(3S,7Ξ,7aΞ)-2,2-dimethyl-5-pentyl-2,3,7,7a-tetrahydro-imidazo[5,1-b]thiazole-3,7-dicarboxylic acid | 60874-75-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (3S,7Ξ,7aΞ)-2,2-dimethyl-5-pentyl-2,3,7,7a-tetrahydro-imidazo[5,1-b]thiazole-3,7-dicarboxylic acid
• 英文别名: (3S,7Ξ,7aΞ)-2,2-Dimethyl-5-pentyl-2,3,7,7a-tetrahydro-imidazo[5,1-b]thiazol-3,7-dicarbonsaeure
• CAS: 60874-75-1
• 化学式: C₁₄H₂₂N₂O₄S
• 分子量: 314.406
• InChiKey: WSHAFFNUXSRZJC-YVNMAJEFSA-N

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 acid solution 作用下， 生成 (3S,7Ξ,7aΞ)-2,2-dimethyl-5-pentyl-2,3,7,7a-tetrahydro-imidazo[5,1-b]thiazole-3,7-dicarboxylic acid
  参考文献：
  名称：

  n-Amylpenicillin

  摘要：

  n-AMYLPENICILLIN was first prepared in an impure state by Catch, Cook and Heilbron1 by the catalytic hydrogenation of Δ"2-pentenylpenicillin, the product being characterized by conversion to the penillic acid and by the identification of n-caproic acid among the products of hydrolysis of the latter substance. The presence of n-amylpenicillin in the mixture of penicillins formed by the submerged fermentation of P. chrysogenum Q 176 has also been reported ; but the isolation of the pure penicillin has not yet been recorded. This penicillin has now been isolated in the pure state and characterized.

  DOI：

  10.1038/163095b0