2,4,6-tris(3,5-dimethylphenylamino)-1,3,5-triazine | 664312-95-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris(3,5-dimethylphenylamino)-1,3,5-triazine
• 英文别名: 2-N,4-N,6-N-tris(3,5-dimethylphenyl)-1,3,5-triazine-2,4,6-triamine
• CAS: 664312-95-2
• 化学式: C₂₇H₃₀N₆
• 分子量: 438.575
• InChiKey: MOSXNKUOAYSREX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  74.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 1-氨基-3,5-二甲苯 在 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到2,4,6-tris(3,5-dimethylphenylamino)-1,3,5-triazine
  参考文献：
  名称：

  Anarchy in the solid state: structural dependence on glass-forming ability in triazine-based molecular glasses

  摘要：

  We have recently shown that molecular glasses, small molecules capable of readily forming glassy solids as opposed to crystals, can be designed by exploiting molecular association through strong and directional intermolecular interactions, as exemplified by several members of the bis(mexylantino)triazine family. Herein, 43 new bis(mexylamino)triazine derivatives were synthesized, 31 of which have been found to spontaneously form glassy phases and did not crystallize upon heating. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.07.026

文献信息

• LIQUID CRYSTAL POLYMER AND FILM THEREOF
  申请人：Uehira Shigeki

  公开号：US20090240022A1

  公开（公告）日：2009-09-24

  A liquid crystal polymer represented by the following formula (I): wherein D represents a n-valence connecting group; n represents an integer of 3 to 20; L 1 represents a single bond or a bivalent connecting group; P represents a polymer having at least one ester bond and/or amide bond and having a weight-average molecular weight of 1,000 or more; m represents an integer that satisfies the relation of n≧m; R represents a hydrogen atom or a substituent; when a plurality of L 1 , a plurality of P, or a plurality of R are present in a molecule, they may be the same or different from each other; and P and P, or P and R may bond together.
• US7888450B2
  申请人：——

  公开号：US7888450B2

  公开（公告）日：2011-02-15
• Anarchy in the solid state: structural dependence on glass-forming ability in triazine-based molecular glasses
  作者：James D. Wuest、Olivier Lebel

  DOI：10.1016/j.tet.2009.07.026

  日期：2009.9

  We have recently shown that molecular glasses, small molecules capable of readily forming glassy solids as opposed to crystals, can be designed by exploiting molecular association through strong and directional intermolecular interactions, as exemplified by several members of the bis(mexylantino)triazine family. Herein, 43 new bis(mexylamino)triazine derivatives were synthesized, 31 of which have been found to spontaneously form glassy phases and did not crystallize upon heating. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.