1-Methoxy-2-propylsulfanyl-benzene | 1779124-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-Methoxy-2-propylsulfanyl-benzene
• 英文别名: 2-Methoxyphenyl 1-propylsulfide；1-methoxy-2-propylsulfanylbenzene
• CAS: 1779124-33-2
• 化学式: C₁₀H₁₄OS
• mdl: MFCD26142716
• 分子量: 182.287
• InChiKey: VCSXGOFEROODCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 1-Methoxy-2-propylsulfanyl-benzene 在 正丁基锂 作用下， 生成 1-Methoxy-2-(trimethylsilyl)-6-(propylthio)benzene
  参考文献：
  名称：

  Metalation reactions. XIV. Regiospecific preparation of polysubstituted benzenes mono- or di-lithiation reactions of aromatic thioethers

  摘要：

  DOI：

  10.1016/s0040-4020(01)81368-5
• 作为产物：
  描述：

  1-methoxy-2-(2-propenylthio)benzene 在 氧气 、 copper(l) chloride 、 肼 作用下， 反应 18.0h， 以95%的产率得到1-Methoxy-2-propylsulfanyl-benzene
  参考文献：
  名称：

  共生过渡金属和有机催化用于催化环境胺氧化和烯烃还原反应

  摘要：

  一种新的基于两种简单催化剂的氧化反应，即四氧嘧啶和Cu I盐，对胺的需氧氧化和氧化交叉偶联非常有效。该反应操作简单，避免了富含双氧的反应气氛，并且两种催化剂组分都不需要事先合成。已经进行了机理研究，并指出了一个复杂的反应流形，其证据支持了不会通过醌-亚胺步骤进行的催化循环。此外，这种双催化剂体系可有效地进行烯烃和炔烃的二酰亚胺介导的加氢反应，这一转变以前在醌催化剂体系中尚未见报道。

  DOI：

  10.1002/cctc.201501153

文献信息

• Photosensitive resin composition, light-shielding color filter and production process therefor, and image sensor
  申请人：FUJIFILM Corporation

  公开号：EP2105792A1

  公开（公告）日：2009-09-30

  A photosensitive resin composition is provided that includes at least (A) titanium black, (B) two or more types of polymerizable compounds, (C) a resin, (D) a photopolymerization initiator, and (E) an organic solvent. There are also provided a light-shielding color filter formed by using the photosensitive resin composition, and a process for producing a light-shielding color filter, the process including a step of coating a substrate with the photosensitive resin composition, a step of imagewise exposing, and a step of developing to form a pattern. Furthermore, there is provided an image sensor that includes the light-shielding color filter.

  提供了一种光敏树脂组合物，它至少包括 (A) 钛黑、(B) 两种或两种以上的可聚合化合物、(C) 树脂、(D) 光聚合引发剂和 (E) 有机溶剂。此外，还提供了一种通过使用感光树脂组合物形成的遮光彩色滤光片，以及一种生产遮光彩色滤光片的工艺，该工艺包括用感光树脂组合物涂覆基底的步骤、图像曝光步骤，以及显影以形成图案的步骤。此外，还提供了一种包括遮光彩色滤光片的图像传感器。
• [EN] THIOLIZED INDOLIZINE COMPOUND HAVING ANTICANCER ACTIVITY AND DERIVATIVE THEREOF<br/>[FR] COMPOSÉ D'INDOLIZINE THIOLISÉ À ACTIVITÉ ANTICANCÉREUSE ET SON DÉRIVÉ<br/>[ZH] 一类具有抗癌活性的硫代吲嗪类化合物及其衍生物
  申请人：GUANG DONG PHARMACEUTICAL UNIV

  公开号：WO2019232665A1

  公开（公告）日：2019-12-12

  提供一类具有抗癌活性的硫代吲嗪类化合物及其衍生物。其以如下（I）所示：所述化合物及其衍生物对多种癌症及肿瘤都有抑制作用。
• PHOTOSENSITIVE RESIN COMPOSITION, LIGHT-SHIELDING COLOR FILTER AND PRODUCTION PROCESS THEREFOR, AND IMAGE SENSOR
  申请人：FUJIMORI Toru

  公开号：US20090246650A1

  公开（公告）日：2009-10-01

  A photosensitive resin composition is provided that includes at least (A) titanium black, (B) two or more types of polymerizable compounds, (C) a resin, (D) a photopolymerization initiator, and (E) an organic solvent. There are also provided a light-shielding color filter formed by using the photosensitive resin composition, and a process for producing a light-shielding color filter, the process including a step of coating a substrate with the photosensitive resin composition, a step of imagewise exposing, and a step of developing to form a pattern. Furthermore, there is provided an image sensor that includes the light-shielding color filter.
• BLACK CURABLE COMPOSITION, LIGHT-SHIELDING COLOR FILTER FOR A SOLID-STATE IMAGING DEVICE AND METHOD OF PRODUCING THE SAME, SOLID-STATE IMAGING DEVICE, WAFER LEVEL LENS, AND CAMERA MODULE
  申请人：Kaneko Yushi

  公开号：US20130028587A1

  公开（公告）日：2013-01-31

  A black curable composition for forming a light-shielding color filter of solid-state imaging device is provided, which is capable of forming a pattern at low exposure dose even when containing a high concentration of an inorganic pigment, and preventing pattern defects. Also, a black curable composition for a wafer level lens is provided, which is capable of forming a cured film having excellent light shieldability and excellent in co-formability of both a large pattern and a fine pattern. The composition includes: an inorganic pigment; a copolymer containing a monomer having at least one of an amino group and a nitrogen-containing heterocyclic group, a monomer having at least one group of a carboxyl group, a phosphate group and a sulfonate group, and a macromonomer having a weight average molecular weight from 1,000 to 50,000; a polymerization initiator; a polymerizable compound; and an alkali-soluble resin having an unsaturated double bond.
• US8110324B2
  申请人：——

  公开号：US8110324B2

  公开（公告）日：2012-02-07