kaempferol 3-O-sophoroside | 160111-95-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: kaempferol 3-O-sophoroside
• 英文别名: 3-[(2R,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-5,7-dihydroxy-2-(4-hydroxyphenyl)chromen-4-one
• CAS: 160111-95-5
• 化学式: C₂₇H₃₀O₁₆
• 分子量: 610.526
• InChiKey: LKZDFKLGDGSGEO-FFFMXZAGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  43
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  266
• 氢给体数：
  10
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  kaempferol 3-O-sophoroside-7-O-β-D-glucopyranoside 在 β-glucosidase 作用下， 以 水 为溶剂， 反应 24.0h， 生成 kaempferol 3-O-sophoroside
  参考文献：
  名称：

  Kaempferol glycosides from Hosta ventricosa

  摘要：

  Leaves of Hosta ventricosa yielded eight kaempferol glycosides, of which six: the 3-(2G-glucosylrutinoside)-7-glucoside, 3-sophoroside-7-glucoside, 3-rutinoside-7-glucoside, 3-(2G-glucosylrutinoside), 3-sophoroside, 3-rutinoside were fully characterized and two: the 3-xylosylrutinoside-7-glucoside and 3-xylosylrutinoside were tentatively identified. Investigations included 1H-1H COSY and 1H-1H 2D J NMR analysis.

  DOI：

  10.1016/0031-9422(90)85292-n

文献信息

• Kaempferol glycosides from Hosta ventricosa
  作者：Jaromir Budzianowski

  DOI：10.1016/0031-9422(90)85292-n

  日期：1990.1

  Leaves of Hosta ventricosa yielded eight kaempferol glycosides, of which six: the 3-(2G-glucosylrutinoside)-7-glucoside, 3-sophoroside-7-glucoside, 3-rutinoside-7-glucoside, 3-(2G-glucosylrutinoside), 3-sophoroside, 3-rutinoside were fully characterized and two: the 3-xylosylrutinoside-7-glucoside and 3-xylosylrutinoside were tentatively identified. Investigations included 1H-1H COSY and 1H-1H 2D J NMR analysis.