(E)-1-(chloromethyl)-3,5-distyrylbenzene | 1028493-70-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: (E)-1-(chloromethyl)-3,5-distyrylbenzene
• 英文别名: 1-(chloromethyl)-3,5-bis[(E)-2-phenylethenyl]benzene
• CAS: 1028493-70-0
• 化学式: C₂₃H₁₉Cl
• 分子量: 330.857
• InChiKey: KPXVCNZDSGZNPW-PHEQNACWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-1-(chloromethyl)-3,5-distyrylbenzene 、 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin 在 18-冠醚-6 、 potassium carbonate 作用下， 以 丙酮 、 乙酸乙酯 为溶剂， 反应 168.33h， 以55%的产率得到
  参考文献：
  名称：

  Synthesis and NLO behavior of Oligo(phenylenevinylene)-Porphyrin Dendrimers

  摘要：

  Dendrons with a porphyrin core and pi-conjugated dendron branches with 8 and 16 stilbene groups have been synthesized and characterized. The dendrons used for dendrimer synthesis possessed an all trans configuration. Cubic non-linear optical behavior of the styryl and porphyrin-containing dendrimers was tested via Z-Scan measurements in spin-coated film samples. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.07.011
• 作为产物：
  描述：

  (E)-3,5-distyrylbenzaldehyde 在 吡啶 、 lithium aluminium tetrahydride 、 氯化亚砜 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 11.0h， 生成 (E)-1-(chloromethyl)-3,5-distyrylbenzene
  参考文献：
  名称：

  Synthesis and NLO behavior of Oligo(phenylenevinylene)-Porphyrin Dendrimers

  摘要：

  Dendrons with a porphyrin core and pi-conjugated dendron branches with 8 and 16 stilbene groups have been synthesized and characterized. The dendrons used for dendrimer synthesis possessed an all trans configuration. Cubic non-linear optical behavior of the styryl and porphyrin-containing dendrimers was tested via Z-Scan measurements in spin-coated film samples. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.07.011

文献信息

• Synthesis and cubic nonlinear optical behavior of phenyl and ferrocenyl-ended resorcinarene-based dendrimers
  作者：Irina Victorovna-Lijanova、Maria I. Reyes-Valderrama、José-Luis Maldonado、Gabriel Ramos-Ortiz、Klimova Tatiana、Marcos Martínez-García

  DOI：10.1016/j.tet.2008.02.050

  日期：2008.5

  Dendrimers were synthesized with phenyl and ferrocenyl-ended groups joined by vinyl moieties. All the dendrons used for dendrimers synthesis had showed trans configuration. This configuration as well as the 'cone' conformation of the resorcinarenes was preserved in the dendrimers. as it was shown by H-1 NMR spectroscopy. The chemical structure and purity of the synthesized dendrimers were confirmed by 1H and C-13 NMR, FAB+, MALDI-TOF, electrospray mass spectra, and elemental analysis. Cubic nonlinear optical behavior of this first generation of resorcinarene dendrimers was studied. The chi((3)) values estimated from the THG Maker-fringe technique for the phenyl and ferrocenyl-ended resorcinarene dendrimers dispersed in thin solid films are of the order of 10(-13) and 10(-12) esu, respectively. (c) 2008 Elsevier Ltd. All rights reserved.
• Synthesis and NLO behavior of Oligo(phenylenevinylene)-Porphyrin Dendrimers
  作者：Guadalupe G. Flores-Rojas、Irina V. Lijanova、Omar G. Morales-Saavedra、Karla Sanchez-Montes、Marcos Martínez-García

  DOI：10.1016/j.dyepig.2012.07.011

  日期：2013.1

  Dendrons with a porphyrin core and pi-conjugated dendron branches with 8 and 16 stilbene groups have been synthesized and characterized. The dendrons used for dendrimer synthesis possessed an all trans configuration. Cubic non-linear optical behavior of the styryl and porphyrin-containing dendrimers was tested via Z-Scan measurements in spin-coated film samples. (C) 2012 Elsevier Ltd. All rights reserved.