| 154724-47-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 154724-47-7
• 化学式: C₁₀H₁₂CuO₈
• 分子量: 323.746
• InChiKey: MJBLSIROQJQZJM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  在 triphenyl phosphine 作用下， 以 乙醇 为溶剂， 以48%的产率得到[Cu(η1-OOCCH2OC6H4OCH2COOH)(PPh3)3]
  参考文献：
  名称：

  Synthesis and X-ray crystal structure of the copper(I) dicarboxylic acid complex [Cu(η1-bdoaH)(PPh3)3] (bdoaH2 = benzene-1,2- dioxyacetic acid)

  摘要：

  The copper(II) complex [Cu(bdoa)(H2O)(2)] (bdoaH(2) = benzene-1,2-dioxyacetic acid) reacts with triphenylphosphine (1:4 mol ratio) to give the colourless copper(I) complex [Cu(eta(1)-bdoaH) (PPh(3))(3)] (1) in good yield. The X-ray crystal structure of the complex shows the copper atom at the centre of a distorted tetrahedron, and is ligated by the phosphorus atoms of the three triphenylphosphines and one carboxylate oxygen atom of the bdoaH(-) ligand. Significant intermolecular hydrogen-bonding exists between the pendant carboxylate OH function of one molecule and the uncoordinated ''ketonic'' oxygen of a neighbouring molecule. Complex 1 is non-conducting in chloroform but ionizes readily in acetonitrile. The cyclic voltammogram of an acetonitrile solution of 1 shows a single irreversible anodic peak for the oxidation of the PPh(3) ligands and the copper(I) centre, and a single irreversible cathodic peak for the reduction of the bdoaH(-) ion. IR and mass spectral data for 1 are given.

  DOI：

  10.1016/s0277-5387(00)88148-6