13-Hydroxy-tetradecan-2-one | 119225-68-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 13-Hydroxy-tetradecan-2-one
• 英文别名: 13-Hydroxytetradecan-2-one
• CAS: 119225-68-2
• 化学式: C₁₄H₂₈O₂
• 分子量: 228.375
• InChiKey: AQEUHQUTDIFHOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  12-oxotridecanal 、 甲基锂 在 甲铝双(2,6-二叔丁基-4-苯甲醚) 作用下， 以72%的产率得到13-Hydroxy-tetradecan-2-one
  参考文献：
  名称：

  化学选择性羰基烷基化和醛或酮的还原

  摘要：

  用两亲性反应体系MAD / RLi或MAD / RMgX可以实现在酮存在下的化学选择性羰基烷基化和醛的还原，而使用Me 2 AlNMePh / RLi系统可以实现酮的选择性羰基烷基化。

  DOI：

  10.1016/0040-4039(88)85096-2

文献信息

• COLORED CURABLE COMPOSITION FOR COLOR FILTER, COLOR FILTER AND METHOD FOR PRODUCING THE SAME, AND SOLID STATE IMAGING DEVICE
  申请人：AOYAGI Kaoru

  公开号：US20100248095A1

  公开（公告）日：2010-09-30

  A colored curable composition for a color filter includes: (A) a pigment in an amount of from 35 to 70 mass % with respect to the total solid content of the colored curable composition, (B) an amino resin, (C) an alkali-soluble resin, (D) a polymerizable monomer, and (E) a photopolymerization initiator, in which the proportion of (B) the amino resin to (C) the alkali-soluble resin (B/C; mass ratio) is in the range of from 1 to 10.
• COLORED COMPOSITION, METHOD OF PRODUCING COLOR FILTER USING THE SAME, COLOR FILTER AND SOLID-STATE IMAGING DEVICE
  申请人：FUJIFILM CORPORATION

  公开号：US20140145286A1

  公开（公告）日：2014-05-29

  The invention is directed to a colored composition containing a coloring agent and a resin, wherein a content of the coloring agent to a total solid content of the colored composition is 50% by weight or more and a solid content acid value of the resin is more than 80 mg KOH/g, and a method of producing a color filter including forming a first colored layer containing a first colored composition and patterning with dry etching so as to from a through-hole group in the first colored layer, wherein the first colored composition is the colored composition as defined herein.
• OPTICAL MEMBER SET AND SOLID-STATE IMAGING ELEMENT USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20140284747A1

  公开（公告）日：2014-09-25

  An optical member set which has a first optical member formed by curing a curable resin composition, and a second optical member which is covered by the first optical member, in which the first optical member has a refractive index of 1.25 to 1.45 and the second optical member has a refractive index of 1.65 to 1.95.
• CURABLE RESIN COMPOSITION, INFRARED RAY CUTOFF FILTER AND SOLID-STATE IMAGING DEVICE USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20150277002A1

  公开（公告）日：2015-10-01

  According to an exemplary embodiment of the present invention, there is provided a curable resin composition comprising a dye having a maximum absorption wavelength in a range of 600 nm to 820 nm, and being capable of forming a high refractive index layer with a refractive index ranging from 1.65 to 2.00.
• COMPOSITION FOR FORMING FAR-INFRARED RADIATION SHIELDING LAYER
  申请人：FUJIFILM Corporation

  公开号：US20160033680A1

  公开（公告）日：2016-02-04

  An object of the present invention is to provide a composition for forming a far-infrared radiation shielding layer which is able to form a layer having excellent far-infrared radiation shielding properties. A composition for forming a far-infrared radiation shielding layer of the present invention contains at least inorganic fine particles and a dispersant.