生作用基的改性聚合物及其制备方法、包含改性聚合物的橡胶组合物以及由橡胶组合物制成的成型品。

  公开号：

  KR20210052965A

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Bis(difluoromethyl)pyrazoles as Fungicides
  申请人：CRISTAU Pierre

  公开号：US20110224257A1

  公开（公告）日：2011-09-15

  Bis(difluoromethyl)pyrazole derivatives of the formula (I) in which the symbols R 1 , X and G are each as defined in the description, and agrochemically active salts, metal complexes and N-oxides thereof, and use thereof for controlling phytopathogenic harmful fungi, and also processes for preparing compounds of the formula (I).

  式(I)的双(二氟甲基)吡唑衍生物，其中符号R1、X和G分别如描述中定义，以及其农药活性盐、金属络合物和N-氧化物，以及其用途用于控制植物病原真菌，以及制备式(I)化合物的方法。
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• MODIFIED CONJUGATED DIENE POLYMER AND RUBBER COMPOSITION COMPRISING SAME
  申请人：LG CHEM, LTD.

  公开号：EP3689926A1

  公开（公告）日：2020-08-05

  The present invention relates to a modified conjugated diene-based polymer and a rubber composition including the same, and the modified conjugated diene-based polymer has a unimodal shape molecular weight distribution curve by gel permeation chromatography and narrow molecular weight distribution, and includes a functional group derived from a modification monomer represented by Formula 1 and a functional group derived from a modifier, thereby achieving effect of excellent processability, tensile properties and viscoelasticity properties.

  本发明涉及一种改性共轭二烯基聚合物和一种包括其在内的橡胶组合物，该改性共轭二烯基聚合物通过凝胶渗透色谱法具有单峰形分子量分布曲线和较窄的分子量分布，并包括一个由式 1 所代表的改性单体衍生的官能团和一个由改性剂衍生的官能团，从而实现优异的加工性能、拉伸性能和粘弹性性能。
• Organic electronic material, ink composition containing same, and organic thin film, organic electronic element, organic eletroluminescent element, lighting device, and display device formed therewith
  申请人：Hitachi Chemical Company, Ltd.

  公开号：US10840451B2

  公开（公告）日：2020-11-17

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  本发明提供了：易于多层化且可用于无法在高温下加工的树脂等基板的有机电子材料；含有该有机电子材料的油墨组合物；使用所述有机电子材料或所述油墨组合物形成的有机薄膜；以及使用所述有机薄膜形成的发光效率和发射寿命优于传统元件的有机电子元件和有机电致发光元件。具体地说，提供了：有机电子材料，其特征在于含有低聚物或聚合物，该低聚物或聚合物具有向三个或更多方向分支的结构，并具有至少一个可聚合的取代基；含有所述有机电子材料的油墨组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了含有上述有机薄膜的有机电子元件和有机电致发光元件。