1-phenyl-3,3-bis(phenylsulfanyl)propyl pent-4-enyl ether | 295785-55-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-3,3-bis(phenylsulfanyl)propyl pent-4-enyl ether
• 英文别名: [1-Pent-4-enoxy-3,3-bis(phenylsulfanyl)propyl]benzene；[1-pent-4-enoxy-3,3-bis(phenylsulfanyl)propyl]benzene
• CAS: 295785-55-6
• 化学式: C₂₆H₂₈OS₂
• 分子量: 420.64
• InChiKey: JTJKGJLLLMJTHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  29
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-phenyl-3,3-bis(phenylsulfanyl)propyl pent-4-enyl ether 在 Cp2Ti(P(OEt)3)2 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 2-phenyl-3,4,7,8-tetrahydro-2H-oxocin 、 8-phenyl-3,4,7,8-tetrahydro-2H-oxocin
  参考文献：
  名称：

  Ring-Closing Metathesis of Titanium–Carbene Complexes Prepared from Thioacetals Having a Carbon–Carbon Double Bond

  摘要：

  The ring-closing metathesis proceeded to give cycloalkenes in good yields when diphenyl thioacetals having a carbon-carbon double bond were treated with the low-valent titanium species Cp2Ti[P(OEt)(3)](2) in THF at room temperature and then at reflux. This methodology is successfully applied to the preparation of cyclic ethers and sulfides. (C) 2000 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(00)00201-5
• 作为产物：
  描述：

  双(苯硫基)甲烷 在 正丁基锂 、 sodium hydride 作用下， 以 四氢呋喃 、 正己烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 生成 1-phenyl-3,3-bis(phenylsulfanyl)propyl pent-4-enyl ether
  参考文献：
  名称：

  Ring-Closing Metathesis of Titanium–Carbene Complexes Prepared from Thioacetals Having a Carbon–Carbon Double Bond

  摘要：

  The ring-closing metathesis proceeded to give cycloalkenes in good yields when diphenyl thioacetals having a carbon-carbon double bond were treated with the low-valent titanium species Cp2Ti[P(OEt)(3)](2) in THF at room temperature and then at reflux. This methodology is successfully applied to the preparation of cyclic ethers and sulfides. (C) 2000 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(00)00201-5

文献信息

• Ring-Closing Metathesis of Titanium–Carbene Complexes Prepared from Thioacetals Having a Carbon–Carbon Double Bond
  作者：Tooru Fujiwara、Yoshiko Kato、Takeshi Takeda

  DOI：10.1016/s0040-4020(00)00201-5

  日期：2000.7

  The ring-closing metathesis proceeded to give cycloalkenes in good yields when diphenyl thioacetals having a carbon-carbon double bond were treated with the low-valent titanium species Cp2Ti[P(OEt)(3)](2) in THF at room temperature and then at reflux. This methodology is successfully applied to the preparation of cyclic ethers and sulfides. (C) 2000 Published by Elsevier Science Ltd.