chloromethyl 4-vinylphenyl ether | 45967-25-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: chloromethyl 4-vinylphenyl ether
• 英文别名: chloromethyl 4-styryl ether；1-(Chloromethoxy)-4-ethenylbenzene
• CAS: 45967-25-7
• 化学式: C₉H₉ClO
• mdl: MFCD19233835
• 分子量: 168.623
• InChiKey: FFILSRMIWBBSQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.111
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-((methylthio)methoxy)benzaldehyde 在 正丁基锂 、 乙酰氯 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 4.67h， 生成 chloromethyl 4-vinylphenyl ether
  参考文献：
  名称：

  Antonsen, Oeyvind; Benneche, Tore; Undheim, Kjell, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1988, vol. 42, # 8, p. 515 - 523

  摘要：

  DOI：

文献信息

• Method for producing modified polyphenylene oxides
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0017939A1

  公开（公告）日：1980-10-29

  A method for producing a modified polyphenylene oxide is described which comprises polymerizing 69 to 25 parts by weight of a mixture of 97 to 45% by weight of a styrene monomer and 3 to 55% by weight of a polar vinyl monomer at 90° to 190 °C using 0.3 to 10 parts by weight of a radical initiator in an aqueous dispersion containing a dispersion stabilizer alone or in combination with at least one of a surfactant and an adhesion-preventing agent in the presence of 31 to 75 parts by weight of a polyphenylene oxide having a unit structure of the formula, wherein Ri, R2, R3 and R4 are each a hydrogen or halogen atom, or a hydrocarbon, substituted hydrocarbon, cyano, hydrocarbonoxy, substituted hydrocarbonoxy, nitro or amino group.

  本发明描述了一种生产改性聚苯醚的方法，该方法包括在 90° 至 190°C 的温度下，使用 0.3 至 10 份（按重量计）的自由基引发剂，将 69 至 25 份（按重量计）由 97 至 45% 的苯乙烯单体和 3 至 55%（按重量计）的极性乙烯基单体组成的混合物在含有分散稳定剂的水分散液中聚合。在含有分散稳定剂（单独或与表面活性剂和防粘剂中的至少一种结合使用）的水性分散体中，在 31 至 75 份（重量）具有式中单元结构的聚苯氧化物存在下，使用 3 至 10 份（重量）自由基引发剂、 其中 Ri、R2、R3 和 R4 各为氢原子或卤素原子，或烃基、取代烃基、氰基、烃氧基、取代烃氧基、硝基或氨基。
• Thermoplastic resin composition and process for producing the same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0352057A2

  公开（公告）日：1990-01-24

  Disclosed herein is a thermoplastic resin composition which comprises: (a) a polyphenylene ether resin or a polyphenylene ether-­containing resin composition, (b) a polypropylene grafted with a styrene-based monomer and/or a propylene copolymer grafted with a styrene-­based monomer, (c) an ethylene-α-olefin copolymer grafted with a styrene-based monomer, said ethylene-α-olefin copo­lymer having a density of 0.85-0.91 g/cm³ and a maximum melting peak temperature of 100°C and above measured with a differential scanning calorimeter (DSC), and (d) an optional rubbery substance. Also disclosed herein is a process a process for pro­ducing a thermoplastic resin composition which comprises incorporating a preblend composed of: (a′) a polyphenylene ether resin or a polyphenylene ether-­containing resin composition, (b′) a polypropylene and/or a propylene copolymer, (c′) an ethylene-α-olefin copolymer having a density of 0.85-0.91 g/cm³ and a maximum melting peak temperature of 100°C and above measured with a differential scan­ning calorimeter (DSC), and (d′) an optional rubbery substance with a styrene-based monomer and an organic peroxide, followed by kneading with heating. The thermoplastic resin composition has good mold­ability and yields molded articles having well-balanced physical properties.

  此处公开的热塑性树脂组合物包括 (a) 聚苯醚树脂或含聚苯醚的树脂组合物、 (b) 与苯乙烯基单体接枝的聚丙烯和/或与苯乙烯基单体接枝的丙烯共聚物、 (c) 与苯乙烯基单体接枝的乙烯-α-烯烃共聚物，所述乙烯-α-烯烃共聚物的密度为 0.85-0.91 g/cm³，用差示扫描量热仪（DSC）测量的最大熔融峰温度为 100°C 及以上，以及 (d) 可选的橡胶物质。 本文还公开了一种生产热塑性树脂组合物的工艺，该工艺包括加入由以下物质组成的预混料： 1： (a′) 聚苯醚树脂或含聚苯醚的树脂组合物、 (b′) 聚丙烯和/或丙烯共聚物、 (c′) 乙烯-α-烯烃共聚物，其密度为 0.85-0.91 克/立方厘米，用差示扫描量热计(DSC)测得的最大熔峰温度为 100℃及以上，和 (d′) 可选的橡胶物质 用苯乙烯基单体和有机过氧化物混合，然后加热捏合。 这种热塑性树脂组合物具有良好的可模塑性，可制成具有均衡物理性能的模塑制品。
• MODIFIED PROPYLENE POLYMER AND THERMOPLASTIC RESIN COMPOSITION COMPRISING MODIFIED PROPYLENE POLYMER AND POLYPHENYLENE ETHER
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP0510206A1

  公开（公告）日：1992-10-28

  A modified propylene polymer having an average number of graft chains of 1 to 10 per molecule of propylene polymer, a weight-average degree of polymerization of the graft chain of 1 to 100 and a weight-average molecular weight of 1,000 to 500,000, said modified polymer being produced by the graft copolymerization of a propylene polymer with a specified amount of a combination of specified monomers selected among styrenic monomers, amine monomers and aminated styrenic monomers; and a thermoplastic resin composition comprising said modified polymer and a polyphenylene ether modified with a compound having a functional group which can react with an amino group. The modified propylene polymer is excellent in coatability, antistatic property and mechanical properties and is useful as a molding and an alloying agent for polymers, while the thermoplastic resin composition is excellent in strength and heat resistance.

  一种改性丙烯聚合物，每分子丙烯聚合物的平均接枝链数为 1 至 10，接枝链的重量平均聚合度为 1 至 100，重量平均分子量为 1,000 至 500,000，所述改性聚合物是通过丙烯聚合物与特定量的特定单体组合（选自苯乙烯类单体、胺类单体和胺化苯乙烯类单体）接枝共聚而制得；以及一种热塑性树脂组合物，该组合物包含上述改性聚合物和用具有可与氨基反应的官能团的化合物改性的聚苯醚。改性丙烯聚合物具有优异的涂覆性、抗静电性和机械性能，可用作聚合物的成型剂和合金剂，而热塑性树脂组合物具有优异的强度和耐热性。
• Liquid crystalline polyester resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0542232A1

  公开（公告）日：1993-05-19

  A liquid crystalline polyester resin composition containing (A) a polyphenylene ether which is modified with at least one amine selected from the group consisting of primary amines and secondary amines; (B) a liquid crystalline polyester; and optionally (C) at least one oil selected from the group consisting of white oil and phenyl ether type oils, which composition has improved moldability and provides a molded article having improved weld strength while maintaining good heat resistance and mechanical properties of the liquid crystalline polyester.

  一种液态结晶聚酯树脂组合物，含有 (A) 聚苯醚，该聚苯醚用至少一种从伯胺和仲胺组成的组中选出的胺进行改性；(B) 液态结晶聚酯；以及 (C) 至少一种从白油和苯醚型油组成的组中选出的油，该组合物具有更好的可模塑性，可提供具有更好焊接强度的模塑制品，同时保持液态结晶聚酯良好的耐热性和机械性能。
• Thermoplastic resin composition containing modified polyphenylene ether
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0648810A1

  公开（公告）日：1995-04-19

  A thermoplastic resin composition containing (A) 100 parts by weight of at least one modified polyphenylene ether selected from the group consisting of (A1) a modified polyphenylene ether having repeating units of the formula (1): in which R₁ and R₂ are, independently from each other, a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms and having a number average polymerization degree of 20 to 1200, in which 0.02/X to 1/X of methyl groups at the 2- and/or 6-positions of phenylene group are modified to an aminomethyl group in which X is a number average polymerization degree and (A2) a modified polyphenylene ether comprising polyphenylene ether to which an amino group-containing monomer is graft polymerized, and (B) 0.1 to 70 parts by weight of an epoxy group-containing ethylene copolymer comprising (a) 50 to 99 % by weight of ethylene units, (b) 0.1 to 30 % by weight of unsaturated carboxylic acid diglycidyl ester units or unsaturated glycidyl ether units and (c) 0 to 50 % by weight of ethylenically unsaturated ester compound units, which composition has improved molding processability and impact resistance.

  一种热塑性树脂组合物，含有 (A) 100 重量份的至少一种改性聚苯醚，该改性聚苯醚选自 (A1) 具有式(1)重复单元的改性聚苯醚： 其中 R₁ 和 R₂ 相互独立地为氢原子或具有 1 至 20 个碳原子且平均聚合度数为 20 至 1200 的烃基，其中 0.02/X 至 1/X 的甲基被改性为氨基甲基，其中 X 为平均聚合度数；(A2) 改性聚苯醚，包括聚苯醚，在聚苯醚上接枝聚合了含氨基单体；以及 (B) 0.1至70份重量的含环氧基乙烯共聚物，该共聚物包括(a)50至99%重量的乙烯单元，(b)0.1至30%重量的不饱和羧酸二缩水甘油酯单元或不饱和缩水甘油醚单元和(c)0至50%重量的乙烯不饱和酯化合物单元，该组合物具有更好的成型加工性和抗冲击性。