tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II) | 126515-59-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II)
• CAS: 126515-59-1
• 化学式: C₈₈H₈₄Cl₁₂CoN₈O₄
• 分子量: 1802.12
• InChiKey: PVVZKEXFPFSXMH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II) 在 溴 作用下， 以 苯 为溶剂， 生成 tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(III)
  参考文献：
  名称：

  Cobalt tetraphenol-substituted phthalocyanine. A spectroscopic study of its redox properties in solution

  摘要：

  The redox properties of tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II), (ArOH)4PcCo (1) have been studied in solution using electron spectroscopy and electron spin resonance. For 1 two reduced species, the yellow (ArOH)4PcCo(I) (2) and the pink (ArOH)4Pc3-Co(I) (3), and two oxidized species, the green (ArOH)4PCCo(III) (4) and the red-brown (ArOH)4Pc1-Co(III) (5), are observed representing the oxidation state changes of the cobalt and phthalocyanine ring. By using PbO2 or K3Fe(CN)6 the oxidation occurs at the peripherically substituted phenolic group and leads to the phenoxy radical (ArO.)(ArOH)3PcCO (6).

  DOI：

  10.1016/s0020-1693(00)83180-1
• 作为产物：
  描述：

  tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninato(3-)cobalt(I) 在 氧气 作用下， 以 not given 为溶剂， 生成 tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II)
  参考文献：
  名称：

  Cobalt tetraphenol-substituted phthalocyanine. A spectroscopic study of its redox properties in solution

  摘要：

  The redox properties of tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II), (ArOH)4PcCo (1) have been studied in solution using electron spectroscopy and electron spin resonance. For 1 two reduced species, the yellow (ArOH)4PcCo(I) (2) and the pink (ArOH)4Pc3-Co(I) (3), and two oxidized species, the green (ArOH)4PCCo(III) (4) and the red-brown (ArOH)4Pc1-Co(III) (5), are observed representing the oxidation state changes of the cobalt and phthalocyanine ring. By using PbO2 or K3Fe(CN)6 the oxidation occurs at the peripherically substituted phenolic group and leads to the phenoxy radical (ArO.)(ArOH)3PcCO (6).

  DOI：

  10.1016/s0020-1693(00)83180-1

文献信息

• ESR study of the interaction of tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)dodecachlorophthalocyaninatocobalt(II) with dioxygen
  作者：Elena R. Milaeva、Zoltan Szeverenyi、Laszlo I. Simandi

  DOI：10.1016/s0020-1693(00)80487-9

  日期：1990.1