8-(1,2,3,4-Tetrachlorofulven-6-yl)-heptafulven | 52923-07-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 8-(1,2,3,4-Tetrachlorofulven-6-yl)-heptafulven
• CAS: 52923-07-6
• 化学式: C₁₄H₈Cl₄
• 分子量: 318.03
• InChiKey: UPXOZODGZHEYGJ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  8-(1,2,3,4-Tetrachlorofulven-6-yl)-heptafulven 、 四氰基乙烯 生成 3-(2,3,4,5-Tetrachloro-cyclopenta-2,4-dienylidenemethyl)-3,8a-dihydro-azulene-1,1,2,2-tetracarbonitrile
  参考文献：
  名称：

  SYNTHESES OF 8-(1,2,3,4-TETRACHLOROFULVEN-6-YL)HEPTAFULVENE AND 8-(9-FLUORENYLIDENE)METHYLHEPTAFULVENE

  摘要：

  Treatment of [2-(2,3,4,5-tetrachloro-1,3-cyclopentadienyl)vinyl]tropylium fluoroborate 9 with bases gave 8-(1,2,3,4-tetrachlorofulven-6-yl)heptafulvene 4. In similar way 8-(9-fluorenylidene)methyl heptafulvene 5 was also prepared. 4 is more polar than 5 is, but is less stable. Both 4 and 5 easily gave [8+2] cycloadducts with tetracyanoethylene.

  DOI：

  10.1246/cl.1974.773
• 作为产物：
  描述：

  2-(2,3,4,5-Tetrachloro-1,3-cyclopentadienyl)-vinyl)-tropylium 在 吡啶 作用下， 生成 8-(1,2,3,4-Tetrachlorofulven-6-yl)-heptafulven
  参考文献：
  名称：

  SYNTHESES OF 8-(1,2,3,4-TETRACHLOROFULVEN-6-YL)HEPTAFULVENE AND 8-(9-FLUORENYLIDENE)METHYLHEPTAFULVENE

  摘要：

  Treatment of [2-(2,3,4,5-tetrachloro-1,3-cyclopentadienyl)vinyl]tropylium fluoroborate 9 with bases gave 8-(1,2,3,4-tetrachlorofulven-6-yl)heptafulvene 4. In similar way 8-(9-fluorenylidene)methyl heptafulvene 5 was also prepared. 4 is more polar than 5 is, but is less stable. Both 4 and 5 easily gave [8+2] cycloadducts with tetracyanoethylene.

  DOI：

  10.1246/cl.1974.773