3,4,7,8-Tetrahydro-2,9-oxonindion | 117409-73-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,4,7,8-Tetrahydro-2,9-oxonindion
• 英文别名: (5Z)-3,4,7,8-tetrahydrooxonine-2,9-dione
• CAS: 117409-73-1
• 化学式: C₈H₁₀O₃
• 分子量: 154.166
• InChiKey: ZKXPLBZNFQNZNJ-UPHRSURJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,4,7,8-Tetrahydro-2,9-oxonindion 在 4-二甲氨基吡啶 、 叠氮基三甲基硅烷 作用下， 以 二氯甲烷 、 氯仿 为溶剂， 反应 9.33h， 生成 3-Hexenyl-laktam
  参考文献：
  名称：

  通过N-羧酸酐中间体从环酐制备内酰胺

  摘要：

  在连续的甲硅烷基叠氮化、质子分解、Curtius 重排和 DMAP 催化闭环后，环酐可以很容易地转化为环缩内酰胺，操作简单。琥珀酸酐不会形成环收缩的 β-内酰胺，而是生成 β- N-羧酸酐，其用作 β-肽和聚合物化学中使用的 β-氨基酸的活化类似物。

  DOI：

  10.1002/ejoc.202100751
• 作为产物：
  描述：

  顺式-5-环辛烯-1,2-二酮 在 potassium fluoride 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成 3,4,7,8-Tetrahydro-2,9-oxonindion
  参考文献：
  名称：

  Mayer, Winfried; Meier, Herbert, Chemische Berichte, 1989, vol. 122, p. 509 - 518

  摘要：

  DOI：

文献信息

• Hydrophilic antioxidant and method for the preparation of the same
  申请人：Founder Fine Chemical Industry Co., Ltd.

  公开号：EP3015450A1

  公开（公告）日：2016-05-04

  The present invention relates to the preparation of a hydrophilic antioxidant comprising a methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate group / poly alkylene glycol bridge group / carboxylic acid group, which has low volatility and high water solubility, and also has a surfactant (emulsifier) characteristic which is useful in the industrial application of oil-soluble antioxidants in aqueous phase systems.

  本发明涉及一种亲水性抗氧化剂的制备，该抗氧化剂由 3-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯基团/聚烷基乙二醇桥基/羧酸基团组成，具有低挥发性和高水溶性，同时还具有表面活性剂（乳化剂）特性，可用于水相体系中油溶性抗氧化剂的工业应用。
• Hydrophilic antioxidant and process for the preparation of the same
  申请人：Founder Fine Chemical Industry Co., Ltd.

  公开号：EP3061746A1

  公开（公告）日：2016-08-31

  The present invention relates to the preparation of a hydrophilic antioxidant containing a group of Methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate/polyalkylene glycol bridge/carboxylic acid/sulfonic acid of formula (I) as defined in claim 1, which have a low volatility and high water solubility, and also have a surfactant (emulsifier) characteristics that can help other oil-soluble antioxidants used in the water phase system in industry.

  本发明涉及一种亲水性抗氧化剂的制备，该抗氧化剂含有权利要求 1 所定义的式 (I) 的 3-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯/聚亚烷基二醇桥/羧酸/磺酸基团，该抗氧化剂具有低挥发性和高水溶性，同时还具有表面活性剂（乳化剂）特性，可以帮助工业中水相体系中使用的其他油溶性抗氧化剂。
• MAYER, WINFRIED;MEIER, HERBERT, CHEM. BER., 122,(1989) N, C. 509-517
  作者：MAYER, WINFRIED、MEIER, HERBERT

  DOI：——

  日期：——
• HYDROPHILIC ANTIOXIDANT AND PROCESS FOR THE PREPARATION OF THE SAME
  申请人：Founder Fine Chemical Industry Co., Ltd.

  公开号：EP3061746B1

  公开（公告）日：2016-12-07
• [EN] PROCESS FOR THE PREPARATION OF DICARBOXYLIC ACIDS OR DICARBOXYLIC ACID ESTERS BY METATHESIS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'ACIDES DICARBOXYLIQUES OU D'ESTERS D'ACIDES DICARBOXYLIQUES PAR MÉTATHÈSE
  申请人：EMERY OLEOCHEMICALS GMBH

  公开号：WO2011110349A2

  公开（公告）日：2011-09-15

  The present invention relates to a process for the preparation of dicarboxylic acids or dicarboxylic acid esters comprising the following process steps: A1 provision of at least the following reactants: a1 - a first aliphatic compound having 5 to 40 carbon atoms with in each case at least one functional group of the general formula (I) and (II), wherein R1 is a saturated or unsaturated aliphatic group having 2 to 20, preferably 4 to 16 and particularly preferably 6 to 12 carbon atoms and R2 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, preferably having 1 to 5 carbon atoms and particularly preferably having 1, 2 or 3 carbon atoms formula (I) and (II) and a2 at least one further aliphatic compound which differs from the first aliphatic compound, chosen from the group consisting of a2a a compound of the general formula (III) in which n is chosen from 1, 2, 3, 4 and 5; a2b a compound of the general formula (IV) in which R3 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, preferably having 1 to 5 carbon atoms and particularly preferably having 1, 2 or 3 carbon atoms and R4 and R5 independently of each other are a saturated alkylene group having 1 to 14 carbon atoms, preferably having 1 to 10 carbon atoms and very particularly preferably 1 to 5 carbon atoms; A2 provision of at least one organometallic catalyst based on ruthenium; A3 bringing into contact of the reactants and the catalyst to obtain a product mixture and the catalyst; A4 separating off of the catalyst; A5 optionally division of the product mixture into products Pi, i being a natural number, and the reactants which remain; the process being a metathesis reaction, and the dicarboxylic acid obtainable therefrom and the dicarboxylic acid ester obtainable therefrom, a process for the preparation of a polymer and the polymer obtainable by this process.

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