{9-[3-(3-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol | 862305-61-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: {9-[3-(3-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol
• 英文别名: [9-[3-[3-(Hydroxymethyl)phenanthren-9-yl]propyl]phenanthren-3-yl]methanol；[9-[3-[3-(hydroxymethyl)phenanthren-9-yl]propyl]phenanthren-3-yl]methanol
• CAS: 862305-61-1
• 化学式: C₃₃H₂₈O₂
• 分子量: 456.584
• InChiKey: QSWNGDITFKAQEZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  {9-[3-(3-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol 在 4-甲基苯磺酸吡啶 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 240.0h， 以13%的产率得到6-Oxaheptacyclo[21.7.1.14,30.18,12.111,19.013,18.024,29]tetratriaconta-1(30),2,4(32),8(34),9,11,13,15,17,19(33),23(31),24,26,28-tetradecaene
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y
• 作为产物：
  描述：

  9-[3-(3-Formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 以78%的产率得到{9-[3-(3-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y

文献信息

• Synthesis and Fluorescence Spectra of Oxa[3.<i>n</i>]phenanthrenophanes
  作者：Yosuke Nakamura、Takuzo Yamazaki、Jun Nishimura

  DOI：10.1021/ol051047y

  日期：2005.7.1

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.