(7-hexyl-7H-indolo[3,2-b]acridin-6-yl)(phenyl)methanone | 1449562-65-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (7-hexyl-7H-indolo[3,2-b]acridin-6-yl)(phenyl)methanone
• 英文别名: (10-Hexyl-10,14-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(21),2,4,6,8,11,13,15,17,19-decaen-12-yl)-phenylmethanone；(10-hexyl-10,14-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(21),2,4,6,8,11,13,15,17,19-decaen-12-yl)-phenylmethanone
• CAS: 1449562-65-5
• 化学式: C₃₂H₂₈N₂O
• 分子量: 456.587
• InChiKey: ACBHXFVGPPRQHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  35
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  34.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-phenylethynyl-quinoline-3-carbaldehyde 、 1-己基吲哚 在 copper(II) bis(trifluoromethanesulfonate) 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 6.0h， 以61%的产率得到(7-hexyl-7H-indolo[3,2-b]acridin-6-yl)(phenyl)methanone
  参考文献：
  名称：

  Synthesis of solid state fluorescent quino[2,3-b]carbazoles via copper(II) triflate-catalyzed heteroannulation: application to detection of TNT

  摘要：

  New analogues of solid state fluorescent quino[2,3-b]carbazoles have been synthesized from heteroannulation of quinoline alkynylaldehyde and indole. Their preliminary photophysical properties are studied and application as chemosensory material for detection of trinitrotoluene is explored. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.016

文献信息

• Synthesis of solid state fluorescent quino[2,3-b]carbazoles via copper(II) triflate-catalyzed heteroannulation: application to detection of TNT
  作者：K.S. Prakash、Rajagopal Nagarajan

  DOI：10.1016/j.tet.2013.07.016

  日期：2013.9

  New analogues of solid state fluorescent quino[2,3-b]carbazoles have been synthesized from heteroannulation of quinoline alkynylaldehyde and indole. Their preliminary photophysical properties are studied and application as chemosensory material for detection of trinitrotoluene is explored. (C) 2013 Elsevier Ltd. All rights reserved.