Cu(1-(pyridine-2-yl)-3-methyl-3,6-diaza-heptane)Cl2 | 137193-50-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Cu(1-(pyridine-2-yl)-3-methyl-3,6-diaza-heptane)Cl2
• CAS: 137193-50-1
• 化学式: C₁₁H₁₉Cl₂CuN₃
• 分子量: 327.744
• InChiKey: FAIKSGMXQGYUTR-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1-(pyridine-2-yl)-3-methyl-3,6-diazaheptane 、 copper dichloride 以 甲醇 为溶剂， 生成 Cu(1-(pyridine-2-yl)-3-methyl-3,6-diaza-heptane)Cl2
  参考文献：
  名称：

  Copper(II) complexes of 1-(pyridine-2-yl)-3-methyl-3,6-diazaheptane (PDAHP). X-ray crystal structure of Cu(PDAHP)Cl2

  摘要：

  The reactions of the novel tridentate ligand 1-(pyridine-2-yl)-3-methyl-3,6-diazaheptane (PDAHP) with copper(II) salts have been investigated. The ligand and the complexes Cu(PDAHP)Cl2, Cu(PDAHP)Br2, [Cu(PDAHP)(OH2)2](ClO4)2 and [Cu(PDAHP)(NO3)](NO3) have been characterized by elemental analyses, conductivity and magnetic susceptibility measurements, mass, IR, electronic absorption and H-1 NMR data. In addition, the X-ray crystal structure of Cu(PDAHP)Cl2 is described. The structure is a distorted trigonal bipyramid in which the copper atom is coordinated by a ligand molecule that spans the two axial and one equatorial sites and by the two chlorine atoms in the remaining equatorial positions.

  DOI：

  10.1016/s0277-5387(00)83781-x