N-异丙基-N-硝基-2-丙胺 | 4164-30-1

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 中文名称: N-异丙基-N-硝基-2-丙胺
• 英文名称: diisopropylnitramine
• 英文别名: N,N-Dipropan-2-ylnitramide；N,N-di(propan-2-yl)nitramide
• CAS: 4164-30-1
• 化学式: C₆H₁₄N₂O₂
• 分子量: 146.189
• InChiKey: NNTWPXAZILBWAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  49.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-异丙基-N-硝基-2-丙胺 以 氘代苯 为溶剂， 生成 N-亚硝基二异丙胺
  参考文献：
  名称：

  Mechanisms of Nitramine Thermolysis

  摘要：

  The thermal decomposition of a number of nitramines was studied in dilute solution and in the melt, The nitramines included acyclic mononitramines [dimethylnitramine (DMN), diethylnitramine (DEN), dipropylnitramine (DPN), and diisopropylnitramine (DIPN)], cyclic mononitramines [N-nitropiperidine (NPIP) and N-nitropyrrolidine (NPyr)], cyclic dinitramines [N-dinitropiperazine (pDNP), 1,3-dinitro-1,3-diazacyclopentane (DNI), and 1,3-dinitro-1,3-diazacyclohexane (mDNP)], and 1,3,5-trinitro-1,3,5-triazocyclohexane (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), hexanitrohexaazaisowurtzitane (HNIW), and 1,3,3-trinitroazetidine (TNAZ). For the acyclic and cyclic mono- and dinitramines, the corresponding nitrosamines were the only or major condensed-phase product. Kinetics and activation parameters were determined for the thermolysis of dilute solutions (0.01-1.0 wt %) over the range 200-300 degrees C. The thermolyses were found to be first-order with the rate constants unaffected by the use of deuterated solvent. As the nitramines became more complex than dimethylnitramine (DMN), the rate of decomposition increased and the product distribution became more complex. As the length of the aliphatic chain increased (DMN < DEN < DPN), the rate of thermolysis increased, yet nitrosamine remained the only observed condensed-phase product. When a secondary carbon was attached to the N-nitramine (DIPN) rather than the primary (DPN), the rate of decomposition increased and a new condensed-phase product was observed. Among the cyclic nitramines, the rate of decomposition increased as the number of NNO2 groups increased (NPIP < pDNP; NPyr < DNI; mDMP < RDX). The position of the nitramine groups affected the decomposition: meta NNO2 groups (mDNP) decomposed faster than para (pDNP). Ring strain decreased stability: mDNP < DNI; HMX < RDX. In complex nitramines, the increase in decomposition rate, the appearance of new products, and the change in the relative importance of nitrosamine and of N-2 and N2O are attributed to new decomposition routes available to them. However, since complex nitramines (e.g. RDX) maintain first-order kinetics and since most have activation energies in the range of 40-50 kcal/mol, it is believed that the triggering mechanism remains N-NO2 homolysis. Intramolecular hydrogen transfer is also considered an important mode of nitramine decomposition.

  DOI：

  10.1021/j100079a019
• 作为产物：
  描述：

  N-亚硝基二异丙胺 在 三氟过氧乙酸 作用下， 生成 N-异丙基-N-硝基-2-丙胺
  参考文献：
  名称：

  Peroxytrifluoroacetic Acid. II. The Oxidation of Anilines to Nitrobenzenes¹

  摘要：

  DOI：

  10.1021/ja01642a030

文献信息

• DETECTION OF ANALYTES INCLUDING NITRO-CONTAINING ANALYTES
  申请人：Swager Timothy M.

  公开号：US20130065318A1

  公开（公告）日：2013-03-14

  Sensors and methods for determination of analytes are provided. Analytes including explosives (e.g., RDX or PETN) may be determined by monitoring, for example, a change in an optical signal of a material upon exposure to the analyte. In some embodiments, the analyte and the material may interact via a chemical reaction to form a new emissive species. Embodiments described herein may provide inexpensive sensors with high selectivity and sensitivity.

  提供了用于测定分析物的传感器和方法。例如，可以通过监测物质在暴露于分析物（例如RDX或PETN）时的光信号变化来确定分析物。在某些实施例中，分析物和物质可以通过化学反应相互作用以形成新的发射物种。本文所述的实施例可能提供价格便宜、选择性和灵敏度高的传感器。
• ZUSAMMENSETZUNGEN ENTHALTEND PRIMÄRE AROMATISCHE AMINE ZUR KORROSIONSSCHÜTZENDEN VORBEHANDLUNG METALLISCHER BAUTEILE
  申请人：Henkel AG & Co. KGaA

  公开号：EP3392373A1

  公开（公告）日：2018-10-24

  Die vorliegende Erfindung betrifft ein Verfahren zur korrosionsschützenden Vorbehandlung metallischer Bauteile, die zumindest teilweise Oberflächen eines metallischen Werkstoffes aufweist, der überwiegend aus einem oder mehreren der Elemente Eisen, Zink und/oder Aluminium besteht, unter Verwendung einer sauren wässrigen Zusammensetzung enthaltend freies Fluorid und primäre aromatische Amine in Gegenwart einer in Wasser gelösten Verbindung, die eine Quelle für NitritIonen darstellt.

  本发明涉及一种金属部件的防腐预处理工艺，该金属部件至少有部分表面是主要由一种或多种铁、锌和/或铝元素组成的金属材料，使用含有游离氟和伯胺的酸性水溶液组合物，并有一种溶解在水中的亚硝酸根离子源化合物存在。
• Peroxytrifluoroacetic Acid. II. The Oxidation of Anilines to Nitrobenzenes¹
  作者：William D. Emmons

  DOI：10.1021/ja01642a030

  日期：1954.7
• Chute et al., Canadian Journal of Research, Section B: Chemical Sciences, 1948, vol. 26, p. 125
  作者：Chute et al.

  DOI：——

  日期：——
• The Reaction of Dialkylcarbamyl Chlorides with Silver Nitrate¹
  作者：William P. Norris

  DOI：10.1021/ja01522a047

  日期：1959.7