Endo-phenyl-pyrrole | 557793-49-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: Endo-phenyl-pyrrole
• 英文别名: (1R,2R,6S,7S)-4-phenyl-4,10-diazatetracyclo[5.5.1.02,6.08,12]trideca-8,11-diene-3,5-dione
• CAS: 557793-49-4
• 化学式: C₁₇H₁₄N₂O₂
• 分子量: 278.31
• InChiKey: UAFNZLHJVOCQSV-AGCIHXOGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  53.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-phenylbicyclo[2.2.1]hept-5-ene-2-endo,3-endo-dicarboximide 在 N-氯代丁二酰亚胺 、 potassium tert-butylate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 间氯过氧苯甲酸 、 三氟乙酸 、 lithium chloride 作用下， 以 四氢呋喃 、 二氯甲烷 、 氯仿 、 乙二醇 为溶剂， 生成 Endo-phenyl-pyrrole
  参考文献：
  名称：

  Defining Space around Conducting Polymers:  Reversible Protonic Doping of a Canopied Polypyrrole

  摘要：

  A canopy-shaped pyrrole derivative 2 was prepared, in which a sterically demanding pendant group is juxtaposed to the pyrrole fragment to minimize interstrand pi-pi stacking interactions in the resulting polymer. Anodic polymerization of 2 afforded highly conductive poly(2), the electronic structure of which was probed by various spectroelectrochemical techniques. A limited charge delocalization within poly(2) translates into a well-defined conductivity profile, properties important for resistivity-based sensing. Notably, the bulk conductivity was precisely modulated by a rapid and reversible deprotonation and reprotonation of the polymer backbone.

  DOI：

  10.1021/ja034894+

文献信息

• Defining Space around Conducting Polymers:  Reversible Protonic Doping of a Canopied Polypyrrole
  作者：Dongwhan Lee、Timothy M. Swager

  DOI：10.1021/ja034894+

  日期：2003.6.1

  A canopy-shaped pyrrole derivative 2 was prepared, in which a sterically demanding pendant group is juxtaposed to the pyrrole fragment to minimize interstrand pi-pi stacking interactions in the resulting polymer. Anodic polymerization of 2 afforded highly conductive poly(2), the electronic structure of which was probed by various spectroelectrochemical techniques. A limited charge delocalization within poly(2) translates into a well-defined conductivity profile, properties important for resistivity-based sensing. Notably, the bulk conductivity was precisely modulated by a rapid and reversible deprotonation and reprotonation of the polymer backbone.