14,18,33,37-tetramethyl-11-N,11-N,30-N,30-N-tetraphenylnonacyclo[20.16.0.03,20.04,17.07,16.08,13.023,36.026,35.027,32]octatriaconta-1,3(20),4(17),5,7(16),8(13),9,11,14,18,21,23(36),24,26(35),27(32),28,30,33,37-nonadecaene-11,30-diamine | 1264757-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 14,18,33,37-tetramethyl-11-N,11-N,30-N,30-N-tetraphenylnonacyclo[20.16.0.03,20.04,17.07,16.08,13.023,36.026,35.027,32]octatriaconta-1,3(20),4(17),5,7(16),8(13),9,11,14,18,21,23(36),24,26(35),27(32),28,30,33,37-nonadecaene-11,30-diamine
• CAS: 1264757-09-6
• 化学式: C₆₆H₄₈N₂
• 分子量: 869.121
• InChiKey: INASOWXLZGJTOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.9
• 重原子数：
  68
• 可旋转键数：
  6
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,N-diphenyl-6-[4-[6-(N-phenylanilino)naphthalen-2-yl]-2,5-bis(prop-1-ynyl)phenyl]naphthalen-2-amine 在 一氧化碳 、 platinum(II) chloride 作用下， 以 甲苯 为溶剂， 反应 12.5h， 以59%的产率得到14,18,33,37-tetramethyl-11-N,11-N,30-N,30-N-tetraphenylnonacyclo[20.16.0.03,20.04,17.07,16.08,13.023,36.026,35.027,32]octatriaconta-1,3(20),4(17),5,7(16),8(13),9,11,14,18,21,23(36),24,26(35),27(32),28,30,33,37-nonadecaene-11,30-diamine
  参考文献：
  名称：

  Ph₂N-Susbtituted Ethylene-Bridged p-Phenylene Oligomers: Synthesis and Photophysical and Redox Properties

  摘要：

  For a series of p-phenylene-based oligomers terminated with two triphenylamines, their absorption, photoluminescence, and band gaps show a pattern of extensive pi-conjugation with increasing array size. Oligomers with large central arrays have greater quantum yields than their small analogues. Cyclic voltammetric (CV) measurements indicated two-step oxidations of the two diphenylamino groups for compounds 1-5 and one-step oxidations for the two amines of large oligomers 6 and 7.

  DOI：

  10.1021/jo1020163