{(α-picoline)(I)2nickel} | 100481-72-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: {(α-picoline)(I)2nickel}
• 英文别名: Diiodonickel;2-methylpyridine
• CAS: 100481-72-9
• 化学式: C₆H₇I₂NNi
• 分子量: 405.627
• InChiKey: UZEWZAYYWKGSIA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  碳酸甲丙酯 、 nickel(II) iodide 以 not given 为溶剂， 生成 {(α-picoline)(I)2nickel}
  参考文献：
  名称：

  甲基吡啶配合物的热分析研究

  摘要：

  摘要 用微分仪研究了与甲基吡啶形成的过渡金属卤化物配合物的热行为。复合物的热分解可以在熔融相或固相中分几个步骤进行。还研究了逐步反应的机理。

  DOI：

  10.1016/0040-6031(85)85025-5

文献信息

• Pyridine-type complexes of transition metal halides
  作者：G. Liptay、G. Kenessey、P. Bukovec

  DOI：10.1007/bf02546624

  日期：1993.8

  Formation of nitrogen ligated complexes of types NiL6X2, NiL4X2, NiL2X2 and NiL1X2 (where L = pyridine, 2-, 3- and 4-methyl-pyridine and X = F, Cl, Br, I) have been studied by traditional preparative methods, i.e. from solutions and by solid-gas phase chemisorption. Quaternary mixed complexes were obtained by chemisorption from heated intermediates. The complexes thus formed were further analysed by simultaneous TG-DTG-DTA. Effects of the ligands on stoichiometry and thermal properties of the complexes are discussed.