bis-(4-lauroylamino-phenyl)-disulfide | 5325-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(4-lauroylamino-phenyl)-disulfide
• 英文别名: Bis-(4-lauroylamino-phenyl)-disulfid；N,N'-(Dithiobis(4,1-phenylene))didodecanamide；N-[4-[[4-(dodecanoylamino)phenyl]disulfanyl]phenyl]dodecanamide
• CAS: 5325-83-7
• 化学式: C₃₆H₅₆N₂O₂S₂
• 分子量: 612.985
• InChiKey: IDJUDSPIWBZZKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.7
• 重原子数：
  42
• 可旋转键数：
  25
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis-(4-lauroylamino-phenyl)-disulfide 在 lithium aluminium tetrahydride 作用下， 生成 bis-(4-dodecylamino-phenyl)-disulfide
  参考文献：
  名称：

  Bis-type modifiers in polymerization. II. Comparison of effectiveness of various compounds in emulsion butadiene and bulk styrene polymerizations

  摘要：

  AbstractThe present paper describes the preparation and evaluation of the effectiveness as modifiers of a number of compounds of bis‐type structure—principally aryl disulfides—in bulk styrene and emulsion butadiene polymerizations. This work endeavors to explore some of the objectives described in the first paper of this series, and deals primarily with attempts to gain quantitative information on the effect of the nature and location of substituting groups with respect to the dissociating bond. The compounds examined include both those containing reactive groups attached and those lacking such groups. A number of the preparations are now compounds. Evaluations in 50°C. bulk styrene were carried out with the objective of eliminating the complications of the diffusion factor always present in emulsion systems. Generally speaking, the correlation between effectiveness in bulk styrene and 50°C. emulsion butadiene was quite good, though there were exceptions. It was found that the modifier activity of many compounds in emulsion butadiene could be enhanced by predispersing them in the aqueous phase—presumably a result of minimizing the importance of diffusion rate. Some of the modifiers were also tested in a low temperature butadiene emulsion system. Aryl disulfides continue to offer the most promise from the standpoint of combining the features of attaining high transfer constants and ease of incorporating desired reactive groups. Some compounds had adequate activity in emulsion butadiene polymerizations for use as practical modifiers. However, it has not yet been established that these compounds cleave to give one‐half the molecule on each end of the butadiene polymer chain, as has been done for styrene polymers.

  DOI：

  10.1002/pol.1955.120178501
• 作为产物：
  描述：

  4,4'-二氨基二苯二硫醚 、 月桂酰氯 生成 bis-(4-lauroylamino-phenyl)-disulfide
  参考文献：
  名称：

  Bis-type modifiers in polymerization. II. Comparison of effectiveness of various compounds in emulsion butadiene and bulk styrene polymerizations

  摘要：

  AbstractThe present paper describes the preparation and evaluation of the effectiveness as modifiers of a number of compounds of bis‐type structure—principally aryl disulfides—in bulk styrene and emulsion butadiene polymerizations. This work endeavors to explore some of the objectives described in the first paper of this series, and deals primarily with attempts to gain quantitative information on the effect of the nature and location of substituting groups with respect to the dissociating bond. The compounds examined include both those containing reactive groups attached and those lacking such groups. A number of the preparations are now compounds. Evaluations in 50°C. bulk styrene were carried out with the objective of eliminating the complications of the diffusion factor always present in emulsion systems. Generally speaking, the correlation between effectiveness in bulk styrene and 50°C. emulsion butadiene was quite good, though there were exceptions. It was found that the modifier activity of many compounds in emulsion butadiene could be enhanced by predispersing them in the aqueous phase—presumably a result of minimizing the importance of diffusion rate. Some of the modifiers were also tested in a low temperature butadiene emulsion system. Aryl disulfides continue to offer the most promise from the standpoint of combining the features of attaining high transfer constants and ease of incorporating desired reactive groups. Some compounds had adequate activity in emulsion butadiene polymerizations for use as practical modifiers. However, it has not yet been established that these compounds cleave to give one‐half the molecule on each end of the butadiene polymer chain, as has been done for styrene polymers.

  DOI：

  10.1002/pol.1955.120178501

文献信息

• US5194539A
  申请人：——

  公开号：US5194539A

  公开（公告）日：1993-03-16
• Bis-type modifiers in polymerization. II. Comparison of effectiveness of various compounds in emulsion butadiene and bulk styrene polymerizations
  作者：A. J. Costanza、R. J. Coleman、R. M. Pierson、C. S. Marvel、Charles King

  DOI：10.1002/pol.1955.120178501

  日期：1955.7

  AbstractThe present paper describes the preparation and evaluation of the effectiveness as modifiers of a number of compounds of bis‐type structure—principally aryl disulfides—in bulk styrene and emulsion butadiene polymerizations. This work endeavors to explore some of the objectives described in the first paper of this series, and deals primarily with attempts to gain quantitative information on the effect of the nature and location of substituting groups with respect to the dissociating bond. The compounds examined include both those containing reactive groups attached and those lacking such groups. A number of the preparations are now compounds. Evaluations in 50°C. bulk styrene were carried out with the objective of eliminating the complications of the diffusion factor always present in emulsion systems. Generally speaking, the correlation between effectiveness in bulk styrene and 50°C. emulsion butadiene was quite good, though there were exceptions. It was found that the modifier activity of many compounds in emulsion butadiene could be enhanced by predispersing them in the aqueous phase—presumably a result of minimizing the importance of diffusion rate. Some of the modifiers were also tested in a low temperature butadiene emulsion system. Aryl disulfides continue to offer the most promise from the standpoint of combining the features of attaining high transfer constants and ease of incorporating desired reactive groups. Some compounds had adequate activity in emulsion butadiene polymerizations for use as practical modifiers. However, it has not yet been established that these compounds cleave to give one‐half the molecule on each end of the butadiene polymer chain, as has been done for styrene polymers.