N-methyl-2-aminoethyl-methacrylate | 25012-66-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-methyl-2-aminoethyl-methacrylate
• 英文别名: 2-(methylamino)ethyl methacrylate；Methacrylsaeure-(2-methylamino-ethylester)；2-(N-Methylamino)aethyl-methacrylat；2-(Methylamino)aethylmethacrylat；Methacrylsaeure-<2-methylamino-aethylester>；methylaminoethyl-methacrylate；2-Propenoic acid, 2-methyl-, 2-(methylamino)ethyl ester；2-(methylamino)ethyl 2-methylprop-2-enoate
• CAS: 25012-66-2
• 化学式: C₇H₁₃NO₂
• mdl: MFCD19217296
• 分子量: 143.186
• InChiKey: DEGZUQBZHACZKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.571
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-methyl-2-aminoethyl-methacrylate 在 caesium carbonate 、 三氟乙酸 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 27.0h， 生成 3,3,3-trifluoro-2-((2-(methacryloyloxy)ethyl)dimethylammonio)propanoate
  参考文献：
  名称：

  FLUORINATED ZWITTERIONIC POLYMERS AND METHODS OF USE

  摘要：

  Fluorinated monomer compositions having the formula: A-L-Z (1), wherein A is a polymerizable group (e.g., a vinyl group); L is a bond or linking portion; Z is a zwitterionic moiety or a zwitterionic precursor moiety containing a protecting group capable of deprotection to form a charged group; wherein at least one hydrogen atom in A, L, and/or Z in Formula (1) is substituted by a fluorinated hydrocarbon group, wherein the fluorinated hydrocarbon group contains 1-12 carbon atoms and precisely or at least one, two, three, four, five, or six fluorine atoms. Also described herein are fluorinated zwitterionic polymers derived from such monomers. Also described herein are mixed-charge zwitterionic polymers. Other aspects include methods for producing the monomers and polymers, bulk material (e.g., hydrogel or copolymer hybrid) compositions of any of the zwitterionic polymers described herein, fouling-resistant and/or fouling releasing surfaces and objects, and nanoparticles containing the polymer or bulk material.

  公开号：

  WO2023249926A2
• 作为产物：
  描述：

  N-methyl-N-tert-butyloxycarbonyl-(2-aminoethyl) methacrylate 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 生成 N-methyl-2-aminoethyl-methacrylate
  参考文献：
  名称：

  FLUORINATED ZWITTERIONIC POLYMERS AND METHODS OF USE

  摘要：

  Fluorinated monomer compositions having the formula: A-L-Z (1), wherein A is a polymerizable group (e.g., a vinyl group); L is a bond or linking portion; Z is a zwitterionic moiety or a zwitterionic precursor moiety containing a protecting group capable of deprotection to form a charged group; wherein at least one hydrogen atom in A, L, and/or Z in Formula (1) is substituted by a fluorinated hydrocarbon group, wherein the fluorinated hydrocarbon group contains 1-12 carbon atoms and precisely or at least one, two, three, four, five, or six fluorine atoms. Also described herein are fluorinated zwitterionic polymers derived from such monomers. Also described herein are mixed-charge zwitterionic polymers. Other aspects include methods for producing the monomers and polymers, bulk material (e.g., hydrogel or copolymer hybrid) compositions of any of the zwitterionic polymers described herein, fouling-resistant and/or fouling releasing surfaces and objects, and nanoparticles containing the polymer or bulk material.

  公开号：

  WO2023249926A2

文献信息

• SALT, RESIN, RESIST COMPOSITION AND METHOD FOR PRODUCING RESIST PATTERN
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20160052877A1

  公开（公告）日：2016-02-25

  A salt represented by the formula (I); wherein Q 1 and Q 2 each independently represent a fluorine atom or a C 1 to C 6 perfluoroalkyl group, L b1 represents a single bond or a divalent C 1 to C 24 saturated hydrocarbon groupwhere a methylene group may be replaced by an oxygen atom or a carbonyl group and where a hydrogen atom may be replaced by a hydroxyl group or a fluorine atom, and Y represents a hydrogen atom, a fluorine atom, or an optionally substituted C 3 to C 18 alicyclic hydrocarbon groupwhere a methylene group may be replaced by an oxygen atom, a carbonyl group or a sulfonyl group; and Ar represents a divalent C 6 to C 20 aromatic hydrocarbon group, and Z + represents an organic sulfonium cation or an organic iodonium cation.

  根据您的要求，以下是化合物的中文翻译： 由公式(I)表示的盐； 其中Q1和Q2各自独立代表一个氟原子或一个C1至C6的过氟代烷基团，Lb1代表一个单键或一个二价的C1至C24的饱和烃基团，其中甲基烯基团可以被一个氧原子或一个羰基团所取代，并且其中氢原子可以被一个羟基或一个氟原子所取代，并且Y代表一个氢原子，一个氟原子，或一个可选地被取代的C3至C18的芳环烃基团，其中甲基烯基团可以被一个氧原子，一个羰基团或一个磺酰基团所取代；并且Ar代表一个二价的C6至C20的芳香烃基团，以及Z+代表一个有机硫正离子或一个有机碘正离子。
• AROMATIC SUBSTITUTED ALKANE-CORE MONOMERS AND POLYMERS THEREOF FOR VOLUME BRAGG GRATINGS
  申请人：Facebook Technologies, LLC

  公开号：US20210155599A1

  公开（公告）日：2021-05-27

  The disclosure provides recording materials including aromatic substituted alkane-core derivatized monomers and polymers for use in volume Bragg gratings, including, but not limited to, volume Bragg gratings for holography applications. Several structures are disclosed, including Formula I. When used in Bragg gratings applications, the monomers and polymers disclosed lead to materials with higher refractive index, low birefringence, and high transparency. The disclosed derivatized monomers and polymers can be used in any volume Bragg gratings materials, including two-stage polymer materials where a matrix is cured in a first step, and then the volume Bragg grating is written by way of a second curing step of a monomer.

  披露提供了包括芳香取代烷基核衍生单体和聚合物在内的记录材料，用于体积布拉格光栅，包括但不限于用于全息应用的体积布拉格光栅。披露了几种结构，包括式I。当在布拉格光栅应用中使用时，披露的单体和聚合物导致具有较高折射率、低双折射和高透明度的材料。披露的衍生单体和聚合物可用于任何体积布拉格光栅材料，包括两阶段聚合物材料，其中矩阵在第一步中固化，然后通过单体的第二次固化步骤编写布拉格光栅。
• ANTHRAQUINONE DERIVATIZED MONOMERS AND POLYMERS FOR VOLUME BRAGG GRATINGS
  申请人：Facebook Technologies, LLC

  公开号：US20210155585A1

  公开（公告）日：2021-05-27

  The disclosure provides recording materials including anthraquinone derivatized monomers and polymers for use in volume Bragg gratings, including, but not limited to, volume Bragg gratings for holography applications. Several structures are disclosed for anthraquinone derivatized monomers and polymers for use in Bragg gratings applications, leading to materials with higher refractive index, low birefringence, and high transparency. The disclosed anthraquinone derivatized monomers and polymers thereof can be used in any volume Bragg gratings materials, including two-stage polymer materials where a matrix is cured in a first step, and then the volume Bragg grating is written by way of a second curing step of a monomer.

  该披露提供了用于体积布拉格光栅的记录材料，包括蒽醌衍生单体和聚合物，包括但不限于用于全息应用的体积布拉格光栅。揭示了几种用于布拉格光栅应用的蒽醌衍生单体和聚合物的结构，导致具有更高折射率、低双折射和高透明度的材料。所披露的蒽醌衍生单体和聚合物可以用于任何体积布拉格光栅材料，包括两阶段聚合物材料，在第一步中固化基体，然后通过第二步的单体固化来编写体积布拉格光栅。
• POLYVINYL ULTRAVIOLET LIGHT ABSORBERS FOR PERSONAL CARE
  申请人：Maleski Robert Joseph

  公开号：US20090185988A1

  公开（公告）日：2009-07-23

  UV-absorbing polymers and copolymers suitable for Composition into sunscreens for the protection of human skin. The UV-absorbing chromophoric monomers chosen are simple and easily synthesized. With the correct choice of chromophoric monomer or mixture of monomers, protection against UV-A radiation or against both UV-A and UV-B radiation can be achieved. With the correct choice of comonomer, copolymers produced as aqueous latex emulsions or as Polyethylene Glycol solutions can also be achieved.

  适用于组成防晒霜以保护人类皮肤的UV吸收聚合物和共聚物。选择的UV吸收色团单体简单易合成。通过正确选择色团单体或混合物，可实现对UV-A辐射或对UV-A和UV-B辐射的保护。通过正确选择共聚单体，也可以生产水乳液乳胶或聚乙二醇溶液中的共聚物。
• [EN] NANOPARTICLES FOR DELIVERY OF A PHARMACOLOGICALLY ACTIVE AGENT<br/>[FR] NANOPARTICLES PERMETTANT DE DISTRIBUER UN AGENT PHARMACEUTIQUEMENT ACTIF
  申请人：IST SUPERIORE SANITA

  公开号：WO2005048997A1

  公开（公告）日：2005-06-02

  Core-shell nanoparticles comprising: (a) a core which comprises a water insoluble polymer or copolymer, and (b) a shell which comprises a hydrophilic polymer or copolymer; said nanoparticles being obtainable by emulsion polymerization of a mixture comprising, in an aqueous solution, at least one water-insoluble styrenic, acrylic or methacrylic monomer and specific hydrophylic monomers or copolymers.

  核壳结构纳米颗粒包括：（a）核心，其中包括水不溶性聚合物或共聚物，和（b）壳层，其中包括亲水性聚合物或共聚物；所述纳米颗粒可以通过乳液聚合制备，其中包括至少一种水不溶性苯乙烯，丙烯酸或甲基丙烯酸单体和特定的亲水性单体或共聚物在水溶液中混合。