anthracene * Ar | 154751-21-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: anthracene * Ar
• 英文别名: (tetracene)Ar；Anthracene;argon
• CAS: 154751-21-0
• 化学式: Ar*C₁₄H₁₀
• 分子量: 218.181
• InChiKey: KNTDIQDFZJBBAH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  蒽 、 氩 以 neat (no solvent, gas phase) 为溶剂， 生成 anthracene * Ar 、 anthracene-(argon)3 complex 、 anthracene-(argon)2 complex 、 anthracene * Ar 、 anthracene-(argon)4 complex
  参考文献：
  名称：

  A study of anthracene–Ar_n (n=0–5) in the ground cationic state by laser threshold photoelectron spectroscopy: Selective ionization of complex isomers formed in the free jet expansion

  摘要：

  The van der Waals complexes formed between anthracene and argon in a free jet expansion are studied using laser resonance enhanced multiphoton ionization (REMPI) threshold photoelectron spectroscopy with the aim of selectively ionizing specific isomers of small- to medium-sized clusters for which discrete absorption peaks exist in the excitation spectrum. Two-color (1+1′) REMPI threshold photoelectron spectra of a number of isomers of anthracene–Arn (n=1–5) have been recorded in addition to that of anthracene itself. The following adiabatic ionization energies (Ia) have been obtained to within ±5 cm−1: 59 872 (n=0), 59 807 and 59 825 (n=1), 59 757 and 59 774 (n=2), 59 695 (n=3), 59 606 and 59 660 (n=4), and 59 565 cm−1 (n=5). For n=1–3, detailed van der Waals cation vibrational structure was observed, showing progressions in both bending and stretching mode vibrations. The resulting vibrational information together with the ionization energy red shifts has helped in assigning bands observed in the threshold photoelectron spectra to particular geometric isomers some of which were not necessarily observed in the excitation spectrum.

  DOI：

  10.1063/1.466386

文献信息

• Resonances in mediated intersystem crossing of jet-cooled anthracene derivatives
  作者：Aviv Amirav、Joshua Jortner

  DOI：10.1016/0009-2614(86)80621-2

  日期：1986.12

  The mechanisms of direct and mediated intersystem crossing from the first excited singlet manifold of anthracene and some of its derivatives were explored by the study of the internal and the external heavy-atom effect on the fluorescence quantum yields. Pronounced mode selectivity was observed in the vibrational energy dependence of the emission quantum yield in 9-bromoan-thracene and 9,10-dibromoanthracene

  通过研究内部和外部重原子对荧光量子产率的影响，探索了从蒽的第一激发单重态歧管及其一些衍生物直接和介导的系统间交叉的机理。在9-溴蒽和9,10-二溴蒽中，在发射量子产率的振动能量依赖性中观察到明显的模式选择性。
• Real-time dynamics of vibrational predissociation in anthracene-Arn (n = 1, 2, 3)
  作者：Ahmed Heikal、Luis Bañares、David H. Semmes、Ahmed H. Zewail

  DOI：10.1016/0301-0104(91)80092-v

  日期：1991.10

  The vibrational predissociation of van der Waals complexes of anthracene-Arn (n = 1, 2, 3), isolated in a supersonic expansion, has been studied following excitation to single vibrational levels ( 1201, 1001 1202 601) in S1. Using picosecond t spectroscopy, the intramolecularvibrational-energy redistribution IVR and the vibrational predissociation (VP) dynamics are studied and related to the character

  范的DER蒽的Ar范德华络合物振动预离解Ñ（Ñ = 1，2，3）中，在超声膨胀分离，已经研究了以下激发到单振动能级（12 0 1 10 0 1 12 0 2 6 0 1）在S 1中。使用皮秒t光谱，研究了分子内振动能量的再分配IVR和振动预离解（VP）动力学，并且与该模式的特性及其能量有关。还讨论了IVR和VP速率与群集大小的关系。