N-hexadecyloctanamide

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-hexadecyloctanamide
• 化学式: C₂₄H₄₉NO
• 分子量: 367.659
• InChiKey: FKLBQDVITUAPTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  26
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  十六胺 、 4-硝基苯基辛酸酯 在 十六烷基三甲基溴化铵 作用下， 以 正己烷 、 水 为溶剂， 生成 4-硝基苯酚阴离子 、 N-hexadecyloctanamide
  参考文献：
  名称：

  摘要：

  In hydrolysis and aminolysis of p-nitrophenyl esters of carboxylic acids in oil-in-water microemulsions on the basis of surfactants of various nature, a complex mechanism of the effect of the medium is operative, including shift of acid-base equilibria in the nucleophile. The rate constants of the processes studied are quantitatively related to the surface potential of the microdroplet. Varied hydrophobicity of the nucleophile and substrate changes the site of the reaction act and the relative contributions of aminolysis and hydrolysis.

  DOI：

  10.1023/a:1020892132432

文献信息

• ——
  作者：A. B. Mirgorodskaya、L. A. Kudryavtseva

  DOI：10.1023/a:1020892132432

  日期：——

  In hydrolysis and aminolysis of p-nitrophenyl esters of carboxylic acids in oil-in-water microemulsions on the basis of surfactants of various nature, a complex mechanism of the effect of the medium is operative, including shift of acid-base equilibria in the nucleophile. The rate constants of the processes studied are quantitatively related to the surface potential of the microdroplet. Varied hydrophobicity of the nucleophile and substrate changes the site of the reaction act and the relative contributions of aminolysis and hydrolysis.